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Quantification of Stern Layer Water Molecules, Total Potentials, and Energy Densities at Fused Silica:Water Interfaces for Adsorbed Alkali Chlorides, CTAB, PFOA, and PFAS

Journal Article · · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
 [1];  [2];  [2];  [2]
  1. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States; OSTI
  2. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States
Not provided.
Research Organization:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0023342
OSTI ID:
2422236
Journal Information:
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Issue: 40 Vol. 127; ISSN 1089-5639
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (84)

Optical label-free and model-free probe of the surface potential of nanoscale and microscopic objects in aqueous solution journal November 2016
Determination of Surface Potential and Electrical Double-Layer Structure at the Aqueous Electrolyte-Nanoparticle Interface journal January 2016
Ion Transport in Super-Concentrated Aqueous Electrolytes for Lithium-Ion Batteries journal October 2021
Electric quadrupole contribution to the nonresonant background of sum frequency generation at air/liquid interfaces journal May 2011
Structure of Water at Charged Interfaces: A Molecular Dynamics Study journal June 2014
Hyperpolarizability of H2O journal January 1991
Direct Measurement of Charge Reversal on Lipid Bilayers Using Heterodyne-Detected Second Harmonic Generation Spectroscopy journal January 2020
Interfacial Water Structure at Surfactant Concentrations below and above the Critical Micelle Concentration as Revealed by Sum Frequency Generation Vibrational Spectroscopy journal June 2015
New method for determination of surface pKa using second harmonic generation journal October 1993
Surface-specific vibrational spectroscopy of the water/silica interface: screening and interference journal January 2017
Divalent Ion Specific Outcomes on Stern Layer Structure and Total Surface Potential at the Silica:Water Interface journal November 2021
Structures of Water Molecules at the Interfaces of Aqueous Salt Solutions and Silica: Cation Effects journal April 2009
A New Imaginary Term in the Second-Order Nonlinear Susceptibility from Charged Interfaces journal June 2021
Self-assembly and adsorption of cetyltrimethylammonium bromide and didodecyldimethylammonium bromide surfactants at the mica–water interface journal January 2019
Rb + Adsorption at the Quartz(101)–Aqueous Interface: Comparison of Resonant Anomalous X-ray Reflectivity with ab Initio Calculations journal February 2015
Second-Order Vibrational Lineshapes from the Air/Water Interface journal April 2018
Effects on hyperpolarizabilities of molecular interactions in associating liquid mixtures journal September 1976
Adsorption of CTAB on Sapphire-c at High pH: Surface and Zeta Potential Measurements Combined with Sum-Frequency and Second-Harmonic Generation journal March 2022
Innermost Ion Association Configuration Is a Key Structural Descriptor of Ionic Liquids at Electrified Interfaces journal October 2022
pH dependence of the Si/SiO2 interface state density for EOS systems journal October 1985
Second Harmonic and Sum-Frequency Generation from Aqueous Interfaces Is Modulated by Interference journal April 2016
Molecular Dynamics in Physiological Solutions: Force Fields, Alkali Metal Ions, and Ionic Strength journal June 2010
Adsorption of monovalent and divalent cations on planar water-silica interfaces studied by optical reflectivity and Monte Carlo simulations journal August 2011
Unveiling Microscopic Structures of Charged Water Interfaces by Surface-Specific Vibrational Spectroscopy journal January 2016
Bimodal or Trimodal? The Influence of Starting pH on Site Identity and Distribution at the Low Salt Aqueous/Silica Interface journal July 2015
The influence of concentration on specific ion effects at the silica/water interface journal May 2014
Specific Cation Effects on the Bimodal Acid–Base Behavior of the Silica/Water Interface journal April 2012
Electrochemistry and surface-enhanced Raman spectroscopy of CTAB modulated interactions of magnetic nanoparticles with biomolecules journal January 2017
Direct Quantification of Water Surface Charge by Phase-Sensitive Second Harmonic Spectroscopy journal August 2019
The Effects of Hofmeister Cations at Negatively Charged Hydrophilic Surfaces journal February 2012
pH-Dependent Inversion of Hofmeister Trends in the Water Structure of the Electrical Double Layer journal June 2017
Surface chemistry but not aspect ratio mediates the biological toxicity of gold nanorods in vitro and in vivo journal June 2015
Neutron Diffraction Study on the Structure of Hydrated Li + in Dilute Aqueous Solutions journal January 2018
Interface Sensitivity in Electron/Ion Yield X-ray Absorption Spectroscopy: The TiO2–H2O Interface journal October 2021
Surface Potential of a Planar Charged Lipid–Water Interface. What Do Vibrating Plate Methods, Second Harmonic and Sum Frequency Measure? journal September 2018
Probing Heterogeneous Charge Distributions at the α-Al 2 O 3 (0001)/H 2 O Interface journal July 2020
New Insights into χ (3) Measurements: Comparing Nonresonant Second Harmonic Generation and Resonant Sum Frequency Generation at the Silica/Aqueous Electrolyte Interface journal February 2019
Evidence of the Existence of Three Types of Species at the Quartz−Aqueous Solution Interface at pH 0−10: XPS Surface Group Quantification and Surface Complexation Modeling journal March 2002
Communication: Hydration structure and polarization of heavy alkali ions: A first principles molecular dynamics study of Rb + and Cs + journal July 2012
Key activity descriptors of nickel-iron oxygen evolution electrocatalysts in the presence of alkali metal cations journal December 2020
