Harnessing dimethyl ether with ultra-low-grade heat for scaling-resistant brine concentration and fractional crystallization

Foo, Zi Hao; Deshmukh, Akshay; Wilson, Aaron D.; Lienhard, John H.

doi:10.1016/j.cej.2024.151159

Harnessing dimethyl ether with ultra-low-grade heat for scaling-resistant brine concentration and fractional crystallization

Journal Article · Wed Apr 10 04:00:00 EDT 2024 · Chemical Engineering Journal

DOI:https://doi.org/10.1016/j.cej.2024.151159· OSTI ID:2440405

Foo, Zi Hao ^[1]; ^[1]; ^[2]; ^[1]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Solvent-driven separations may enable scalable concentration of hypersaline brines, supporting a circular resource economy from the extraction of lithium and rare earth elements from spent battery and magnet leachates. This work analyses a novel solvent-driven water extraction (SDWE) system employing dimethyl ether (DME) and ultra-low-grade heat for brine concentration and fractional crystallization. SDWE exploits DME’s unique properties: (1) a low dielectric constant that promotes water solubility over charged solutes by a factor of 10³, and (2) a high volatility that facilitate efficient DME reconcentration with ultra-low-grade heat. The techno-economic viability of SDWE is assessed with a computational framework that encompasses a liquid–liquid separator and a solvent concentrator. We integrate the extended universal quasichemical model with the virial equation of state to predict the compositions of the complex three-phase DME-water mixture at vapor–liquid and liquid–liquid equilibrium. Subsequently, we optimize the thermodynamic and economic performance of SDWE, by controlling the interstage flash pressure, heat source temperature, and the number of concentrating stages. DME-based SDWE concentrates an input saline feed to 5.5 M and regenerates over 99 % of the DME using ultra-low-grade heat below 50 °C, with a DME/water selectivity ratio of 125. Here our calculations reveal that optimal performance is achieved at interstage flash pressures of 0.4 – 0.5 bar for heat source temperatures between 323–373 K, with improved exergetic efficiencies at lower temperatures. At a heat source temperature of 323 K and an interstage pressure of 0.489 bar, DME-driven SDWE achieves an optimal thermodynamic efficiency of 20.5 % and a projected specific cost of US$ 1.93 m^-3. These specific costs suggest that SDWE is competitive with commercialized thermal distillation technologies, while mitigating the traditional risks associated with scaling in heat and mass exchangers with hypersaline brines.

View Accepted Manuscript (DOE)

Research Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Materials & Manufacturing Technologies Office (AMMTO)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 2440405

Alternate ID(s):: OSTI ID: 2336840

Report Number(s):: INL/JOU--24-80158-Rev000

Journal Information:: Chemical Engineering Journal, Journal Name: Chemical Engineering Journal Vol. 489; ISSN 1385-8947

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (90)

