Possible hydride and methide transfer reactions: Reactions of Fe(CO){sub 4}R{sup -} (R=H, CH{sub 3}) and W(CO){sub 5}R{sup -} (R = H, CH{sub 3}, CL, Br, I) with metal carbonyl cations
Journal Article
·
· Journal of Coordination Chemistry
- State Univ. of New York, Buffalo, NY (United States)
Reactions of metal carbonyl cations (M(CO){sub 6}{sup +}, M = Mn, Re) with hydride-, methide- or halide-containing metal carbonyl anions Fe(CO){sub 4}R{sup -}, R = H, Me; W(CO){sub 5} (CH{sub 3}CN) and W(CO){sub 5}X{sup -}. In contrast, the tungsten hydride and methide complexes react, predominantly, by transfer of the hydride or methide to a carbonyl of the cation at a much faster rate. The iron hydride and methide complexes react by iron-based nucleophilicity involving a two-electron process.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 273996
- Journal Information:
- Journal of Coordination Chemistry, Journal Name: Journal of Coordination Chemistry Journal Issue: 1-4 Vol. 37; ISSN JCCMBQ; ISSN 0095-8972
- Country of Publication:
- United States
- Language:
- English
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