Time-resolved infrared absorption studies applied to the study of radical plus molecule reactions
Book
·
OSTI ID:28070
- Argonne National Lab., IL (United States). Chemistry Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
The reaction of the cyano radical (CN) with ethane (C{sub 2}H{sub 6}) was studied using time resolved infrared absorption to monitor the product hydrogen cyanide (HCN) in individual ro-vibrational states. Pulse laser photolysis was used to provide an initial excess of the CN radical and the time dependence of individual ro-vibrational states of the high frequency antisymmetric stretching mode of HCN (0,0,v{sub 3}) was followed. These experiments reveal that the initial product state distribution of HCN is not highly excited in the HCN(0,0,v{sub 3}) vibrational manifold.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 28070
- Report Number(s):
- CONF-940142--; ISBN 0-8194-1417-4
- Country of Publication:
- United States
- Language:
- English
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