An empirical correlation of second virial coefficients Tsonopoulos, Constantine AIChE Journal, Vol. 20, Issue 2 https://doi.org/10.1002/aic.690200209	journal	March 1974
Correlation and prediction of thermal properties and phase behaviour for a class of aqueous electrolyte systems Thomsen, Kaj; Rasmussen, Peter; Gani, Rafiqul Chemical Engineering Science, Vol. 51, Issue 14 https://doi.org/10.1016/0009-2509(95)00418-1	journal	July 1996
The Puraq seawater desalination process — An update Lazare, Leon Desalination, Vol. 85, Issue 3 https://doi.org/10.1016/0011-9164(92)80016-3	journal	March 1992
Thermal performance and exergy analysis of a thermal vapor compression desalination system Hamed, O. A.; Zamamiri, A. M.; Aly, S. Energy Conversion and Management, Vol. 37, Issue 4 https://doi.org/10.1016/0196-8904(95)00194-8	journal	April 1996
Fluid phase equilibria in the system dimethyl ether/water from 50 to 220 C and pressures to 500 bar Pozo, M. E.; Streett, W. B. Fluid Phase Equilibria, Vol. 14 https://doi.org/10.1016/0378-3812(83)80128-9	journal	January 1983
Binary vapor-liquid-liquid equilibrium of dimethyl ether - water and mutual solubilities of methyl chloride and water: Experimental results and data reduction Holldorff, H.; Knapp, H. Fluid Phase Equilibria, Vol. 44, Issue 2 https://doi.org/10.1016/0378-3812(88)80111-0	journal	December 1988
Extended UNIQUAC model for correlation and prediction of vapour–liquid–solid equilibria in aqueous salt systems containing non-electrolytes. Part A. Methanol–water–salt systems Iliuta, Maria C.; Thomsen, Kaj; Rasmussen, Peter Chemical Engineering Science, Vol. 55, Issue 14 https://doi.org/10.1016/S0009-2509(99)00534-5	journal	April 2000
A solvent extraction desalination pilot plant Davison, R. R.; Harris, W. B.; Smith, W. H. Desalination, Vol. 3, Issue 1 https://doi.org/10.1016/S0011-9164(00)84020-5	journal	January 1967
The puraq seawater desalination process Lazare, Leon Desalination, Vol. 42, Issue 1 https://doi.org/10.1016/S0011-9164(00)88736-6	journal	July 1982
Second virial coefficients of normal alkanes, linear 1-alkanols (and water), alkyl ethers, and their mixtures Tsonopoulos, Constantine; Dymond, John H. Fluid Phase Equilibria, Vol. 133, Issue 1-2 https://doi.org/10.1016/S0378-3812(97)00058-7	journal	June 1997
Performance of parallel feed multiple effect evaporation system for seawater desalination El-Dessouky, Hisham T.; Ettouney, Hisham M.; Mandani, Faisal Applied Thermal Engineering, Vol. 20, Issue 17 https://doi.org/10.1016/S1359-4311(99)00098-8	journal	December 2000
Salting-out separation and liquid–liquid equilibrium of tertiary butanol aqueous solution Lu, Xiaoping; Han, Pingfan; Zhang, Yaming Chemical Engineering Journal, Vol. 78, Issue 2-3 https://doi.org/10.1016/S1385-8947(00)00153-4	journal	August 2000
Low-carbon lithium extraction makes deep geothermal plants cost-competitive in future energy systems Weinand, Jann Michael; Vandenberg, Ganga; Risch, Stanley Advances in Applied Energy, Vol. 11 https://doi.org/10.1016/j.adapen.2023.100148	journal	September 2023
Primary energy and exergy of desalination technologies in a power-water cogeneration scheme Altmann, Thomas; Robert, Justin; Bouma, Andrew Applied Energy, Vol. 252 https://doi.org/10.1016/j.apenergy.2019.113319	journal	October 2019
A comprehensive review of energy consumption of seawater reverse osmosis desalination plants Kim, Jungbin; Park, Kiho; Yang, Dae Ryook Applied Energy, Vol. 254 https://doi.org/10.1016/j.apenergy.2019.113652	journal	November 2019
Application of solar energy to seawater desalination in a pilot system based on vacuum multi-effect membrane distillation Andrés-Mañas, J. A.; Roca, L.; Ruiz-Aguirre, A. Applied Energy, Vol. 258 https://doi.org/10.1016/j.apenergy.2019.114068	journal	January 2020
