Alternating Gyroid Network Structure in an ABC Miktoarm Terpolymer Comprised of Polystyrene and Two Polydienes

Moschovas, D; Manesi, G.; Karydis-Messinis, A.; Zapsas, G.; Ntetsikas, K.; Zafeiropoulos, N.; Piryazev, A.; Thomas, E.; Hadjichristidis, N.; Ivanov, D.; Avgeropoulos, A.

doi:10.3390/nano10081497

Alternating Gyroid Network Structure in an ABC Miktoarm Terpolymer Comprised of Polystyrene and Two Polydienes

Journal Article · 01 January 2022 · Nanomaterials

DOI:https://doi.org/10.3390/nano10081497· OSTI ID:1809001

Moschovas, D; Manesi, G.; Karydis-Messinis, A.; Zapsas, G.; Ntetsikas, K.; Zafeiropoulos, N.; Piryazev, A.; Thomas, E.; Hadjichristidis, N.; Ivanov, D.; Avgeropoulos, A.

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1809001

Report Number(s):: BNL-221896-2021-JACI

Journal Information:: Nanomaterials, Vol. 10, Issue 8

Country of Publication:: United States

Language:: English

References (61)

Observation of a non-constant mean curvature interface in an ABC triblock copolymer Gido, Samuel P.; Schwark, Dwight W.; Thomas, Edwin L. Macromolecules, Vol. 26, Issue 10 https://doi.org/10.1021/ma00062a040	journal	May 1993
New morphologies in rubber-modified polymers Riess, Gérard; Schlienger, Michel; Marti, Salvatore Journal of Macromolecular Science, Part B, Vol. 17, Issue 2 https://doi.org/10.1080/00222348008213128	journal	February 1980
New ordered morphologies in ABC triblock copolymers Auschra, Clemens; Stadler, Reimund Macromolecules, Vol. 26, Issue 9 https://doi.org/10.1021/ma00061a005	journal	April 1993
Morphology and Thermodynamics of Symmetric Poly(A-block-B-block-C) Triblock Copolymers Stadler, Reimund; Auschra, Clemens; Beckmann, Joerg Macromolecules, Vol. 28, Issue 9 https://doi.org/10.1021/ma00113a010	journal	April 1995
Thermodynamically Controlled Morphological Disorder in a Microphase-Separated Cylindrical Block Copolymer Jung, Karsten; Abetz, Volker; Stadler, Reimund Macromolecules, Vol. 29, Issue 3 https://doi.org/10.1021/ma951307z	journal	January 1996
New Structural Motif in Hexagonally Ordered Cylindrical Ternary (ABC) Block Copolymer Microdomains Brinkmann, Susanne; Stadler, Reimund; Thomas, Edwin L. Macromolecules, Vol. 31, Issue 19 https://doi.org/10.1021/ma980103q	journal	September 1998
Preparation and morphology of triblock copolymers of the ABC type Mogi, Yasuhiro; Kotsuji, Hiroyuki; Kaneko, Yuji Macromolecules, Vol. 25, Issue 20 https://doi.org/10.1021/ma00046a043	journal	September 1992
Tricontinuous morphology of triblock copolymers of the ABC type Mogi, Yasuhiro; Mori, Katsuaki; Matsushita, Yushu Macromolecules, Vol. 25, Issue 20 https://doi.org/10.1021/ma00046a044	journal	September 1992
Superlattice Structures in Morphologies of the ABC Triblock Copolymers Mogi, Yasuhiro; Nomura, Mahito; Kotsuji, Hiroyuki Macromolecules, Vol. 27, Issue 23 https://doi.org/10.1021/ma00101a013	journal	November 1994
Microphase separation of ABC-type triblock copolymers Nakazawa, Hatsumi; Ohta, Takao Macromolecules, Vol. 26, Issue 20 https://doi.org/10.1021/ma00072a031	journal	September 1993
Morphology of ABC Triblock Copolymers Zheng, Wei; Wang, Zhen-Gang Macromolecules, Vol. 28, Issue 21 https://doi.org/10.1021/ma00125a026	journal	October 1995
