Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1 H, 2 H, 31 P, and 119 Sn MAS NMR Techniques

Bakhmutov, Vladimir I.; Elliott, Douglas W.; Contreras-Ramirez, Aida; Drake, Hannah; Zhou, Hong-Cai

doi:10.1021/acs.inorgchem.2c03047

Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State ¹ H, ² H, ³¹ P, and ¹¹⁹ Sn MAS NMR Techniques

Journal Article · Fri Oct 21 04:00:00 EDT 2022 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.2c03047· OSTI ID:2420657

^[1]; Elliott, Douglas W. ^[2]; Contreras-Ramirez, Aida ^[2]; Drake, Hannah ^[2]; ^[3]

Department of Chemistry, Texas A&M University, College Station, Texas77843, United States; OSTI
Department of Chemistry, Texas A&M University, College Station, Texas77843, United States
Department of Chemistry, Texas A&M University, College Station, Texas77843, United States; Department of Materials Science and Engineering, Texas A&M University, College Station, Texas77843-3003, United States

Not provided.

Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0017864

OSTI ID:: 2420657

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 44 Vol. 61; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (43)

A 1H NMR relaxation time study of dynamic processes in zirconium phosphates of differing crystallinities and in related compounds Slade, R.; Forano, C.; Peraio, A. Solid State Ionics, Vol. 61, Issue 1-3 https://doi.org/10.1016/0167-2738(93)90330-6	journal	May 1993
Guest Molecules in a Layered Microporous Tin(IV) Phosphonate–Phosphate Material: Solid State NMR Studies Bakhmutov, Vladimir I.; Elliott, Douglas W.; Contreras, Aida R. The Journal of Physical Chemistry A, Vol. 122, Issue 51 https://doi.org/10.1021/acs.jpca.8b09144	journal	November 2018
CASSCF/CASPT2 Studies of the Lowest States of H₅O₂⁺ Klein, Stéphane; Kochanski, Elise; Strich, Alain The Journal of Physical Chemistry A, Vol. 101, Issue 26 https://doi.org/10.1021/jp970401+	journal	June 1997
Unexpected structural/motional mode of water intercalated into an α‐crystalline zirconium phosphate deduced by ³¹ P and ² H solid‐state MAS NMR spectra Bakhmutov, Vladimir I.; Contreras‐Ramirez, Aida; Banerjee, Sayan Magnetic Resonance in Chemistry, Vol. 60, Issue 2 https://doi.org/10.1002/mrc.5225	journal	October 2021
³¹ P, ¹ H NMR Relaxation and Molecular Mobility in Layered α-Zirconium Phosphate: Variable-Temperature NMR Experiments Bakhmutov, Vladimir I.; Clearfield, Abraham The Journal of Physical Chemistry C, Vol. 121, Issue 1 https://doi.org/10.1021/acs.jpcc.6b11247	journal	December 2016
Selective ion-exchange separation of scandium(III) over iron(III) by crystalline α-zirconium phosphate platelets under acidic conditions Avdibegović, Dženita; Zhang, Wenzhong; Xu, Junhua Separation and Purification Technology, Vol. 215 https://doi.org/10.1016/j.seppur.2018.12.079	journal	May 2019
NMR line shape analysis for two-site exchange in rotating solids Schmidt, Asher; Vega, Shimon The Journal of Chemical Physics, Vol. 87, Issue 12 https://doi.org/10.1063/1.453384	journal	December 1987
An approach to increase the permselectivity and mono-valent ion selectivity of cation-exchange membranes by introduction of amorphous zirconium phosphate nanoparticles Golubenko, D. V.; Karavanova, Yu. A.; Melnikov, S. S. Journal of Membrane Science, Vol. 563 https://doi.org/10.1016/j.memsci.2018.06.024	journal	October 2018