Cost effectiveness of conventionally and solar powered monovalent selective electrodialysis for seawater desalination in greenhouses Ahdab, Yvana D.; Schücking, Georg; Rehman, Danyal Applied Energy, Vol. 301 https://doi.org/10.1016/j.apenergy.2021.117425	journal	November 2021
Energy and water without carbon: Integrated desalination and nuclear power at Diablo Canyon Bouma, Andrew T.; Wei, Quantum J.; Parsons, John E. Applied Energy, Vol. 323 https://doi.org/10.1016/j.apenergy.2022.119612	journal	October 2022
A holistic techno-economic evaluation framework for sizing renewable power plant in a hydro-based hybrid generation system Jiang, Jianhua; Ming, Bo; Huang, Qiang Applied Energy, Vol. 348 https://doi.org/10.1016/j.apenergy.2023.121537	journal	October 2023
Mineral scale formation and mitigation on metals and a polymeric heat exchanger surface Kazi, S. N.; Duffy, G. G.; Chen, X. D. Applied Thermal Engineering, Vol. 30, Issue 14-15, p. 2236-2242 https://doi.org/10.1016/j.applthermaleng.2010.06.005	journal	October 2010
Improvement of low-grade heat utilization: Sensitivity mechanism of saturated vapor pressure–temperature in dehumidified materials Che, Chunwen; Yin, Yonggao Applied Thermal Engineering, Vol. 230 https://doi.org/10.1016/j.applthermaleng.2023.120788	journal	July 2023
Evaluation of systems coupling vacuum membrane distillation and solar energy for seawater desalination Mericq, Jean-Pierre; Laborie, Stéphanie; Cabassud, Corinne Chemical Engineering Journal, Vol. 166, Issue 2 https://doi.org/10.1016/j.cej.2010.11.030	journal	January 2011
Transfer learning for solvation free energies: From quantum chemistry to experiments Vermeire, Florence H.; Green, William H. Chemical Engineering Journal, Vol. 418 https://doi.org/10.1016/j.cej.2021.129307	journal	August 2021
A nature-inspired suspended solar evaporator for water desalination of high-salinity brines Luo, Yu-Qiong; Song, Fei; Wu, Jia-Min Chemical Engineering Journal, Vol. 421 https://doi.org/10.1016/j.cej.2021.129824	journal	October 2021
Solar-driven desalination and resource recovery of shale gas wastewater by on-site interfacial evaporation Xie, Wancen; Tang, Peng; Wu, Qidong Chemical Engineering Journal, Vol. 428 https://doi.org/10.1016/j.cej.2021.132624	journal	January 2022
Thermodynamics of solvent-driven water extraction from hypersaline brines using dimethyl ether Deshmukh, Akshay; Foo, Zi Hao; Stetson, Caleb Chemical Engineering Journal, Vol. 434 https://doi.org/10.1016/j.cej.2021.134391	journal	April 2022
Reclamation of aqueous waste solutions polluted with pharmaceutical and pesticide residues by biological-photocatalytic (solar) coupling in situ for agricultural reuse Pérez-Lucas, G.; El Aatik, A.; Aliste, M. Chemical Engineering Journal, Vol. 448 https://doi.org/10.1016/j.cej.2022.137616	journal	November 2022
Interfacial-heating solar desalination of high-salinity brine: Recent progress on salt management and water production He, Fang; You, Huayan; Liu, Xiaojiang Chemical Engineering Journal, Vol. 470 https://doi.org/10.1016/j.cej.2023.144332	journal	August 2023
Extended UNIQUAC model for correlation and prediction of vapor–liquid–liquid–solid equilibria in aqueous salt systems containing non-electrolytes. Part B. Alcohol (ethanol, propanols, butanols)–water–salt systems Thomsen, Kaj; C. Iliuta, Maria; Rasmussen, Peter Chemical Engineering Science, Vol. 59, Issue 17 https://doi.org/10.1016/j.ces.2004.05.024	journal	September 2004
Molecular aspects of temperature swing solvent extraction for brine desalination using imidazole-based solvents Barbosa, Gabriel D.; Bara, Jason E.; Weinman, Steven T. Chemical Engineering Science, Vol. 247 https://doi.org/10.1016/j.ces.2021.116866	journal	January 2022
Recent developments in thermally-driven seawater desalination: Energy efficiency improvement by hybridization of the MED and AD cycles Ng, Kim Choon; Thu, Kyaw; Oh, Seung Jin Desalination, Vol. 356 https://doi.org/10.1016/j.desal.2014.10.025	journal	January 2015
