Core–Shell Gyroid in ABC Bottlebrush Block Terpolymers

Cui, Shuquan; Zhang, Bo; Shen, Liyang; Bates, Frank S.; Lodge, Timothy P.

doi:10.1021/jacs.2c09674

Core–Shell Gyroid in ABC Bottlebrush Block Terpolymers

Journal Article · 14 November 2022 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.2c09674· OSTI ID:2423326

Cui, Shuquan ^[1]; ^[2]; ^[2]; ^[2]; ^[3]

Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, United States
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, United States
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, United States; Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, United States

Not provided.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2423326

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 47 Vol. 144; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (54)

Rapid self-assembly of brush block copolymers to photonic crystals Sveinbjornsson, B. R.; Weitekamp, R. A.; Miyake, G. M. Proceedings of the National Academy of Sciences, Vol. 109, Issue 36, p. 14332-14336 https://doi.org/10.1073/pnas.1213055109	journal	August 2012
An Overview of Materials with Triply Periodic Minimal Surfaces and Related Geometry: From Biological Structures to Self-Assembled Systems Han, Lu; Che, Shunai Advanced Materials, Vol. 30, Issue 17 https://doi.org/10.1002/adma.201705708	journal	March 2018
Polystyrene- block -poly(ethylene oxide) Bottlebrush Block Copolymer Morphology Transitions: Influence of Side Chain Length and Volume Fraction Gai, Yue; Song, Dong-Po; Yavitt, Benjamin M. Macromolecules, Vol. 50, Issue 4 https://doi.org/10.1021/acs.macromol.6b01415	journal	February 2017
Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement Xia, Yan; Olsen, Bradley D.; Kornfield, Julia A. Journal of the American Chemical Society, Vol. 131, Issue 51, p. 18525-18532 https://doi.org/10.1021/ja908379q	journal	December 2009
Bottlebrush polymers with flexible enantiomeric side chains display differential biological properties Nguyen, Hung V. -T.; Jiang, Yivan; Mohapatra, Somesh Nature Chemistry, Vol. 14, Issue 1 https://doi.org/10.1038/s41557-021-00826-8	journal	November 2021
A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile Love, Jennifer A.; Morgan, John P.; Trnka, Tina M. Angewandte Chemie International Edition, Vol. 41, Issue 21 https://doi.org/10.1002/1521-3773(20021104)41:21<4035::AID-ANIE4035>3.0.CO;2-I	journal	November 2002
Synthesis of High Molecular Weight Comb Block Copolymers and Their Assembly into Ordered Morphologies in the Solid State Runge, M. Brett; Bowden, Ned B. Journal of the American Chemical Society, Vol. 129, Issue 34 https://doi.org/10.1021/ja072929q	journal	August 2007
Cubosomes: The Next Generation of Smart Lipid Nanoparticles? Barriga, Hanna M. G.; Holme, Margaret N.; Stevens, Molly M. Angewandte Chemie International Edition, Vol. 58, Issue 10 https://doi.org/10.1002/anie.201804067	journal	March 2019
Single gyroid-structured metallic nanoporous spheres fabricated from double gyroid-forming block copolymers via templated electroless plating Yang, Kai-Chieh; Yao, Cheng-Thai; Huang, Liang-Yu NPG Asia Materials, Vol. 11, Issue 1 https://doi.org/10.1038/s41427-019-0108-z	journal	February 2019
Giant Gyroid and Templates from High-Molecular-Weight Block Copolymer Self-assembly Park, Sungmin; Kim, Yeongsik; Ahn, Hyungju Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep36326	journal	November 2016
