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Efficacy of atomic layer deposition of Al2O3 on composite LiNi0.8Mn0.1Co0.1O2 electrode for Li-ion batteries

Journal Article · · Scientific Reports
Not Available
Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States); State University of New York (SUNY), Albany, NY (United States)
Sponsoring Organization:
National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)
Grant/Contract Number:
SC0001135; SC0012704
OSTI ID:
2426982
Alternate ID(s):
OSTI ID: 2472087
Journal Information:
Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 14; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (87)

A Novel Cathode Material with a Concentration-Gradient for High-Energy and Safe Lithium-Ion Batteries journal February 2010
Probing the Mysterious Behavior of Tungsten as a Dopant Inside Pristine Cobalt‐Free Nickel‐Rich Cathode Materials journal February 2023
Enhancing Cycling Stability and Capacity Retention of NMC811 Cathodes by Reengineering Interfaces via Electrochemical Fluorination journal February 2022
Recent Progress and Perspective of Advanced High‐Energy Co‐Less Ni‐Rich Cathodes for Li‐Ion Batteries: Yesterday, Today, and Tomorrow journal September 2020
Polycrystalline and Single Crystalline NCM Cathode Materials—Quantifying Particle Cracking, Active Surface Area, and Lithium Diffusion journal March 2021
Modified High‐Nickel Cathodes with Stable Surface Chemistry Against Ambient Air for Lithium‐Ion Batteries journal April 2018
Compositional and structural analysis of aluminum oxide films prepared by plasma-enhanced chemical vapor deposition journal January 1994
Artificial interface modification of Ni-rich ternary cathode material to enhance electrochemical performance for Li-ion storage through RF-plasma-assisted technique journal May 2023
Low-temperature atomic layer deposited Al2O3 thin film on layer structure cathode for enhanced cycleability in lithium-ion batteries journal April 2010
High-voltage performance of concentration-gradient Li[Ni0.67Co0.15Mn0.18]O2 cathode material for lithium-ion batteries journal December 2010
Potentiostatic intermittent titration technique (PITT) for spherical particles with finite interfacial kinetics journal July 2012
Enhanced elevated-temperature performance of Li(Ni0.8Co0.15Al0.05)O2 electrodes coated with Li2O-2B2O3 glass journal August 2014
Ultrathin Al2O3 Coatings for Improved Cycling Performance and Thermal Stability of LiNi0.5Co0.2Mn0.3O2 Cathode Material journal June 2016
Improving the cycling stability of Ni-rich cathode materials by fabricating surface rock salt phase journal December 2018
Optimized structure stability and cycling performance of LiNi0.8Co0.1Mn0.1O2 through homogeneous nano-thickness Al2O3 coating journal December 2022
An overview of modification strategies to improve LiNi0·8Co0·1Mn0·1O2 (NCM811) cathode performance for automotive lithium-ion batteries journal February 2021
Benchmarking the electrochemical parameters of the LiNi0.8Mn0.1Co0.1O2 positive electrode material for Li-ion batteries journal December 2023
STEM-EELS analysis of improved cycle life of lithium-ion cells with Al2O3-coated LiNi0.8Co0.1Mn0.1O2 cathode active material journal July 2021
An effective strategy to control thickness of Al2O3 coating layer on nickel-rich cathode materials journal January 2021
Dual-anion ionic liquid electrolyte enables stable Ni-rich cathodes in lithium-metal batteries journal August 2021
Comparative studies of zirconium doping and coating on LiNi0.6Co0.2Mn0.2O2 cathode material at elevated temperatures journal August 2018
Investigation of lithium-ion battery degradation mechanisms by combining differential voltage analysis and alternating current impedance journal February 2020
Inhibition of Gas-evolved electrolyte decomposition in cylindrical Li-ion battery cells of Ni-rich layered oxide with a dry coating process without post thermal annealing journal December 2022
Synthesis of full concentration gradient cathode studied by high energy X-ray diffraction journal January 2016
Functionalization of fine particles using atomic and molecular layer deposition journal May 2012