Analysis of saline water desalination by directed solvent extraction using octanoic acid Sanap, Dipak B.; Kadam, Kiran D.; Narayan, Mohan Desalination, Vol. 357 https://doi.org/10.1016/j.desal.2014.11.020	journal	February 2015
The effect of increased top brine temperature on the performance and design of OT-MSF using a case study Roy, Yagnaseni; Thiel, Gregory P.; Antar, Mohamed A. Desalination, Vol. 412 https://doi.org/10.1016/j.desal.2017.02.015	journal	June 2017
Regeneration of dimethyl ether as a draw solute in forward osmosis by utilising thermal energy from a solar pond Monjezi, Alireza Abbassi; Mahood, Hameed B.; Campbell, A. N. Desalination, Vol. 415 https://doi.org/10.1016/j.desal.2017.03.034	journal	August 2017
On thermoeconomic analysis of a single-effect mechanical vapor compression desalination system Jamil, Muhammad Ahmad; Zubair, Syed M. Desalination, Vol. 420 https://doi.org/10.1016/j.desal.2017.07.024	journal	October 2017
A zero liquid discharge system integrating multi-effect distillation and evaporative crystallization for desalination brine treatment Chen, Qian; Burhan, Muhammad; Shahzad, Muhammad Wakil Desalination, Vol. 502 https://doi.org/10.1016/j.desal.2020.114928	journal	April 2021
Making zero-liquid discharge desalination greener: Utilising low-grade heat and vacuum membrane distillation for the regeneration of volatile draw solutes Peters, Christian D.; Hankins, Nicholas P. Desalination, Vol. 507 https://doi.org/10.1016/j.desal.2021.115034	journal	July 2021
Drivers, challenges, and emerging technologies for desalination of high-salinity brines: A critical review Shah, Kinnari M.; Billinge, Ian H.; Chen, Xi Desalination, Vol. 538 https://doi.org/10.1016/j.desal.2022.115827	journal	September 2022
Computational and experimental study of different brines in temperature swing solvent extraction desalination with amine solvents Barbosa, Gabriel D.; Dach, Elizabeth; Liu, Xiaoyang Desalination, Vol. 537 https://doi.org/10.1016/j.desal.2022.115863	journal	September 2022
A mechanical vapor compression regeneration system of potassium formate solution: Model development, experimental verification and performance prediction Zhang, Huafu; Zhang, Zhentao; Tong, Lige Desalination, Vol. 539 https://doi.org/10.1016/j.desal.2022.115940	journal	October 2022
Phase equilibria insights into amine-water-NaCl interactions in liquid-liquid biphasic systems for temperature swing solvent extraction desalination Shah, Kinnari M.; Dach, Elizabeth; Winton, Robert Desalination, Vol. 548 https://doi.org/10.1016/j.desal.2022.116259	journal	February 2023
Component-based, dynamic simulation of a novel once through multistage flash (MSF-OT) solar thermal desalination plant Kaheal, Mohamed M.; Chiasson, Andrew; Alsehli, Mishal Desalination, Vol. 548 https://doi.org/10.1016/j.desal.2022.116290	journal	February 2023
Experimental study of mechanistic factors influencing solvent-driven fractional crystallization of calcium sulfate Jayasinghe, Ashini S.; Stetson, Caleb; Orme, Christopher J. Desalination, Vol. 579 https://doi.org/10.1016/j.desal.2024.117474	journal	June 2024
Modelling scaling growth in heat transfer surfaces and its application on the design of heat exchangers Lugo-Granados, Hebert; Picón Núñez, Martín Energy, Vol. 160 https://doi.org/10.1016/j.energy.2018.07.059	journal	October 2018
Thermodynamic and economic analysis of the integration of Organic Rankine Cycle and Multi-Effect Distillation in waste-heat recovery applications Baccioli, A.; Antonelli, M.; Desideri, U. Energy, Vol. 161 https://doi.org/10.1016/j.energy.2018.07.150	journal	October 2018
Transient and thermo-economic analysis of MED-MVC desalination system Elsayed, Mohamed L.; Mesalhy, Osama; Mohammed, Ramy H. Energy, Vol. 167 https://doi.org/10.1016/j.energy.2018.10.145	journal	January 2019
Perspectives for low-temperature waste heat recovery Xu, Z. Y.; Wang, R. Z.; Yang, Chun Energy, Vol. 176 https://doi.org/10.1016/j.energy.2019.04.001	journal	June 2019