Control of Grafting Density and Distribution in Graft Polymers by Living Ring-Opening Metathesis Copolymerization Lin, Tzu-Pin; Chang, Alice B.; Chen, Hsiang-Yun Journal of the American Chemical Society, Vol. 139, Issue 10 https://doi.org/10.1021/jacs.7b00791	journal	March 2017
Morphological Behavior of Compositionally Gradient Polystyrene–Polylactide Bottlebrush Copolymers Jiang, Liuyin; Nykypanchuk, Dmytro; Pastore, Vincent J. Macromolecules, Vol. 52, Issue 21 https://doi.org/10.1021/acs.macromol.9b01756	journal	October 2019
Solvent-free, supersoft and superelastic bottlebrush melts and networks Daniel, William F. M.; Burdyńska, Joanna; Vatankhah-Varnoosfaderani, Mohammad Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4508	journal	November 2015
Morphology of Polystyrene-block-poly(ethylene-alt-propylene) Diblock Copolymers in the Strong-Segregation Limit Sakurai, Shinichi; Hashimoto, Takeji; Fetters, Lewis J. Macromolecules, Vol. 28, Issue 23 https://doi.org/10.1021/ma00127a050	journal	November 1995
Impact of Side-Chain Length on the Self-Assembly of Linear-Bottlebrush Diblock Copolymers Liberman, Lucy; Coughlin, McKenzie L.; Weigand, Steven Macromolecules, Vol. 55, Issue 12 https://doi.org/10.1021/acs.macromol.2c00758	journal	June 2022
Stability of the Double Gyroid Phase in Bottlebrush Diblock Copolymer Melts Park, So Jung; Cheong, Guo Kang; Bates, Frank S. Macromolecules, Vol. 54, Issue 19 https://doi.org/10.1021/acs.macromol.1c01654	journal	September 2021
Core−Shell Gyroid Morphology in a Poly(isoprene- block -styrene- block -dimethylsiloxane) Triblock Copolymer Shefelbine, T. A.; Vigild, M. E.; Matsen, M. W. Journal of the American Chemical Society, Vol. 121, Issue 37 https://doi.org/10.1021/ja991442h	journal	September 1999
Bottlebrush Block Polymers: Quantitative Theory and Experiments Dalsin, Samuel J.; Rions-Maehren, Thomas G.; Beam, Marissa D. ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b05473	journal	October 2015
Polymer-Polymer Phase Behavior Bates, Frank S. Science, Vol. 251, Issue 4996, p. 898-905 https://doi.org/10.1126/science.251.4996.898	journal	February 1991
Ordered Network Phases in Linear Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers Epps, Thomas H.; Cochran, Eric W.; Bailey, Travis S. Macromolecules, Vol. 37, Issue 22 https://doi.org/10.1021/ma048762s	journal	November 2004
Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals Miyake, Garret M.; Weitekamp, Raymond A.; Piunova, Victoria A. Journal of the American Chemical Society, Vol. 134, Issue 34 https://doi.org/10.1021/ja306430k	journal	August 2012
Synthesis of Polystyrene−Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures Rzayev, Javid Macromolecules, Vol. 42, Issue 6 https://doi.org/10.1021/ma802304y	journal	March 2009
Design of ABC Triblock Copolymers near the ODT with the Random Phase Approximation Cochran, Eric W.; Morse, David C.; Bates, Frank S. Macromolecules, Vol. 36, Issue 3 https://doi.org/10.1021/ma020651a	journal	February 2003
Ordering of Sphere Forming SISO Tetrablock Terpolymers on a Simple Hexagonal Lattice Zhang, Jingwen; Sides, Scott; Bates, Frank S. Macromolecules, Vol. 45, Issue 1 https://doi.org/10.1021/ma202196c	journal	December 2011
Self-Assembly of Poly(styrene- block -acrylated epoxidized soybean oil) Star-Brush-Like Block Copolymers Lin, Fang-Yi; Hohmann, Austin D.; Hernández, Nacú Macromolecules, Vol. 53, Issue 18 https://doi.org/10.1021/acs.macromol.0c00441	journal	August 2020