The multipole polarizabilities and hyperpolarizabilities of the water molecule in liquid state: an ab initio study journal July 2001
Surface Decoration of Cetyltrimethyl Ammonium Bromide on SiC Particles and Its Effects on the Co-Deposition Process journal April 2021
Water Structure in the Electrical Double Layer and the Contributions to the Total Interfacial Potential at Different Surface Charge Densities journal August 2022
New Method for Determination of Surface Potential of Microscopic Particles by Second Harmonic Generation journal August 1998
First principles studies of the interactions between alkali metal elements and oxygen-passivated nanopores in graphene journal January 2018
Phase-referenced nonlinear spectroscopy of the α-quartz/water interface journal December 2016
Density functional theory simulation of hydrogen-bonding structure and vibrational densities of states at the quartz (1 0 1)-water interface and its relation to dissolution as a function of solution pH and ionic strength journal May 2014
Study on the Assembly Structure Variation of Cetyltrimethylammonium Bromide on the Surface of Gold Nanoparticles journal March 2020
Quantifying Specific Ion Effects on the Surface Potential and Charge Density at Silica Nanoparticle–Aqueous Electrolyte Interfaces journal July 2016
Cytotoxicity of organic surface coating agents used for nanoparticles synthesis and stability journal June 2015
Charge Regulation in the Electrical Double Layer: Ion Adsorption and Surface Interactions journal December 2015
The Governing Role of Surface Hydration in Ion Specific Adsorption to Silica: An AFM-Based Account of the Hofmeister Universality and Its Reversal journal May 2013
Direct measurement of colloidal forces using an atomic force microscope journal September 1991
Beyond the Gouy–Chapman Model with Heterodyne-Detected Second Harmonic Generation journal April 2019
Nano-Structures and Interactions of Alkali Metals within Silica Gel journal April 2011
XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction journal August 2018
Occurrence and Bioaccumulation Patterns of Per- and Polyfluoroalkyl Substances (PFAS) in the Marine Environment journal April 2023
Evaluation of Surface vs Bulk Contributions in Sum-Frequency Vibrational Spectroscopy Using Reflection and Transmission Geometries journal April 2000
Applications of CTAB modified magnetic nanoparticles for removal of chromium (VI) from contaminated water journal July 2017
Second-order spectral lineshapes from charged interfaces journal October 2017
Anomalously low dielectric constant of confined water journal June 2018
How Ion Pair Formation Drives Adsorption in the Electrical Double Layer: Molecular Dynamics of Charged Silica–Water Interfaces in the Presence of Divalent Alkaline Earth Ions journal September 2021
Effects of Cetyltrimethylammonium Bromide on the Toxicity of Gold Nanorods Both In Vitro and In Vivo: Molecular Origin of Cytotoxicity and Inflammation journal January 2020
Adsorption of Benzyldimethylhexadecylammonium Chloride at the Hydrophobic Silica–Water Interface Studied by Total Internal Reflection Raman Spectroscopy: Effects of Silica Surface Properties and Metal Salt Addition journal August 2013
Operation of chemically sensitive field-effect sensors as a function of the insulator-electrolyte interface journal October 1983
Moving beyond the Solvent-Tip Approximation to Determine Site-Specific Variations of Interfacial Water Structure through 3D Force Microscopy journal December 2020
What the Diffuse Layer (DL) Reveals in Non-Linear SFG Spectroscopy journal July 2018
A set-up for simultaneous measurement of second harmonic generation and streaming potential and some test applications journal November 2018
Structure of Molten Alkali Chlorides at Charged Interfaces and the Prediction and Interpretation of Their X-ray Reflectivity journal November 2021
Towards greener and more sustainable batteries for electrical energy storage journal November 2014
Probing Charged Aqueous Interfaces Near Critical Angles: Effect of Varying Coherence Length journal June 2019
Adsorption of CTAB on Hydrophilic Silica Studied by Linear and Nonlinear Optical Spectroscopy journal December 2008
An Optical Voltmeter for Studying Cetyltrimethylammonium Interacting with Fused Silica/Aqueous Interfaces at High Ionic Strength journal March 2009
Specific Ion Effects on Particle Aggregation Induced by Monovalent Salts within the Hofmeister Series journal March 2015
Revealing Silica’s pH-Dependent Second Harmonic Generation Response with Overcharging journal April 2023
Surface charge density on silica in alkali and alkaline earth chloride electrolyte solutions journal November 2005
A Study of the Hydration of the Alkali Metal Ions in Aqueous Solution journal December 2011
Molecular Dynamics Study of the Electric Double Layer and Nonlinear Spectroscopy at the Amorphous Silica–Water Interface journal June 2019
Structure of the Cetyltrimethylammonium Surfactant at Fused Silica/Aqueous Interfaces Studied by Vibrational Sum Frequency Generation journal March 2010
Macromolecular Structure of Dodecyltrimethylammonium Chloride at the Silica/Water Interface Studied by Sum Frequency Generation Spectroscopy journal October 2015
Quantifying Double-Layer Potentials at Liquid–Gas Interfaces from Vibrational Sum-Frequency Generation journal December 2018
Specifics about Specific Ion Adsorption from Heterodyne-Detected Second Harmonic Generation journal June 2019
Real-time observation of cation exchange kinetics and dynamics at the muscovite-water interface journal June 2017
Oxide– and Silicate–Water Interfaces and Their Roles in Technology and the Environment journal May 2023

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