The use of dimethyl ether as an organic extraction solvent for biomass applications in future biorefineries: A user-oriented review Bauer, Manuel C.; Kruse, Andrea Fuel, Vol. 254 https://doi.org/10.1016/j.fuel.2019.115703	journal	October 2019
Class-based separations of mixed solid–liquid systems with condensable solvent washing and extraction: The dilemma of pizza box recycling Lee, Hyeonseok; Stetson, Caleb; Orme, Christopher J. Journal of Cleaner Production, Vol. 426 https://doi.org/10.1016/j.jclepro.2023.139080	journal	November 2023
Heat source and application-dependent levelized cost of decarbonized heat Gilbert, Tristan; Menon, Akanksha K.; Dames, Chris Joule, Vol. 7, Issue 1 https://doi.org/10.1016/j.joule.2022.11.006	journal	January 2023
Multicomponent Fickian solution-diffusion model for osmotic transport through membranes Foo, Zi Hao; Rehman, Danyal; Coombs, Orisa Z. Journal of Membrane Science, Vol. 640 https://doi.org/10.1016/j.memsci.2021.119819	journal	December 2021
High-salinity brine desalination with amine-based temperature swing solvent extraction: A molecular dynamics study Barbosa, Gabriel D.; Liu, Xiaoyang; Bara, Jason E. Journal of Molecular Liquids, Vol. 341 https://doi.org/10.1016/j.molliq.2021.117359	journal	November 2021
Local stress within a granular molecular solvent matrix, a mechanism for individual ion hydration Wilson, Aaron D.; Lee, Hyeonseok; Stetson, Caleb Journal of Molecular Liquids, Vol. 361 https://doi.org/10.1016/j.molliq.2022.119544	journal	September 2022
Low-grade waste heat recovery scenarios: Pyroelectric, thermomagnetic, and thermogalvanic thermal energy harvesting Hur, Sunghoon; Kim, Sangtae; Kim, Hyun-Soo Nano Energy, Vol. 114 https://doi.org/10.1016/j.nanoen.2023.108596	journal	September 2023
Closed-loop pressure retarded osmosis draw solutions and their regeneration processes: A review Zadeh, Ali Etemad; Touati, Khaled; Mulligan, Catherine N. Renewable and Sustainable Energy Reviews, Vol. 159 https://doi.org/10.1016/j.rser.2022.112191	journal	May 2022
Solvent-driven aqueous separations for hypersaline brine concentration and resource recovery Foo, Zi Hao; Stetson, Caleb; Dach, Elizabeth Trends in Chemistry, Vol. 4, Issue 12 https://doi.org/10.1016/j.trechm.2022.09.004	journal	December 2022
Extraction of strategically important elements from brines: Constraints and opportunities Pramanik, Biplob Kumar; Nghiem, Long Duc; Hai, Faisal I. Water Research, Vol. 168 https://doi.org/10.1016/j.watres.2019.115149	journal	January 2020
Minimal and zero liquid discharge with reverse osmosis using low-salt-rejection membranes Wang, Zhangxin; Deshmukh, Akshay; Du, Yuhao Water Research, Vol. 170 https://doi.org/10.1016/j.watres.2019.115317	journal	March 2020
Zero Liquid Discharge of Ultrahigh-Salinity Brines with Temperature Swing Solvent Extraction Boo, Chanhee; Billinge, Ian H.; Chen, Xi Environmental Science & Technology, Vol. 54, Issue 14 https://doi.org/10.1021/acs.est.0c02555	journal	June 2020
Solar Desalination Using Thermally Responsive Ionic Liquids Regenerated with a Photonic Heater Haddad, Andrew Z.; Menon, Akanksha K.; Kang, Hyungmook Environmental Science & Technology, Vol. 55, Issue 5 https://doi.org/10.1021/acs.est.0c06232	journal	February 2021
Comparison of Energy Consumption of Osmotically Assisted Reverse Osmosis and Low-Salt-Rejection Reverse Osmosis for Brine Management Wang, Zhangxin; Feng, Dejun; Chen, Yuanmiaoliang Environmental Science & Technology, Vol. 55, Issue 15 https://doi.org/10.1021/acs.est.1c01638	journal	July 2021
Lithium Concentration from Salt-Lake Brine by Donnan-Enhanced Nanofiltration Foo, Zi Hao; Rehman, Danyal; Bouma, Andrew T. Environmental Science & Technology, Vol. 57, Issue 15 https://doi.org/10.1021/acs.est.2c08584	journal	April 2023
