Molybdenum alkylidynes and phosphamolybdacyclobutenes derived from phosphaalkynes and molybdenum alkylidenes
Conference
·
OSTI ID:370611
- Sandia National Laboratories, Albuquerque, NM (United States); and others
Molybdenum alkylidynes are formed in the reaction of t-Bu-C{triple_bond}P with molybdenum alkylidenes. Alkylidynes undergo a secondary thermal transformation to form 1-phospha-3-molybdacyclobut-2-enes quantitatively; Complex 3c is formed directly from the reaction of t-Bu-C{triple_bond}P with 1c. Spectral and structural characterization of complexes and mechanistic considerations will be discussed.
- Research Organization:
- Sandia National Laboratory
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 370611
- Report Number(s):
- CONF-960376--
- Country of Publication:
- United States
- Language:
- English
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