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>24% screen printed Cu contacted n-TOPCon solar cells with successful implementation of LECO process

Journal Article · · Solar Energy Materials and Solar Cells
In this paper, we report the successful fabrication of >24.0 % efficiency n-TOPCon Si solar cells with screen-printed, fire-through Cu contact to n-TOPCon on the rear side and Ag contacted boron emitter on the front side by implementing optimized firing and LECO conditions. The highest efficiency (24.3%) Cu contacted n-TOPCon cell in this study showed excellent cell performance parameters with Voc >730 mV, Jsc of 41.1 mA/cm2 and FF of 80.8%, resulting in an absolute efficiency gap of 0.2% between Cu-contacted and fully Ag contacted n-TOPCon cells (24.5%). The mini-module fabricated with the Cu contacted n-TOPCon cell showed excellent reliability and durability of open-circuit voltage (Voc), pseudo fill factor (pFF) and efficiency after prolonged damp-heat tests. Such high efficiency screen printed Cu contacted n-TOPCon cells provide unique opportunity to replace very expensive Ag contact on n-TOPCon with cheaper screen printable Cu metal pastes.
Research Organization:
National Laboratory of the Rockies (NLR), Golden, CO (United States)
Sponsoring Organization:
USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
Grant/Contract Number:
AC36-08GO28308; EE0010497
OSTI ID:
3031075
Report Number(s):
NLR/JA-5K00-99787
Journal Information:
Solar Energy Materials and Solar Cells, Journal Name: Solar Energy Materials and Solar Cells Vol. 302; ISSN 0927-0248
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (16)

Silicon‐based passivating contacts: The TOPCon route journal December 2021
Laser‐enhanced contact optimization oniTOPCon solar cells journal August 2022
Investigation on Effects of the Laser‐Enhanced Contact Optimization Process With Ag Paste in a Boron Emitter for n‐TOPCon Solar Cell journal October 2024
Investigation of the Ag–Si Contact Characteristics of Boron Emitters for n‐Tunnel Oxide‐Passivated Contact Solar Cells Metallized by Laser‐Assisted Current Injection Treatment journal June 2024
Investigation of Cu metallization for Si solar cells journal October 2002
Long Term Stability Analysis of Copper Front Side Metallization for Silicon Solar Cells journal January 2014
Development of nanoparticle copper screen printing pastes for silicon heterojunction solar cells journal September 2019
24.58% total area efficiency of screen-printed, large area industrial silicon solar cells with the tunnel oxide passivated contacts (i-TOPCon) design journal March 2020
Fully screen-printed bifacial large area 22.6% N-type Si solar cell with lightly doped ion-implanted boron emitter and tunnel oxide passivated rear contact journal August 2020
~23% rear side poly-Si/SiO2 passivated silicon solar cell with optimized ion-implanted boron emitter and screen-printed contacts journal September 2021
Investigation of contact formation mechanism and application of copper-based front contact paste for crystalline silicon solar cells journal May 2023
Industrial-scale deposition of nanocrystalline silicon oxide for 26.4%-efficient silicon heterojunction solar cells with copper electrodes journal November 2023
Carrier-selective contacts for Si solar cells journal May 2014
High Efficiency Screen-Printed Ag-Free PERC Solar Cell With Cu Paste and Laser-Enhanced Contact Optimization journal November 2025
Physics of Copper in Silicon journal January 2002
Quick Determination of Copper-Metallization Long-Term Impact on Silicon Solar Cells journal January 2010

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