Long-Term Cyclability of NCM-811 at High Voltages in Lithium-Ion Batteries: an In-Depth Diagnostic Study journal August 2020
Delineating the Roles of Mn, Al, and Co by Comparing Three Layered Oxide Cathodes with the Same Nickel Content of 70% for Lithium-Ion Batteries journal January 2022
Surface Stabilization with Fluorine of Layered Ultrahigh-Nickel Oxide Cathodes for Lithium-Ion Batteries journal May 2022
Effect of Annealing on the Structure, Composition, and Electrochemistry of NMC811 Coated with Al2O3 Using an Alkoxide Precursor journal October 2022
Reaction Heterogeneity in LiNi 0.8 Co 0.15 Al 0.05 O 2 Induced by Surface Layer journal August 2017
Insights on the Stabilization of Nickel-Rich Cathode Surfaces: Evidence of Inherent Instabilities in the Presence of Conformal Coatings journal May 2019
Evolution of Structure and Lithium Dynamics in LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) Cathodes during Electrochemical Cycling journal March 2019
Chemical versus Electrochemical Electrolyte Oxidation on NMC111, NMC622, NMC811, LNMO, and Conductive Carbon journal September 2017
Electrolyte-Induced Surface Transformation and Transition-Metal Dissolution of Fully Delithiated LiNi 0.8 Co 0.15 Al 0.05 O 2 journal June 2017
Simultaneous Enhancement of Interfacial Stability and Kinetics of Single-Crystal LiNi 0.6 Mn 0.2 Co 0.2 O 2 through Optimized Surface Coating and Doping journal November 2020
Comprehensive Study of Al- and Zr-Modified LiNi 0.8 Mn 0.1 Co 0.1 O 2 through Synergy of Coating and Doping journal August 2020
Roll-To-Roll Atomic Layer Deposition of Titania Nanocoating on Thermally Stabilizing Lithium Nickel Cobalt Manganese Oxide Cathodes for Lithium Ion Batteries journal November 2020
Insights into the Dual Role of Lithium Difluoro(oxalato)borate Additive in Improving the Electrochemical Performance of NMC811||Graphite Cells journal December 2019
Enhancing the Electrochemical Performance of LiNi 0.70 Co 0.15 Mn 0.15 O 2 Cathodes Using a Practical Solution-Based Al 2 O 3 Coating journal June 2020
Influence of Calendering on the Electrochemical Performance of LiNi 0.9 Mn 0.05 Al 0.05 O 2 Cathodes in Lithium-Ion Cells journal August 2021
Electrolyte Reactivity at the Charged Ni-Rich Cathode Interface and Degradation in Li-Ion Batteries journal March 2022
Surface Reduction Stabilizes the Single-Crystalline Ni-Rich Layered Cathode for Li-Ion Batteries journal August 2022
Enhancing the High-Voltage Cycling Performance of LiNi 0.5 Mn 0.3 Co 0.2 O 2 by Retarding Its Interfacial Reaction with an Electrolyte by Atomic-Layer-Deposited Al 2 O 3 journal November 2015
Mechanisms of LiCoO 2 Cathode Degradation by Reaction with HF and Protection by Thin Oxide Coatings journal October 2015
From Coating to Dopant: How the Transition Metal Composition Affects Alumina Coatings on Ni-Rich Cathodes journal November 2017
Origin of Carbon Dioxide Evolved during Cycling of Nickel-Rich Layered NCM Cathodes journal October 2018
Surface Modification of Ni-Rich LiNi 0.8 Co 0.1 Mn 0.1 O 2 Cathode Material by Tungsten Oxide Coating for Improved Electrochemical Performance in Lithium-Ion Batteries journal April 2019
Li–Nb–O Coating/Substitution Enhances the Electrochemical Performance of the LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC 811) Cathode journal June 2019
What is the Role of Nb in Nickel-Rich Layered Oxide Cathodes for Lithium-Ion Batteries? journal March 2021
Onset Potential for Electrolyte Oxidation and Ni-Rich Cathode Degradation in Lithium-Ion Batteries journal September 2022
What Limits the Capacity of Layered Oxide Cathodes in Lithium Batteries? journal July 2019
Electrode Degradation in Lithium-Ion Batteries journal January 2020
Limitations of Ultrathin Al2O3 Coatings on LNMO Cathodes journal November 2021
Atomic Layer Deposition of Al–W–Fluoride on LiCoO 2 Cathodes: Comparison of Particle- and Electrode-Level Coatings journal July 2017
Metallurgy Inspired Formation of Homogeneous Al 2 O 3 Coating Layer To Improve the Electrochemical Properties of LiNi 0.8 Co 0.1 Mn 0.1 O 2 Cathode Material journal October 2017
Role of Alumina Coating on Li−Ni−Co−Mn−O Particles as Positive Electrode Material for Lithium-Ion Batteries journal July 2005