Structural Characterization of the “Knitting Pattern” in Polystyrene- block -poly(ethylene- co -butylene)- block -poly(methyl methacrylate) Triblock Copolymers Breiner, Ulrike; Krappe, Udo; Thomas, Edwin L. Macromolecules, Vol. 31, Issue 1 https://doi.org/10.1021/ma961550d	journal	January 1998
Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk Hadjichristidis, N.; Iatrou, H.; Pitsikalis, M. Progress in Polymer Science, Vol. 30, Issue 7 https://doi.org/10.1016/j.progpolymsci.2005.04.001	journal	July 2005
Ordered Network Mesostructures in Block Polymer Materials Meuler, Adam J.; Hillmyer, Marc A.; Bates, Frank S. Macromolecules, Vol. 42, Issue 19 https://doi.org/10.1021/ma9009593	journal	October 2009
Periodic area-minimizing surfaces in block copolymers Thomas, Edwin L.; Anderson, David M.; Henkee, Chris S. Nature, Vol. 334, Issue 6183 https://doi.org/10.1038/334598a0	journal	August 1988
Synthesis of a model 3-miktoarm star terpolymer Iatrou, Hermis; Hadjichristidis, Nikos Macromolecules, Vol. 25, Issue 18 https://doi.org/10.1021/ma00044a028	journal	August 1992
Morphology and miscibility of miktoarm styrene-diene copolymers and terpolymers Hadjichristidis, N.; Iatrou, H.; Behal, S. K. Macromolecules, Vol. 26, Issue 21 https://doi.org/10.1021/ma00073a042	journal	October 1993
Chain Architecture and Asymmetry in Copolymer Microphases Milner, Scott T. Macromolecules, Vol. 27, Issue 8 https://doi.org/10.1021/ma00086a057	journal	April 1994
Synthesis and Microphase Separation of Linear Triblock Terpolymers of Polystyrene, High 1,4-Polybutadiene, and High 3,4-Polyisoprene Avgeropoulos, Apostolos; Paraskeva, Stella; Hadjichristidis, Nikos Macromolecules, Vol. 35, Issue 10 https://doi.org/10.1021/ma010824g	journal	April 2002
Successive synthesis of well-defined multiarmed miktoarm star polymers by iterative methodology using living anionic polymerization Ito, Shotaro; Goseki, Raita; Ishizone, Takashi European Polymer Journal, Vol. 49, Issue 9 https://doi.org/10.1016/j.eurpolymj.2013.05.014	journal	September 2013
Preparation and characterization of novel star-shaped copolymers having three different branches Fujimoto, Teruo; Zhang, Hongmin; Kazama, Takeo Polymer, Vol. 33, Issue 10 https://doi.org/10.1016/0032-3861(92)90890-9	journal	January 1992
Synthesis and morphology of ABC heteroarm star terpolymers of polystyrene, polybutadiene and poly(2-vinylpyridine) Hückstädt, Hanno; Göpfert, Astrid; Abetz, Volker Macromolecular Chemistry and Physics, Vol. 201, Issue 3 https://doi.org/10.1002/(SICI)1521-3935(20000201)201:3<296::AID-MACP296>3.0.CO;2-U	journal	February 2000
Synthesis of a polystyrene-arm-polybutadiene-arm-poly(methyl methacrylate) triarm star copolymer Hückstädt, Hanno; Abetz, Volker; Stadler, Reimund Macromolecular Rapid Communications, Vol. 17, Issue 8 https://doi.org/10.1002/marc.1996.030170814	journal	August 1996
Synthesis of Model 3-Miktoarm Star Terpolymers of Styrene, Isoprene, and Methyl Methacrylate Sioula, Stella; Tselikas, Yiannis; Hadjichristidis, Nikos Macromolecules, Vol. 30, Issue 5 https://doi.org/10.1021/ma961447o	journal	March 1997