Sustainable Lithium Recovery from Hypersaline Salt-Lakes by Selective Electrodialysis: Transport and Thermodynamics Foo, Zi Hao; Thomas, John B.; Heath, Samuel M. Environmental Science & Technology, Vol. 57, Issue 39 https://doi.org/10.1021/acs.est.3c04472	journal	September 2023
The Global Rise of Zero Liquid Discharge for Wastewater Management: Drivers, Technologies, and Future Directions Tong, Tiezheng; Elimelech, Menachem Environmental Science & Technology, Vol. 50, Issue 13 https://doi.org/10.1021/acs.est.6b01000	journal	June 2016
Solar Evaporator with Controlled Salt Precipitation for Zero Liquid Discharge Desalination Shi, Yusuf; Zhang, Chenlin; Li, Renyuan Environmental Science & Technology, Vol. 52, Issue 20 https://doi.org/10.1021/acs.est.8b03300	journal	September 2018
Advancing the Productivity-Selectivity Trade-off of Temperature Swing Solvent Extraction Desalination with Intermediate-Step Release Shah, Kinnari M.; Billinge, Ian H.; Dach, Elizabeth Environmental Science & Technology Letters, Vol. 10, Issue 10 https://doi.org/10.1021/acs.estlett.3c00616	journal	September 2023
High-Pressure Reverse Osmosis for Energy-Efficient Hypersaline Brine Desalination: Current Status, Design Considerations, and Research Needs Davenport, Douglas M.; Deshmukh, Akshay; Werber, Jay R. Environmental Science & Technology Letters, Vol. 5, Issue 8 https://doi.org/10.1021/acs.estlett.8b00274	journal	June 2018
Membrane-less and Non-Evaporative Desalination of Hypersaline Brines by Temperature Swing Solvent Extraction Boo, Chanhee; Winton, Robert K.; Conway, Kelly M. Environmental Science & Technology Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acs.estlett.9b00182	journal	April 2019
Thermomorphic Hydrophilicity Base-Induced Precipitation for Effective Descaling of Hypersaline Brines Boo, Chanhee; Qi, Heyang; Billinge, Ian H. ACS ES&T Engineering, Vol. 1, Issue 9 https://doi.org/10.1021/acsestengg.1c00160	journal	July 2021
Synergistic Deep Eutectic Solvents for Lithium Extraction Hanada, Takafumi; Goto, Masahiro ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 5 https://doi.org/10.1021/acssuschemeng.0c07606	journal	January 2021
Salting-Out Effect in Aqueous NaCl Solutions: Trends with Size and Polarity of Solute Molecules Endo, Satoshi; Pfennigsdorff, Andrea; Goss, Kai-Uwe Environmental Science & Technology, Vol. 46, Issue 3 https://doi.org/10.1021/es203183z	journal	January 2012
Thermodynamic Cycles for Recovery of Water by Solvent Extraction Davison, R. R.; Hood, D. W. Industrial & Engineering Chemistry Process Design and Development, Vol. 3, Issue 4 https://doi.org/10.1021/i260012a023	journal	October 1964
Liquid−Liquid Extraction of Low-Concentration Aniline from Aqueous Solutions with Salts Wu, Xiaohua; Lei, Zhigang; Li, Qunsheng Industrial & Engineering Chemistry Research, Vol. 49, Issue 6 https://doi.org/10.1021/ie9012979	journal	February 2010
Salt-Induced Liquid–Liquid Phase Separation: Combined Experimental and Theoretical Investigation of Water–Acetonitrile–Salt Mixtures Li, Minglun; Zhuang, Bilin; Lu, Yuyuan Journal of the American Chemical Society, Vol. 143, Issue 2 https://doi.org/10.1021/jacs.0c09420	journal	January 2021
Electrochemical Wastewater Refining: A Vision for Circular Chemical Manufacturing Miller, Dean M.; Abels, Kristen; Guo, Jinyu Journal of the American Chemical Society, Vol. 145, Issue 36 https://doi.org/10.1021/jacs.3c01142	journal	August 2023
Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo Journal of Chemical & Engineering Data, Vol. 38, Issue 3 https://doi.org/10.1021/je00011a031	journal	July 1993
Isothermal Vapor-Liquid Equilibria for Methanol + Ethanol + Water, Methanol + Water, and Ethanol + Water Kurihara, Kiyofumi; Minoura, Tsuyoshi; Takeda, Kouichi Journal of Chemical & Engineering Data, Vol. 40, Issue 3 https://doi.org/10.1021/je00019a033	journal	May 1995
Fluid phase equilibria for the system dimethyl ether/water from 50 to 220.degree.C and pressures to 50.9 MPa Pozo, Maria E.; Streett, William B. Journal of Chemical & Engineering Data, Vol. 29, Issue 3 https://doi.org/10.1021/je00037a030	journal	July 1984
