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U.S. Department of Energy
Office of Scientific and Technical Information

FY24 Development of Improved Grout Waste Forms for Alternative Low Activity Waste Treatment

Technical Report ·
DOI:https://doi.org/10.2172/2569108· OSTI ID:2569108
 [1];  [1]
  1. The Catholic Univ. of America, Washington, DC (United States)

Since the WTP Low Activity Waste (LAW) Vitrification Facility was not designed to process the entire inventory of Hanford LAW, up to half of the retrieved Hanford LAW will require supplemental immobilization. Immobilizing LAW in a cementitious waste form known as Cast Stone has been investigated as a possible candidate supplemental immobilization technology. In FY21, Washington River Protection Solutions, LLC (WRPS) tasked Atkins and the Vitreous State Laboratory (VSL) of The Catholic University of America (CUA) to perform testing to evaluate methods for reducing the release of COCs, particularly nitrate, 99Tc, and 129I, from cementitious waste forms made from aqueous LAW derived from Hanford Tank Waste. FY22 work built on the FY21 results and further developed formulations while targeting higher waste loadings. The objective of this work was to perform laboratory-scale testing to further refine the most promising formulation(s) that were identified in the FY23 work. The goal of the refinement was to further reduce the release rates for 99Tc, Cr, 129I, and nitrate while maintaining workability of the fresh grout, and to increase waste loading.

Research Organization:
Hanford Site (HNF), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Environmental Management (EM)
DOE Contract Number:
89303324DEM000096
OSTI ID:
2569108
Report Number(s):
H2C--72049
Country of Publication:
United States
Language:
English