Structure, function, self-assembly, and applications of bottlebrush copolymers Verduzco, Rafael; Li, Xianyu; Pesek, Stacy L. Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/C4CS00329B	journal	January 2015
The ABCs of Block Polymers Chang, Alice B.; Bates, Frank S. Macromolecules, Vol. 53, Issue 8 https://doi.org/10.1021/acs.macromol.0c00174	journal	April 2020
Phase Behavior of Linear-Bottlebrush Block Polymers Liberman, Lucy; Coughlin, McKenzie L.; Weigand, Steven Macromolecules, Vol. 55, Issue 7 https://doi.org/10.1021/acs.macromol.2c00337	journal	March 2022
3D Continuous Water Nanosheet as a Gyroid Minimal Surface Formed by Bicontinuous Cubic Liquid-Crystalline Zwitterions Ichikawa, Takahiro; Kato, Takashi; Ohno, Hiroyuki Journal of the American Chemical Society, Vol. 134, Issue 28 https://doi.org/10.1021/ja304124w	journal	July 2012
Phase Behavior of Binary Polymer Blends Doped with Salt Xie, Shuyi; Lodge, Timothy P. Macromolecules, Vol. 51, Issue 1 https://doi.org/10.1021/acs.macromol.7b02310	journal	December 2017
Reevaluation of Poly(ethylene- alt -propylene)- block -Polydimethylsiloxane Phase Behavior Uncovers Topological Close-Packing and Epitaxial Quasicrystal Growth Lindsay, Aaron P.; Jayaraman, Ashish; Peterson, Austin J. ACS Nano, Vol. 15, Issue 6 https://doi.org/10.1021/acsnano.1c02420	journal	April 2021
Block Copolymers—Designer Soft Materials Bates, Frank S.; Fredrickson, Glenn H. Physics Today, Vol. 52, Issue 2 https://doi.org/10.1063/1.882522	journal	February 1999
Investigation of the Assembly of Comb Block Copolymers in the Solid State Runge, M. Brett; Lipscomb, Corinne E.; Ditzler, Lindsay R. Macromolecules, Vol. 41, Issue 20 https://doi.org/10.1021/ma8009323	journal	October 2008
Impact of intrinsic backbone chain stiffness on the morphologies of bottle-brush diblock copolymers Chremos, Alexandros; Theodorakis, Panagiotis E. Polymer, Vol. 97 https://doi.org/10.1016/j.polymer.2016.05.034	journal	August 2016
Large Pore Size Nanoporous Materials from the Self-Assembly of Asymmetric Bottlebrush Block Copolymers Bolton, Justin; Bailey, Travis S.; Rzayev, Javid Nano Letters, Vol. 11, Issue 3 https://doi.org/10.1021/nl103747m	journal	March 2011
Phase Behavior of Polylactide-Based Liquid Crystalline Brushlike Block Copolymers Choo, Youngwoo; Mahajan, Lalit H.; Gopinadhan, Manesh Macromolecules, Vol. 48, Issue 22 https://doi.org/10.1021/acs.macromol.5b02009	journal	October 2015
Well-ordered nanohybrids and nanoporous materials from gyroid block copolymer templates Hsueh, Han-Yu; Yao, Cheng-Thai; Ho, Rong-Ming Chemical Society Reviews, Vol. 44, Issue 7 https://doi.org/10.1039/C4CS00424H	journal	January 2015
Regulate the Stability of Gyroids of ABC-Type Multiblock Copolymers by Controlling the Packing Frustration Xie, Qiong; Qiang, Yicheng; Li, Weihua ACS Macro Letters, Vol. 9, Issue 2 https://doi.org/10.1021/acsmacrolett.9b00966	journal	January 2020
Theory of Microphase Separation in Block Copolymers Leibler, Ludwik Macromolecules, Vol. 13, Issue 6 https://doi.org/10.1021/ma60078a047	journal	November 1980
Self-Assembly of Symmetric Brush Diblock Copolymers Gu, Weiyin; Huh, June; Hong, Sung Woo ACS Nano, Vol. 7, Issue 3 https://doi.org/10.1021/nn305867d	journal	February 2013
Ordered Bicontinuous Nanoporous and Nanorelief Ceramic Films from Self Assembling Polymer Precursors Chan, Vanessa Z.-H.; Hoffman, James; Lee, Victor Y. Science, Vol. 286, Issue 5445, p. 1716-1719 https://doi.org/10.1126/science.286.5445.1716	journal	November 1999
