Corrosion Behavior of Hydrophobic Coatings in Aqueous CO2 Environments

Conference · Tue Apr 08 04:00:00 EDT 2025

DOI:https://doi.org/10.2172/2562888· OSTI ID:2562888

Belarbi, Zineb ^[1]; Xiang, Fangming ^[1]; Hopkinson, David ^[2]; Dogan, Omer ^[2]

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1. NETL Site Support Contractor, National Energy Technology Laboratory
2. NETL

Internal corrosion is caused by gas impurities such as CO2, moisture, and H2S, leading to material degradation. To combat this, the National Energy Technology Laboratory (NETL) developed a novel hydrophobic coating to reduce surface hydrophobicity and enhance the corrosion resistance of steel. NETL’s approach uses multi-layer hydrophobic coatings, a novel and promising coating that could potentially revolutionize the industry's approach to internal corrosion mitigation. This work aims to investigate the corrosion performance of the hydrophobic coating and determine the water uptake. Electrochemical corrosion experiments were carried out on bare X65 carbon steel without and with coating in 3.5 wt.% NaCl saturated with CO2 at 20 °C to follow the water uptake as a function of exposure time. Linear polarization resistance (LPR) was used to determine the corrosion rate for carbon steel immersed in a NaCl electrolyte saturated with CO2. Electrochemical impedance spectroscopy (EIS) of uncoated and coated bare carbon steel was investigated. The analyses of impedance models and water uptake behaviors of hydrophobic coatings were studied for 200 hours during the corrosion process. The water uptake was estimated using the Brasher and Kingsbury relation. The results showed that the superhydrophobic coating that was developed used innovative nano-based materials to act as protection layers on the surface of metallic parts against mechanical aggressors, corrosion, and fouling agents.

• Research Organization: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
• Sponsoring Organization: USDOE Office of Fossil Energy and Carbon Management (FECM); USDOE Office of Fossil Energy and Carbon Management (FECM), Office of Resource Sustainability (FE-30)
• OSTI ID: 2562888
• Country of Publication: United States
• Language: English

Related Subjects

corrosion behavior
corrosion resistance
surface hydrophobicity