Synthesis Optimization and Crystal Structures of Layered Metal(IV) Hydrogen Phosphates, .alpha.-M(HPO4)2.cntdot.H2O (M = Ti, Sn, Pb) Bruque, Sebastian; Aranda, Miguel A. G.; Losilla, Enrique R. Inorganic Chemistry, Vol. 34, Issue 4 https://doi.org/10.1021/ic00108a021	journal	February 1995
Structure and cation effects on phosphorus-31 NMR chemical shifts and chemical-shift anisotropies of orthophosphates Turner, Gary L.; Smith, Karen Ann; Kirkpatrick, R. James Journal of Magnetic Resonance (1969), Vol. 70, Issue 3 https://doi.org/10.1016/0022-2364(86)90129-0	journal	December 1986
Thermal Transformations and Proton Species in 12-Phosphotungstic Acid Hexahydrate Studied by ¹H and ³¹P Solid-State Nuclear Magnetic Resonance de Oliveira, Marcos; Rodrigues-Filho, Ubirajara Pereira; Schneider, J. The Journal of Physical Chemistry C, Vol. 118, Issue 22 https://doi.org/10.1021/jp501887x	journal	May 2014
2H chemical shift anisotropies from high-field 2H MAS NMR spectroscopy Hauch, Anne; Bildsøe, Henrik; Jakobsen, Hans J. Journal of Magnetic Resonance, Vol. 165, Issue 2 https://doi.org/10.1016/j.jmr.2003.09.007	journal	December 2003
Evolution of Hydrogen-Bond Networks in Protonated Water Clusters H⁺(H₂O)_n (n = 1 to 120) Studied by Cryogenic Ion Mobility-Mass Spectrometry Servage, Kelly A.; Silveira, Joshua A.; Fort, Kyle L. The Journal of Physical Chemistry Letters, Vol. 5, Issue 11 https://doi.org/10.1021/jz500693k	journal	May 2014
Characterization of defects and the local structure in natural and synthetic alunite (K, Na, H3O)Al3(SO4)2(OH)6 by multi-nuclear solid-state NMR spectroscopy Nielsen, U. G.; Majzlan, J.; Phillips, B. American Mineralogist, Vol. 92, Issue 4 https://doi.org/10.2138/am.2007.2414	journal	April 2007
Deuterium Solid-State NMR Study of the Dynamic Behavior of Deuterons and Water Molecules in Solid D₃PW₁₂O₄₀ Stepanov, Alexander G.; Shegai, Timur O.; Luzgin, Mikhail V. The Journal of Physical Chemistry B, Vol. 107, Issue 45 https://doi.org/10.1021/jp030204c	journal	October 2003
Synthesis and characterization of a novel layered tin(IV) phosphate with ion exchange properties Bortun, Anatoly I.; Khainakov, Sergei A.; Bortun, Lyudmila N. Materials Research Bulletin, Vol. 34, Issue 6 https://doi.org/10.1016/S0025-5408(99)00076-8	journal	April 1999
Calculation of the Vibrational Spectra of H ₅ O ₂ ⁺ and Its Deuterium-Substituted Isotopologues by Molecular Dynamics Simulations ^† Kaledin, Martina; Kaledin, Alexey L.; Bowman, Joel M. The Journal of Physical Chemistry A, Vol. 113, Issue 26 https://doi.org/10.1021/jp900737r	journal	July 2009
Carbon-13 NMR distinction between categories of molecular order and disorder in cellulose Newman, Roger H.; Hemmingson, Jacqueline A. Cellulose, Vol. 2, Issue 2 https://doi.org/10.1007/BF00816383	journal	June 1995
A 2H NMR Study of the Phases and Motions in Solid Oxonium Perchlorate, D3O+ClO4- Ratcliffe, C. I. The Journal of Physical Chemistry, Vol. 98, Issue 42 https://doi.org/10.1021/j100093a041	journal	October 1994
Properties and Applications of Metal Phosphates and Pyrophosphates as Proton Conductors Colodrero, Rosario M. P.; Olivera-Pastor, Pascual; Cabeza, Aurelio Materials, Vol. 15, Issue 4 https://doi.org/10.3390/ma15041292	journal	February 2022
Adsorption of aqueous Pb(II), Cu(II), Zn(II) ions by amorphous tin(VI) hydrogen phosphate: an excellent inorganic adsorbent Zhu, C.; Dong, X.; Chen, Z. International Journal of Environmental Science and Technology, Vol. 13, Issue 5 https://doi.org/10.1007/s13762-016-0964-9	journal	March 2016
