Pd-CeO2 catalyst facilely derived from one-pot generated Pd@Ce-BTC for low temperature CO oxidation

Xie, Shaohua; Tan, Wei; Xu, Yuhan; Wang, Chunying; Feng, Yuan; Ye, Kailong; Ma, Lu; Ehrlich, Steven N.; Li, Yaobin; Zhang, Yan; Dong, Lin; Deng, Jiguang; Liu, Fudong

doi:10.1016/j.jhazmat.2024.133632

Pd-CeO₂ catalyst facilely derived from one-pot generated Pd@Ce-BTC for low temperature CO oxidation

Journal Article · Sun Jan 28 00:00:00 EST 2024 · Journal of Hazardous Materials

DOI:https://doi.org/10.1016/j.jhazmat.2024.133632· OSTI ID:2432574

Xie, Shaohua ^[1]; Tan, Wei ^[2]; Xu, Yuhan ^[3]; Wang, Chunying ^[4]; Feng, Yuan ^[5]; Ye, Kailong ^[1]; Ma, Lu ^[6]; Ehrlich, Steven N. ^[6]; Li, Yaobin ^[4]; Zhang, Yan ^[4]; Dong, Lin ^[7]; Deng, Jiguang ^[5]; Liu, Fudong ^[8]

Univ. of Central Florida, Orlando, FL (United States)
Univ. of Central Florida, Orlando, FL (United States); Nanjing Univ. (China)
Univ. of Central Florida, Orlando, FL (United States); Beijing University of Technology (China)
Chinese Academy of Sciences (CAS), Xiamen (China)
Beijing University of Technology (China)
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Nanjing Univ. (China)
Univ. of Central Florida, Orlando, FL (United States); Univ. of California, Riverside, CA (United States)

Due to the capacity to offer abundant catalytic sites within porous solids featuring high surface areas, metal-organic frameworks (MOFs) and their derivatives have garnered considerable attention as prospective catalysts in environmental catalysis. Here, to promote the industrial application of MOFs, there is an urgent need for an effective and environmental-friendly preparation approach. Breaking through the limitation of the traditional two-step preparation method that Pd was introduced to the already prepared Ce-BTC (Pd/Ce-BTC, BTC = 1, 3, 5 benzenetricarboxylate), in this work, we present a novel one-pot solvothermal method for synthesizing the Pd material supported by Ce-BTC (Pd@Ce-BTC). After pyrolysis in N₂ flow or air flow, Pd-CeO₂ catalysts derived from Pd@Ce-BTC exhibited much higher CO oxidation activity than those from Pd/Ce-BTC. Moreover, Pd/Ce-BTC and Pd@Ce-BTC pyrolyzed in N₂ flow (Pd/Ce-BTC-N and Pd@Ce-BTC-N) could better catalyze the oxidation of CO than Pd/Ce-BTC and Pd@Ce-BTC pyrolyzed in air flow (Pd/Ce-BTC-A and Pd@Ce-BTC-A). Further characterizations revealed that the abundant surface Ce³⁺ species, rich surface adsorbed oxygen species and superior redox properties were the main reasons for the superior CO oxidation activity of Pd@Ce-BTC-N.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Natural Science Foundation of China; National Science Foundation (NSF); Natural Science Foundation of Hebei Province; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: SC0012704

OSTI ID:: 2432574

Report Number(s):: BNL--225952-2024-JAAM

Journal Information:: Journal of Hazardous Materials, Journal Name: Journal of Hazardous Materials Vol. 466; ISSN 0304-3894

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Pd-CeO2 catalyst facilely derived from one-pot generated Pd@Ce-BTC for low temperature CO oxidation

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Pd-CeO₂ catalyst facilely derived from one-pot generated Pd@Ce-BTC for low temperature CO oxidation