ELECTRODE POTENTIALS OF THE URANIUM CHLORIDES IN FUSED ALKALI CHLORIDE SOLUTIONS
Journal Article
·
· Canadian Journal of Chemistry (Canada)
Using a silver - silver chloride reference electrode, the electrode potentials of the system U, UCl/sub 3/(KCl, NaCl) and the redox potentials of the system Pt, UCl/sub 3/, UCl/sub 4/(KCl. NaCl) were measured at various concentrations of the uranium chlorides and at temperatures between 650 and 85O deg C. From the results, the electrode potential of the system U. UCl/sub 4/(KCl, NaCl) was calculated. In addition, the activity coeificients and partial molal properties of dilute solutions of UCl/sub 3/ and UCl/sub 4/ in the equimolar mixture of potassium and sodium chlorides were calculated. (auth)
- Research Organization:
- Dept. of Mines and Technical Surveys, Ottawa
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-15-015599
- OSTI ID:
- 4034673
- Journal Information:
- Canadian Journal of Chemistry (Canada), Journal Name: Canadian Journal of Chemistry (Canada) Vol. Vol: 39; ISSN CJCHA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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