Solvent-driven fractional crystallization for atom-efficient separation of metal salts from permanent magnet leachates Stetson, Caleb; Prodius, Denis; Lee, Hyeonseok Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-31499-7	journal	July 2022
SciPy 1.0: fundamental algorithms for scientific computing in Python Virtanen, Pauli; Gommers, Ralf; Oliphant, Travis E. Nature Methods https://doi.org/10.1038/s41592-019-0686-2	journal	February 2020
Solute displacement in the aqueous phase of water–NaCl–organic ternary mixtures relevant to solvent-driven water treatment McNally, Joshua S.; Foo, Zi Hao; Deshmukh, Akshay RSC Advances, Vol. 10, Issue 49 https://doi.org/10.1039/D0RA06361D	journal	January 2020
Status and advances of deep eutectic solvents for metal separation and recovery Yuan, Ziwen; Liu, Hang; Yong, Wai Fen Green Chemistry, Vol. 24, Issue 5 https://doi.org/10.1039/D1GC03851F	journal	January 2022
Modeling Henry's law and phase separations of water–NaCl–organic mixtures with solvation and ion-pairing Wilson, Aaron D.; Foo, Zi Hao; Jayasinghe, Ashini S. Physical Chemistry Chemical Physics, Vol. 26, Issue 2 https://doi.org/10.1039/D3CP02003G	journal	January 2024
Very low temperature membrane-free desalination by directional solvent extraction Bajpayee, Anurag; Luo, Tengfei; Muto, Andrew Energy & Environmental Science, Vol. 4, Issue 5 https://doi.org/10.1039/c1ee01027a	journal	January 2011
An Equation of State for the Thermodynamic Properties of Dimethyl Ether Wu, Jiangtao; Zhou, Yong; Lemmon, Eric W. Journal of Physical and Chemical Reference Data, Vol. 40, Issue 2 https://doi.org/10.1063/1.3582533	journal	June 2011
Directional solvent for membrane-free water desalination—A molecular level study Luo, Tengfei; Bajpayee, Anurag; Chen, Gang Journal of Applied Physics, Vol. 110, Issue 5 https://doi.org/10.1063/1.3627239	journal	September 2011
An improved model for multiple effect distillation Mistry, Karan H.; Antar, Mohamed A.; Lienhard V., John H. Desalination and Water Treatment, Vol. 51, Issue 4-6 https://doi.org/10.1080/19443994.2012.703383	journal	January 2013
Economic assessment of thermal desalination processes Al-Hengari, Salah; ElMoudir, Walid; El-Bousiffi, Mohamed Ali Desalination and Water Treatment, Vol. 55, Issue 9 https://doi.org/10.1080/19443994.2014.957982	journal	September 2014
Techno-economic comparison of a high-temperature heat pump and an organic Rankine cycle machine for low-grade waste heat recovery in UK industry Law, Richard; Harvey, Adam; Reay, David International Journal of Low-Carbon Technologies, Vol. 8, Issue suppl 1 https://doi.org/10.1093/ijlct/ctt029	journal	June 2013
Exergy Analysis of Directional Solvent Extraction Desalination Process Alotaibi, Sorour; Ibrahim, Osama; Wang, Yu Entropy, Vol. 21, Issue 3 https://doi.org/10.3390/e21030321	journal	March 2019

Similar Records

Electrically Powered High-Salinity Brine Separation Using Dimethyl Ether

Journal Article · Tue Apr 23 00:00:00 EDT 2024 · Industrial and Engineering Chemistry Research · OSTI ID:2440403

Energy and exergy analysis of multi-stage vacuum membrane distillation integrated with mechanical vapor compression

Journal Article · Wed Nov 16 23:00:00 EST 2022 · Separation and Purification Technology · OSTI ID:2228427

Solvent-driven aqueous separations for hypersaline brine concentration and resource recovery

Journal Article · Fri Oct 07 00:00:00 EDT 2022 · Trends in Chemistry · OSTI ID:1924043

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
brine concentration
desalination
dimethyl ether
fractional crystallization
solvent-driven treatment
ultra-low-grade heat
water treatment
zero liquid discharge

Harnessing dimethyl ether with ultra-low-grade heat for scaling-resistant brine concentration and fractional crystallization

Citation Formats

References (90)

Similar Records

Related Subjects