Tetragonal domain structure and magnetoresistance of La{sub 1{minus}{ital x}}Sr{sub {ital x}}CoO{sub 3}
- School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245 (United States)
- Advanced Technology Materials, Inc., 7 Commerce Drive, Danbury, Connecticut 06810 (United States)
La{sub 1{minus}{ital x}}Sr{sub {ital x}}CoO{sub 3} (LSCO) has recently been found to exhibit large magnetoresistance (MR) effect. In this paper, microstructures of LSCO thin films, which may provide important clues for understanding the unusual MR characteristics in these intrinsic magnetic oxides, were determined by transmission electron microscopy. An ordered, anisotropic perovskite-type structure {ital n}-LSCO was observed and its atomic model was determined. The ordered structure has a tetragonal cell with a La-Co-Sr-Co-[001] layered atom distribution along the {ital c} axis. This structure is intrinsic for the LSCO system and is resulted directly from the lattice substitution between La and Sr. The entire film is composed of [001], [010], and [100] anisotropic domains of sizes in the order of 30{endash}200 nm. Microstructures of (011)- and (001)-type domain boundaries were determined. Although {ital n}-La{sub 0.5}Sr{sub 0.5}CoO{sub 3} is the dominant structure, a tetragonal phase {ital n}-La{sub 0.33}Sr{sub 0.67}CoO{sub 3} has also been identified, which is produced by both the lattice substitution between La and Sr and the variation of local chemical composition. These structures could play a key role in determining the MR properties of the materials which are believed due to the intrinsic coupled spin scattering of Co atoms in different atomic layers. {copyright} {ital 1996 The American Physical Society.}
- OSTI ID:
- 285957
- Journal Information:
- Physical Review, B: Condensed Matter, Journal Name: Physical Review, B: Condensed Matter Journal Issue: 2 Vol. 54; ISSN PRBMDO; ISSN 0163-1829
- Country of Publication:
- United States
- Language:
- English
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