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The method of symmetrized bosons with applications to vibrations of octahedral molecules

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.470807· OSTI ID:253456
 [1];  [2];  [3]
  1. Department of Physics, Nanjing University, Nanjing, 210008 (People`s Republic of China)
  2. Center for Theoretical Physics, Yale University, New Haven, Connecticut 06520-8120 (United States)
  3. Department of Physics, Nanjing Normal University, Nanjing, 210097 (People`s Republic of China)

A new technique for constructing representations of point groups, called symmetrized boson representation is introduced. This method is particularly useful when describing vibrations of large molecules and for high overtones. The method is illustrated by applying it to stretching overtones of octahedral molecules, SF{sub 6}, WF{sub 6}, and UF{sub 6} with group {ital O}{sub {ital h}}. {copyright} {ital 1996 American Institute of Physics.}

Research Organization:
Yale University
DOE Contract Number:
FG02-91ER40608
OSTI ID:
253456
Journal Information:
Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 3 Vol. 104; ISSN JCPSA6; ISSN 0021-9606
Country of Publication:
United States
Language:
English

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