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Title: The method of symmetrized bosons with applications to vibrations of octahedral molecules

Abstract

A new technique for constructing representations of point groups, called symmetrized boson representation is introduced. This method is particularly useful when describing vibrations of large molecules and for high overtones. The method is illustrated by applying it to stretching overtones of octahedral molecules, SF{sub 6}, WF{sub 6}, and UF{sub 6} with group {ital O}{sub {ital h}}. {copyright} {ital 1996 American Institute of Physics.}

Authors:
 [1];  [2];  [3]
  1. Department of Physics, Nanjing University, Nanjing, 210008 (People`s Republic of China)
  2. Center for Theoretical Physics, Yale University, New Haven, Connecticut 06520-8120 (United States)
  3. Department of Physics, Nanjing Normal University, Nanjing, 210097 (People`s Republic of China)
Publication Date:
Research Org.:
Yale Univ., New Haven, CT (United States)
OSTI Identifier:
253456
DOE Contract Number:  
FG02-91ER40608
Resource Type:
Journal Article
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 104; Journal Issue: 3; Other Information: PBD: Jan 1996
Country of Publication:
United States
Language:
English
Subject:
66 PHYSICS; MOLECULES; VIBRATIONAL STATES; ABSORPTION SPECTRA; BOND LENGTHS; HAMILTONIANS; INFRARED SPECTRA; RAMAN SPECTROSCOPY; RYDBERG STATES; POINT GROUPS

Citation Formats

Chen, J, Department of Physics, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6396, Iachello, F, and Ping, J. The method of symmetrized bosons with applications to vibrations of octahedral molecules. United States: N. p., 1996. Web. doi:10.1063/1.470807.
Chen, J, Department of Physics, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6396, Iachello, F, & Ping, J. The method of symmetrized bosons with applications to vibrations of octahedral molecules. United States. doi:10.1063/1.470807.
Chen, J, Department of Physics, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6396, Iachello, F, and Ping, J. Mon . "The method of symmetrized bosons with applications to vibrations of octahedral molecules". United States. doi:10.1063/1.470807.
@article{osti_253456,
title = {The method of symmetrized bosons with applications to vibrations of octahedral molecules},
author = {Chen, J and Department of Physics, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6396 and Iachello, F and Ping, J},
abstractNote = {A new technique for constructing representations of point groups, called symmetrized boson representation is introduced. This method is particularly useful when describing vibrations of large molecules and for high overtones. The method is illustrated by applying it to stretching overtones of octahedral molecules, SF{sub 6}, WF{sub 6}, and UF{sub 6} with group {ital O}{sub {ital h}}. {copyright} {ital 1996 American Institute of Physics.}},
doi = {10.1063/1.470807},
journal = {Journal of Chemical Physics},
number = 3,
volume = 104,
place = {United States},
year = {1996},
month = {1}
}