Microphase separation in block CO- and terpolymers of novel macromolecular architectures Sioula, Stella; Tselikas, Yiannis; Hadjichristidis, Nikos Macromolecular Symposia, Vol. 117, Issue 1 https://doi.org/10.1002/masy.19971170120	journal	May 1997
Synthesis and morphology of model 3-miktoarm star terpolymers of styrene, isoprene and 2-vinyl pyridine Zioga, Agapi; Sioula, Stella; Hadjichristidis, Nikos Macromolecular Symposia, Vol. 157, Issue 1 https://doi.org/10.1002/1521-3900(200007)157:1<239::AID-MASY239>3.0.CO;2-I	journal	July 2000
Controlled Anionic Polymerization of Hexamethylcyclotrisiloxane. Model Linear and Miktoarm Star Co- and Terpolymers of Dimethylsiloxane with Styrene and Isoprene Bellas, Vasilios; Iatrou, Hermis; Hadjichristidis, Nikos Macromolecules, Vol. 33, Issue 19 https://doi.org/10.1021/ma000635i	journal	September 2000
Synthesis of amphiphilic triarm star block copolymers Lambert, Olivier; Reutenauer, Simone; Hurtrez, Guy Polymer Bulletin, Vol. 40, Issue 2-3 https://doi.org/10.1007/s002890050235	journal	February 1998
Synthesis of polystyrene-poly(tert-butyl methacrylate)-poly(ethylene oxide) triarm star block copolymers Nasser-Eddine, Mohamad; Reutenauer, Simone; Delaite, Christelle Journal of Polymer Science Part A: Polymer Chemistry, Vol. 42, Issue 7 https://doi.org/10.1002/pola.20019	journal	January 2004
Synthesis of well-defined functionalized polymers and star branched polymers by means of living anionic polymerization using specially designed 1,1-diphenylethylene derivatives Hirao, Akira; Hayashi, Mayumi; Haraguchi, Naoki Macromolecular Rapid Communications, Vol. 21, Issue 17 https://doi.org/10.1002/1521-3927(20001101)21:17<1171::AID-MARC1171>3.0.CO;2-C	journal	November 2000
Systematic Transitions of Tiling Patterns Formed by ABC Star-Shaped Terpolymers Hayashida, Kenichi; Takano, Atsushi; Arai, Shigeo Macromolecules, Vol. 39, Issue 26 https://doi.org/10.1021/ma0618474	journal	December 2006
Facile synthesis of well-defined ABC miktoarm star terpolymers bearing poly(ε-caprolactone), polystyrene and stereoregular helical poly(phenyl isocyanide) blocks Liu, Chunhua; Mi, Yan-Xin; Wang, Rong-Hua Polymer Chemistry, Vol. 7, Issue 14 https://doi.org/10.1039/C6PY00220J	journal	January 2016
Morphology of model three-component three-arm star-shaped copolymers Okamoto, Shigeru; Hasegawa, Hirokazu; Hashimoto, Takeji Polymer, Vol. 38, Issue 21 https://doi.org/10.1016/S0032-3861(97)00089-X	journal	October 1997
Direct Evidence for Confinement of Junctions to Lines in an 3 Miktoarm Star Terpolymer Microdomain Structure Sioula, Stella; Hadjichristidis, Nikos; Thomas, Edwin L. Macromolecules, Vol. 31, Issue 23 https://doi.org/10.1021/ma980622t	journal	October 1998
Novel 2-Dimensionally Periodic Non-Constant Mean Curvature Morphologies of 3-Miktoarm Star Terpolymers of Styrene, Isoprene, and Methyl Methacrylate Sioula, Stella; Hadjichristidis, Nikos; Thomas, Edwin L. Macromolecules, Vol. 31, Issue 16 https://doi.org/10.1021/ma971848j	journal	August 1998
Structure and Dynamics of Structure Formation in Model Triarm Star Block Copolymers of Polystyrene, Poly(ethylene oxide), and Poly(ε-caprolactone) Floudas, G.; Reiter, G.; Lambert, O. Macromolecules, Vol. 31, Issue 21 https://doi.org/10.1021/ma9806716	journal	October 1998