Single Gyroid Self-Assembled by Linear BABAB Pentablock Copolymer Xie, Qiong; Qiang, Yicheng; Li, Weihua ACS Macro Letters, Vol. 11, Issue 2 https://doi.org/10.1021/acsmacrolett.1c00656	journal	January 2022
50th Anniversary Perspective : Block Polymers—Pure Potential Bates, Christopher M.; Bates, Frank S. Macromolecules, Vol. 50, Issue 1 https://doi.org/10.1021/acs.macromol.6b02355	journal	December 2016
ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties Bates, Christopher M.; Chang, Alice B.; Momčilović, Nebojša Macromolecules, Vol. 48, Issue 14 https://doi.org/10.1021/acs.macromol.5b00880	journal	July 2015
Block copolymer self-assembly–directed synthesis of mesoporous gyroidal superconductors Robbins, Spencer W.; Beaucage, Peter A.; Sai, Hiroaki Science Advances, Vol. 2, Issue 1 https://doi.org/10.1126/sciadv.1501119	journal	January 2016
Surface Structure Dependent Circular Dichroism in Single and Double Gyroid Metamaterials Cote, Bryan M.; Lenart, William R.; Ellison, Christopher J. Advanced Optical Materials, Vol. 10, Issue 13 https://doi.org/10.1002/adom.202200363	journal	May 2022
The standard Gaussian model for block copolymer melts Matsen, M. W. Journal of Physics: Condensed Matter, Vol. 14, Issue 2 https://doi.org/10.1088/0953-8984/14/2/201	journal	December 2001
Block Copolymers: Long-Term Growth with Added Value Lodge, Timothy P. Macromolecules, Vol. 53, Issue 1 https://doi.org/10.1021/acs.macromol.9b02069	journal	January 2020
Graft-through Synthesis and Assembly of Janus Bottlebrush Polymers from A- Branch -B Diblock Macromonomers Kawamoto, Ken; Zhong, Mingjiang; Gadelrab, Karim R. Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b07670	journal	September 2016
Unifying Weak- and Strong-Segregation Block Copolymer Theories Matsen, M. W.; Bates, F. S. Macromolecules, Vol. 29, Issue 4 https://doi.org/10.1021/ma951138i	journal	January 1996
Miniature chiral beamsplitter based on gyroid photonic crystals Turner, Mark D.; Saba, Matthias; Zhang, Qiming Nature Photonics, Vol. 7, Issue 10 https://doi.org/10.1038/nphoton.2013.233	journal	September 2013
Complete Photonic Band Gaps with Nonfrustrated ABC Bottlebrush Block Polymers Lequieu, Joshua; Quah, Timothy; Delaney, Kris T. ACS Macro Letters, Vol. 9, Issue 7 https://doi.org/10.1021/acsmacrolett.0c00380	journal	July 2020
Ordered Network Mesostructures in Block Polymer Materials Meuler, Adam J.; Hillmyer, Marc A.; Bates, Frank S. Macromolecules, Vol. 42, Issue 19 https://doi.org/10.1021/ma9009593	journal	October 2009
Phase Behaviour and Morphologies of Block Copolymers Abetz, Volker; Simon, Peter F. W. Block Copolymers I https://doi.org/10.1007/12_004	book	January 2005

Similar Records

Cylinders-in-Undulating-Lamellae Morphology from ABC Bottlebrush Block Terpolymers

Journal Article · 2024 · Journal of the American Chemical Society · OSTI ID:2581728

Gyroid Structures at Highly Asymmetric Volume Fractions by Blending of ABC Triblock Terpolymer and AB Diblock Copolymer

Journal Article · 2017 · Macromolecules · OSTI ID:1421978

Alternating Gyroid Network Structure in an ABC Miktoarm Terpolymer Comprised of Polystyrene and Two Polydienes

Journal Article · 2021 · Nanomaterials · OSTI ID:1809001

Related Subjects

Chemistry

Core–Shell Gyroid in ABC Bottlebrush Block Terpolymers

Citation Formats

References (54)

Similar Records

Related Subjects