Atomically dispersed palladium catalyses Suzuki–Miyaura reactions under phosphine-free conditions

Ding, Guodong; Hao, Leiduan; Xu, Haiping; Wang, Liguang; Chen, Jian; Li, Tao; Tu, Xinman; Zhang, Qiang

doi:10.1038/s42004-020-0289-y

Atomically dispersed palladium catalyses Suzuki–Miyaura reactions under phosphine-free conditions

Journal Article · Fri Apr 03 00:00:00 EDT 2020 · Communications Chemistry

DOI:https://doi.org/10.1038/s42004-020-0289-y· OSTI ID:2470102

^[1]; Hao, Leiduan ^[1]; Xu, Haiping ^[2]; ^[2]; Chen, Jian ^[3]; Li, Tao ^[4]; Tu, Xinman ^[3]; ^[1]

Washington State Univ., Pullman, WA (United States)
Northern Illinois Univ., DeKalb, IL (United States)
Nanchang Hangkong University (China)
Northern Illinois Univ., DeKalb, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Single-atom catalysts have emerged as a new frontier in catalysis science. However, their applications are still limited to small molecule activations in the gas phase, the classic organic transformations catalyzed by single-atom catalysts are still rare. Here, we report the use of a single-atom Pd catalyst for the classic Suzuki–Miyaura carbon–carbon coupling reaction under phosphine-free and open-air conditions at room temperature. The single-atom Pd catalyst is prepared through anchoring Pd on bimetal oxides (Pd-ZnO-ZrO₂). The significant synergetic effect of ZnO and ZrO₂ is observed. The catalyst exhibits high activity and tolerance of a wide scope of substrates. Characterization demonstrates that Pd single atoms are coordinated with two oxygen atoms in Pd-ZnO-ZrO₂ catalyst. The catalyst can be fabricated on a multi-gram scale using a simple in situ co-precipitation method, which endows this catalytic system with great potential in practical applications.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2470102

Journal Information:: Communications Chemistry, Journal Name: Communications Chemistry Journal Issue: 1 Vol. 3; ISSN 2399-3669

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

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