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Manufacture of ammonium sulfate fertilizer from FGD-gypsum. Technical report, September 1--November 30, 1994

Technical Report ·
DOI:https://doi.org/10.2172/28257· OSTI ID:28257
; ;  [1];  [2];  [3];  [4]
  1. Illinois State Geological Survey, Champaign, IL (United States)
  2. Illinois Univ., Urbana, IL (United States)
  3. Allied-Signal, Inc., Morristown, NJ (United States)
  4. Southeast Marketing Chemical Process, Inc. (United States)

The overall goal of this project is to assess the technical and economic feasibility for producing commercial-grade ammonium sulfate fertilizer from gypsum produced as part of limestone flue gas desulfurization (FGD) processes. This is a cooperative effort among the ISGS, the UIUC, AlliedSignal, SE-ME, Henry Fertilizer, Illinois Power Co. (IP), and Central Illinois Public Services (CIPS). Bench-scale experiments will be conducted to obtain process engineering data for manufacture of ammonium sulfate from FGD-gypsum and to help evaluate technical and economical feasibility of the process. Controlled greenhouse experiments will be conducted at UIUC to evaluate the chemical impact of the produced ammonium sulfate on soil properties. A process flow sheet will be proposed and market demand for the products will be established. An engineering team at IP will provide an independent review of the economics of the process. AlliedSignal will be involved in testing and quality evaluation of ammonium sulfate samples and is interested in an agreement to market the finished product. CIPS will provide technical assistance and samples of FGD-gypsum for the project. In this quarter, a literature study that should give detailed insight into the chemistry, process schemes, and costs of producing ammonium sulfate from gypsum is in progress at the ISGS. Acquisition of a high quality FGD-gypsum sample was completed. Collecting of the other lower grade sample was scheduled to be conducted in December. Characterization of these feed materials is in progress.

Research Organization:
Illinois State Geological Survey, Champaign, IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States); Illinois Dept. of Energy and Natural Resources, Springfield, IL (United States); Illinois Clean Coal Inst., Carterville, IL (United States)
DOE Contract Number:
FC22-92PC92521
OSTI ID:
28257
Report Number(s):
DOE/PC/92521--T199; ON: DE95008016
Country of Publication:
United States
Language:
English

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