Polymerization and Functionalization of Membrane Pores for Water Related Applications journal January 2015
Correlation between manganese dissolution and dynamic phase stability in spinel-based lithium-ion battery journal October 2019
Anomalous collapses of Nares Strait ice arches leads to enhanced export of Arctic sea ice journal January 2021
Enabling high energy lithium metal batteries via single-crystal Ni-rich cathode material co-doping strategy journal April 2022
Pathways for practical high-energy long-cycling lithium metal batteries journal February 2019
Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries journal August 2020
Effect of Low-Temperature Al2O3 ALD Coating on Ni-Rich Layered Oxide Composite Cathode on the Long-Term Cycling Performance of Lithium-Ion Batteries journal March 2019
Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion Batteries journal May 2016
A high-capacity Li[Ni 0.8 Co 0.06 Mn 0.14 ]O 2 positive electrode with a dual concentration gradient for next-generation lithium-ion batteries journal January 2015
Quantitative investigation of the decomposition of organic lithium ion battery electrolytes with LC-MS/MS journal January 2017
Room temperature, liquid-phase Al 2 O 3 surface coating approach for Ni-rich layered oxide cathode material journal January 2019
Single-particle measurements of electrochemical kinetics in NMC and NCA cathodes for Li-ion batteries journal January 2018
Optimized atomic layer deposition of homogeneous, conductive Al2O3 coatings for high-nickel NCM containing ready-to-use electrodes journal January 2021
Stabilizing the surface of Ni-rich cathodes via facing-target sputtering for high-performance lithium-ion batteries journal January 2022
Direct measurements of size-independent lithium diffusion and reaction times in individual polycrystalline battery particles journal January 2023
A novel concentration-gradient Li[Ni0.83Co0.07Mn0.10]O2 cathode material for high-energy lithium-ion batteries journal January 2011
Surface degradation of Li1–xNi0.80Co0.15Al0.05O2 cathodes: Correlating charge transfer impedance with surface phase transformations journal June 2016
Providing A Long-term Protection for NCM811 Cathode Material by Al2O3 Coating Layer journal January 2020
Effects of Fluorine Doping on Nickel-Rich Positive Electrode Materials for Lithium-Ion Batteries journal May 2020
Al Substitution for Mn during Co-Precipitation Boosts the Electrochemical Performance of LiNi 0.8 Mn 0.1 Co 0.1 O 2 journal May 2021
Ambient Storage Derived Surface Contamination of NCM811 and NCM111: Performance Implications and Mitigation Strategies journal January 2019
The Impact of Electrolyte Additives and Upper Cut-off Voltage on the Formation of a Rocksalt Surface Layer in LiNi 0.8 Mn 0.1 Co 0.1 O 2 Electrodes journal January 2017
Influence of Coating Protocols on Alumina-Coated Cathode Material: Atomic Layer Deposition versus Wet-Chemical Coating journal January 2019
Analysis of the Interphase on Carbon Black Formed in High Voltage Batteries journal January 2015
Editors' Choice—Capacity Fading Mechanisms of NCM-811 Cathodes in Lithium-Ion Batteries Studied by X-ray Diffraction and Other Diagnostics journal January 2019
Editors' Choice—Growth of Ambient Induced Surface Impurity Species on Layered Positive Electrode Materials and Impact on Electrochemical Performance journal January 2017
Slightly Fluorination of Al 2 O 3 ALD Coating on Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 Electrodes: Interface Reaction to Create Stable Solid Permeable Interphase Layer journal January 2019
impedance.py: A Python package for electrochemical impedance analysis journal August 2020
Surface-Coated LiNi0.8Co0.1Mn0.1O2 (NCM811) Cathode Materials by Al2O3, ZrO2, and Li2O-2B2O3 Thin-Layers for Improving the Performance of Lithium Ion Batteries journal November 2019
Influence of the Ambient Storage of LiNi0.8Mn0.1Co0.1O2 Powder and Electrodes on the Electrochemical Performance in Li-ion Technology journal July 2022
Ultrathin Al2O3 Coating on LiNi0.8Co0.1Mn0.1O2 Cathode Material for Enhanced Cycleability at Extended Voltage Ranges journal February 2019

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