Jewelry Box of Morphologies with Mesoscopic Length Scales - ABC Star-shaped Terpolymers Matsushita, Yushu; Hayashida, Kenichi; Takano, Atsushi Macromolecular Rapid Communications, Vol. 31, Issue 18 https://doi.org/10.1002/marc.201000169	journal	September 2010
Giant Zincblende Structures Formed by an ABC Star-Shaped Terpolymer/Homopolymer Blend System Hayashida, Kenichi; Takano, Atsushi; Dotera, Tomonari Macromolecules, Vol. 41, Issue 17 https://doi.org/10.1021/ma801367v	journal	August 2008
A Reevaluation of Bicontinuous Cubic Phases in Starblock Copolymers Hajduk, Damian A.; Harper, Paul E.; Gruner, Sol M. Macromolecules, Vol. 28, Issue 7 https://doi.org/10.1021/ma00111a061	journal	March 1995
Architecturally-Induced Tricontinuous Cubic Morphology in Compositionally Symmetric Miktoarm Starblock Copolymers Tselikas, Yiannis; Hadjichristidis, Nikos; Lescanec, Robert L. Macromolecules, Vol. 29, Issue 10 https://doi.org/10.1021/ma9515083	journal	January 1996
A Noncubic Triply Periodic Network Morphology in Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers Bailey, Travis S.; Hardy, Cordell M.; Epps, Thomas H. Macromolecules, Vol. 35, Issue 18 https://doi.org/10.1021/ma011716x	journal	August 2002
Network Phases in ABC Triblock Copolymers Epps, Thomas H.; Cochran, Eric W.; Hardy, Cordell M. Macromolecules, Vol. 37, Issue 19 https://doi.org/10.1021/ma0493426	journal	September 2004
Ordered Network Phases in Linear Poly(isoprene- b -styrene- b -ethylene oxide) Triblock Copolymers Epps, Thomas H.; Cochran, Eric W.; Bailey, Travis S. Macromolecules, Vol. 37, Issue 22 https://doi.org/10.1021/ma048762s	journal	November 2004
Synthesis and Self-Assembly of Amphiphilic Triblock Terpolymers with Complex Macromolecular Architecture Polymeropoulos, George; Zapsas, George; Hadjichristidis, Nikos ACS Macro Letters, Vol. 4, Issue 12 https://doi.org/10.1021/acsmacrolett.5b00795	journal	November 2015
Synthesis and Self‐Assembly of 2 ^nd Generation Dendritic Homopolymers and Copolymers of Polydienes with Different Isomeric Microstructures Avgeropoulos, Apostolos; Rangou, Sofia; Krikorian, Vahik Macromolecular Symposia, Vol. 267, Issue 1 https://doi.org/10.1002/masy.200850703	journal	June 2008
Synthesis of dendritic terpolymers consisting of polystyrene, polybutadiene, and polyisoprene with different isomerisms Rangou, Sofia; Avgeropoulos, Apostolos Journal of Polymer Science Part A: Polymer Chemistry, Vol. 47, Issue 6 https://doi.org/10.1002/pola.23261	journal	March 2009
Segregation of Maghemite Nanoparticles within Symmetric Diblock Copolymer and Triblock Terpolymer Patterns under Solvent Vapor Annealing Zapsas, George; Moschovas, Dimitrios; Ntetsikas, Konstantinos Materials, Vol. 13, Issue 6 https://doi.org/10.3390/ma13061286	journal	March 2020
Immiscible polydiene blocks in linear copolymer and terpolymer sequences Zapsas, George; Moschovas, Dimitrios; Ntetsikas, Konstantinos Journal of Polymer Science Part B: Polymer Physics, Vol. 53, Issue 17 https://doi.org/10.1002/polb.23759	journal	June 2015
