Efficient Dehydration of 1-Phenylethanol to Styrene by Copper(II) and Zinc(II) Fused-Bisoxazolidine Catalysts

Panda, Aurodeep; Wood, Caroline R.; Brennessel, William W.; Jones, William D.

doi:10.1021/acscatal.4c04572

Efficient Dehydration of 1-Phenylethanol to Styrene by Copper(II) and Zinc(II) Fused-Bisoxazolidine Catalysts

Journal Article · Fri Oct 11 00:00:00 UTC 2024 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.4c04572· OSTI ID:2466278

Panda, Aurodeep ^[1]; Wood, Caroline R. ^[1]; ^[1]; ^[1]

Department of Chemistry, University of Rochester, Rochester, New York 14627, United States

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Research Organization:: University of Rochester, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0020230

OSTI ID:: 2466278

Alternate ID(s):: OSTI ID: 2472830
OSTI ID: 2475763

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 21 Vol. 14; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (18)

New Motifs in Deoxydehydration: Beyond the Realms of Rhenium Petersen, Allan R.; Fristrup, Peter Chemistry – A European Journal, Vol. 23, Issue 43 https://doi.org/10.1002/chem.201701153	journal	June 2017
Catalytic Dehydration of Benzylic Alcohols to Styrenes by Rhenium Complexes Korstanje, Ties J.; Jastrzebski, Johann T. B. H.; Klein Gebbink, Robertus J. M. ChemSusChem, Vol. 3, Issue 6 https://doi.org/10.1002/cssc.201000055	journal	May 2010
Copper(II) Triflate, a New Reagent for Mild Dehydration of Alcohols: Synthetic Usefulness and Mechanistic Insight Laali, Khosrow; Gerzina, Robert J.; Flajnik, Christine M. Helvetica Chimica Acta, Vol. 70, Issue 3 https://doi.org/10.1002/hlca.19870700314	journal	May 1987
Liquid-phase dehydration of 1-phenylethanol over HZSM-5: Kinetic modeling Bertero, Nicolás M.; Apesteguía, Carlos R.; Marchi, Alberto J. Catalysis Communications, Vol. 10, Issue 9 https://doi.org/10.1016/j.catcom.2009.02.018	journal	April 2009
Zeolite Fe-MFI as catalysts in the selective liquid-phase dehydration of 1-phenylethanol Zhang, Wenfeng; Wang, Baorong; Yang, Jianming Catalysis Communications, Vol. 110 https://doi.org/10.1016/j.catcom.2018.03.018	journal	May 2018
Rate Enhancement of Acid-Catalyzed Alcohol Dehydration by Supramolecular Organic Capsules Zhang, Wei; Cheng, Guanhua; Haller, Gary L. ACS Catalysis, Vol. 10, Issue 22 https://doi.org/10.1021/acscatal.0c03625	journal	November 2020
An Iron-Based Dehydration Catalyst for Selective Formation of Styrene Nachtigall, Olaf; VanderWeide, Andrew I.; Brennessel, William W. ACS Catalysis, Vol. 11, Issue 17 https://doi.org/10.1021/acscatal.1c03037	journal	August 2021
Kinetics and Mechanisms of Dehydration of Secondary Alcohols Under Hydrothermal Conditions Bockisch, Christiana; Lorance, Edward D.; Hartnett, Hilairy E. ACS Earth and Space Chemistry, Vol. 2, Issue 8 https://doi.org/10.1021/acsearthspacechem.8b00030	journal	June 2018
Rhenium-Catalyzed Dehydration and Deoxydehydration of Alcohols and Polyols: Opportunities for the Formation of Olefins from Biomass Raju, Suresh; Moret, Marc-Etienne; Klein Gebbink, Robertus J. M. ACS Catalysis, Vol. 5, Issue 1 https://doi.org/10.1021/cs501511x	journal	November 2014
Utilizing the Evans method with a superconducting NMR spectrometer in the undergraduate laboratory Schubert, Ernest M. Journal of Chemical Education, Vol. 69, Issue 1 https://doi.org/10.1021/ed069p62.1	journal	January 1992
Dehydration of Phenyl Ethanol to Styrene under Reactive Distillation Conditions: Understanding the Catalyst Deactivation Lange, Jean-Paul; Otten, Vincent Industrial & Engineering Chemistry Research, Vol. 46, Issue 21 https://doi.org/10.1021/ie070397g	journal	October 2007
Dehydration of Alcohols over Alumina Adkins, Homer; Perkins, Philip P. Journal of the American Chemical Society, Vol. 47, Issue 4 https://doi.org/10.1021/ja01681a036	journal	April 1925
Anhydrous copper(II) sulfate: an efficient catalyst for the liquid-phase dehydration of alcohols Hoffman, Robert V.; Bishop, Richard D.; Fitch, Patricia M. The Journal of Organic Chemistry, Vol. 45, Issue 5 https://doi.org/10.1021/jo01293a030	journal	February 1980
Organic Reactions Catalyzed by Methylrhenium Trioxide: Dehydration, Amination, and Disproportionation of Alcohols Zhu, Zuolin; Espenson, James H. The Journal of Organic Chemistry, Vol. 61, Issue 1 https://doi.org/10.1021/jo951613a	journal	January 1996
Sustainable routes to alkenes: applications of homogeneous catalysis to the dehydration of alcohols to alkenes Ward, Daniel J.; Saccomando, Daniel J.; Walker, Gary Catalysis Science & Technology, Vol. 13, Issue 9 https://doi.org/10.1039/D2CY01690G	journal	January 2023
Catalyst screening for dehydration of primary alcohols from renewable feedstocks under formation of alkenes at energy-saving mild reaction conditions Allahverdiyev, Adil; Yang, Jianing; Gröger, Harald Green Chemistry, Vol. 26, Issue 13 https://doi.org/10.1039/D4GC01038H	journal	January 2024
400. The determination of the paramagnetic susceptibility of substances in solution by nuclear magnetic resonance Evans, D. F. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9590002003	journal	January 1959
Liquid-phase Dehydration of 1-Phenylethanol to Styrene over an Acidic Resin Catalyst Khan, Nazmul Abedin; Hwang, Jin-Soo; Jhung, Sung-Hwa Bulletin of the Korean Chemical Society, Vol. 32, Issue 4 https://doi.org/10.5012/bkcs.2011.32.4.1327	journal	April 2011

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Efficient Dehydration of 1-Phenylethanol to Styrene by Copper(II) and Zinc(II) Fused-Bisoxazolidine Catalysts

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