Factoring the contribution of through-space and through-bond interactions to rates of photoinduced electron transfer in donor- spacer-acceptor molecules using ultrafast transient absorption spectroscopy
Conference
·
OSTI ID:242616
- Argonne National Lab., IL (United States). Chemistry Div.
Contributions from through-space and through-bond interactions to the electronic coupling matrix elements for photoinduced charge separation and recombination in linked donor-spacer-acceptor molecules were studied. The molecules consisted of a 4-piperidinyl-naphthalene-1,8-dicarboximide electron donor and a N-(n-octyl)pyromellitimide electron acceptor attached to the 1,5- and 1,8-positions of either anthracene or dibenzobicyclo(2.2.2)octatriene spacers.
- Research Organization:
- Argonne National Lab., IL (United States). Chemistry Div.
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 242616
- Report Number(s):
- ANL/CHM/CP--89998; CONF-9605149--2; ON: DE96011114
- Country of Publication:
- United States
- Language:
- English
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