Dioxin-Linked Covalent Organic Framework-Supported Palladium Complex for Rapid Room-Temperature Suzuki–Miyaura Coupling Reaction

Campbell, Allea; Alsudairy, Ziad; Dun, Chaochao; Akram, Fazli; Smith-Petty, Kayla; Ambus, Abrianna; Bingham, Danielle; Dinadayalane, Tandabany; Ingram, Conrad; Li, Xinle

doi:10.3390/cryst13081268

Dioxin-Linked Covalent Organic Framework-Supported Palladium Complex for Rapid Room-Temperature Suzuki–Miyaura Coupling Reaction

Journal Article · Thu Aug 17 00:00:00 EDT 2023 · Crystals

DOI:https://doi.org/10.3390/cryst13081268· OSTI ID:2337856

Campbell, Allea ^[1]; ^[2]; ^[3]; Akram, Fazli ^[2]; Smith-Petty, Kayla ^[2]; Ambus, Abrianna ^[2]; Bingham, Danielle ^[2]; ^[2]; Ingram, Conrad ^[2]; ^[2]

Clark Atlanta Univ., Atlanta, GA (United States); Clark Atlanta university
Clark Atlanta Univ., Atlanta, GA (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Foundry

Covalent organic framework (COF)-supported palladium catalysts have garnered enormous attention for cross-coupling reactions. However, the limited linkage types in COF hosts and their suboptimal catalytic performance have hindered their widespread implementation. Herein, we present the first study immobilizing palladium acetate onto a dioxin-linked COF (Pd/COF-318) through a facile solution impregnation approach. By virtue of its permanent porosity, accessible Pd sites arranged in periodic skeletons, and framework robustness, the resultant Pd/COF-318 exhibits exceptionally high activity and broad substrate scope for the Suzuki–Miyaura coupling reaction between aryl bromides and arylboronic acids at room temperature within an hour, rendering it among the most effective Pd/COF catalysts for Suzuki–Miyaura coupling reactions to date. Moreover, Pd/COF-318 demonstrates excellent recyclability, retaining high activity over five cycles without significant deactivation. The leaching test confirms the heterogeneity of the catalyst. This work uncovers the vast potential of dioxin-linked COFs as catalyst supports for highly active, selective, and durable organometallic catalysis.

View Accepted Manuscript (DOE)

Research Organization:: Clark Atlanta Univ., Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0022000

OSTI ID:: 2337856

Journal Information:: Crystals, Journal Name: Crystals Journal Issue: 8 Vol. 13; ISSN 2073-4352

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
Pd(II) immobilization
Suzuki–Miyaura coupling
covalent organic framework (COF)
dioxin-linked COF

Dioxin-Linked Covalent Organic Framework-Supported Palladium Complex for Rapid Room-Temperature Suzuki–Miyaura Coupling Reaction

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