Synthesis, characterization and self‐assembly of well‐defined linear heptablock quaterpolymers Ntaras, Christos; Polymeropoulos, George; Zapsas, George Journal of Polymer Science Part B: Polymer Physics, Vol. 54, Issue 15 https://doi.org/10.1002/polb.24058	journal	April 2016
Complex Star Architectures of Well-Defined Polyethylene-Based Co/Terpolymers Ntetsikas, Konstantinos; Zapsas, George; Bilalis, Panayiotis Macromolecules, Vol. 53, Issue 11 https://doi.org/10.1021/acs.macromol.0c00668	journal	May 2020
Synthesis and Self-Assembly of Well-Defined Star and Tadpole Homo-/Co-/Terpolymers Polymeropoulos, George; Bilalis, Panayiotis; Feng, Xueyan Macromolecules, Vol. 52, Issue 15 https://doi.org/10.1021/acs.macromol.9b01013	journal	July 2019
50th Anniversary Perspective : Polymers with Complex Architectures Polymeropoulos, George; Zapsas, George; Ntetsikas, Konstantinos Macromolecules, Vol. 50, Issue 4 https://doi.org/10.1021/acs.macromol.6b02569	journal	February 2017
Anionic polymerization: High vacuum techniques Hadjichristidis, Nikos; Iatrou, Hermis; Pispas, Stergios Journal of Polymer Science Part A: Polymer Chemistry, Vol. 38, Issue 18 https://doi.org/10.1002/1099-0518(20000915)38:18<3211::AID-POLA10>3.0.CO;2-L	journal	January 2000
Tricontinuous Double Gyroid Cubic Phase in Triblock Copolymers of the ABA Type Avgeropoulos, Apostolos; Dair, Benita J.; Hadjichristidis, Nikos Macromolecules, Vol. 30, Issue 19 https://doi.org/10.1021/ma970266z	journal	September 1997
One‐ and two‐dimensional x‐ray detector systems at NSLS beam line X12B, for time‐resolved and static x‐ray‐diffraction studies Capel, M. S.; Smith, G. C.; Yu, B. Review of Scientific Instruments, Vol. 66, Issue 2 https://doi.org/10.1063/1.1145668	journal	February 1995
Small-Angle X-Ray Scattering from Bulk Block Polymers in Disordered State. Estimation of χ-Values from Accidental Thermal Fluctuations Mori, Keiji; Hasegawa, Hifokazu; Hashimoto, Takeji Polymer Journal, Vol. 17, Issue 6 https://doi.org/10.1295/polymj.17.799	journal	June 1985
Synchrotron SAXS study of the microphase separation transition in diblock copolymers Wolff, T.; Burger, C.; Ruland, W. Macromolecules, Vol. 26, Issue 7 https://doi.org/10.1021/ma00059a033	journal	March 1993
The tricontinuous double-gyroid structure from a three-component polymer system Suzuki, Jiro; Seki, Motohiro; Matsushita, Yushu The Journal of Chemical Physics, Vol. 112, Issue 10 https://doi.org/10.1063/1.481089	journal	March 2000
Gyroid versus double-diamond in ABC triblock copolymer melts Matsen, M. W. The Journal of Chemical Physics, Vol. 108, Issue 2 https://doi.org/10.1063/1.475439	journal	January 1998
Enabling nanotechnology with self assembled block copolymer patterns Park, Cheolmin; Yoon, Jongseung; Thomas, Edwin L. Polymer, Vol. 44, Issue 22, p. 6725-6760 https://doi.org/10.1016/j.polymer.2003.08.011	journal	October 2003
Structure, function, and self-assembly of single network gyroid (I4132) photonic crystals in butterfly wing scales Saranathan, V.; Osuji, C. O.; Mochrie, S. G. J. Proceedings of the National Academy of Sciences, Vol. 107, Issue 26 https://doi.org/10.1073/pnas.0909616107	journal	June 2010

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