Time-resolved infrared absorption studies applied to the study of radical plus molecule reactions
Conference
·
OSTI ID:10118420
- Argonne National Lab., IL (United States)
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Reaction of the cyano radical (CN) with ethane (C{sub 2}H{sub 6}) was studied using time resolved infrared absorption to monitor the product hydrogen cyanide (HCN) in individual to-vibrational states. Pulse laser photolysis was used to provide an initial excess of the CN radical and the time dependence of individual ro-vibrational states of the high frequency anti-symmetric stretching mode of HCN (0,0,v{sub 3}) was followed. These experiments reveal that the initial product state distribution of HCN is not highly excited in the HCN(0,0,{sub 3}) vibrational manifold.
- Research Organization:
- Argonne National Lab., IL (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 10118420
- Report Number(s):
- ANL/CHM/CP--81658; CONF-940142--10; ON: DE94005921
- Country of Publication:
- United States
- Language:
- English
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Time-resolved infrared absorption studies applied to the study of radical plus molecule reactions
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Fri Dec 30 23:00:00 EST 1994
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OSTI ID:28070
The initial vibrational state distribution of HCN {ital {tilde X}} {sup 1}{Sigma}{sup +}({ital v}{sub 1},0,{ital v}{sub 3}) from the reaction CN({sup 2}{Sigma}{sup +})+C{sub 2}H{sub 6}{r_arrow}HCN+C{sub 2}H{sub 5}
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Mon May 22 00:00:00 EDT 1995
· Journal of Chemical Physics
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OSTI ID:46333
Direct measurement of the transition dipole moment of the {nu}{sub 3} asymmetric C-H stretching vibration of the methyl radical
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Sat Dec 30 23:00:00 EST 1995
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OSTI ID:456854