Characterization and Dynamics of the Different Protonic Species in Hydrated 12-Tungstophosphoric Acid Studied by ² H NMR Kolokolov, Daniil I.; Kazantsev, Maxim S.; Luzgin, Mikhail V. The Journal of Physical Chemistry C, Vol. 118, Issue 51 https://doi.org/10.1021/jp510410k	journal	December 2014
On the textural and morphological properties of crystalline and amorphous α-tin phosphate Velásquez, C.; Rojas, F.; Lara, V. H. Phys. Chem. Chem. Phys., Vol. 6, Issue 19 https://doi.org/10.1039/B403830D	journal	January 2004
Proton Migration on Hydrated Surface of Cubic ZrO ₂ : Ab initio Molecular Dynamics Simulation Sato, Ryuhei; Ohkuma, Shohei; Shibuta, Yasushi The Journal of Physical Chemistry C, Vol. 119, Issue 52 https://doi.org/10.1021/acs.jpcc.5b09026	journal	December 2015
Elucidating structure and dynamics of crystalline α‐zirconium phosphates intercalated with water and methanol by multinuclear solid‐state MAS NMR: A comprehensive NMR approach Bakhmutov, Vladimir I.; Contreras‐Ramirez, Aida; Drake, Hannah Magnetic Resonance in Chemistry, Vol. 60, Issue 6 https://doi.org/10.1002/mrc.5262	journal	March 2022
Insight into Proton Transfer in Phosphotungstic Acid Functionalized Mesoporous Silica-Based Proton Exchange Membrane Fuel Cells Zhou, Yuhua; Yang, Jing; Su, Haibin Journal of the American Chemical Society, Vol. 136, Issue 13 https://doi.org/10.1021/ja411268q	journal	March 2014
Molecular dynamics as studied by static-powder and magic-angle spinning 2H NMR Hologne, Maggy; Hirschinger, Jérôme Solid State Nuclear Magnetic Resonance, Vol. 26, Issue 1 https://doi.org/10.1016/S0926-2040(03)00062-6	journal	August 2004
Theoretical investigations on Zundel cation present inside boron-nitride nanotubes: Effect of confinement and hydrogen bonding Tripathy, Manoj K.; Jena, Naresh K.; Samanta, Alok K. Chemical Physics, Vol. 446 https://doi.org/10.1016/j.chemphys.2014.11.010	journal	January 2015
Probing molecular motions in metal-organic frameworks with solid-state NMR Fu, Yao; Guan, Hanxi; Yin, Jinglin Coordination Chemistry Reviews, Vol. 427 https://doi.org/10.1016/j.ccr.2020.213563	journal	January 2021
Acid sites and oxidation center in molybdena supported on tin oxide as studied by solid-state NMR spectroscopy and theoretical calculation Wang, Jiqing; Su, Yongchao; Xu, Jun Physical Chemistry Chemical Physics, Vol. 8, Issue 20 https://doi.org/10.1039/b516833c	journal	January 2006
Proton NMR Chemical Shifts of Hydronium and Hydroxyl Ions Kresge, A. J. The Journal of Chemical Physics, Vol. 39, Issue 5 https://doi.org/10.1063/1.1734449	journal	September 1963
A comparative study of proton transport properties of metal (IV) phosphates Patel, Heemanshu; Chudasama, Uma Journal of Chemical Sciences, Vol. 119, Issue 1 https://doi.org/10.1007/s12039-007-0006-8	journal	January 2007
In Situ IR Spectrum of 12-Tungstophosphoric Acid Hexahydrate with Planar H₅O₂⁺ Hashimoto, Masaki; Koyano, Gaku; Mizuno, Noritaka The Journal of Physical Chemistry B, Vol. 108, Issue 33 https://doi.org/10.1021/jp0485744	journal	July 2004
Water chemistry at the SnO2(110) surface: the role of inter-molecular interactions and surface geometry Lindan, Philip J. D. Chemical Physics Letters, Vol. 328, Issue 4-6 https://doi.org/10.1016/S0009-2614(00)00963-5	journal	October 2000
Hydronium Ions on the Surface of a Partially Hydrolyzed α-Zirconium Phosphate: Solid-State ²H and ³¹P MAS NMR Evidence Bakhmutov, Vladimir I.; Drake, Hannah F.; Zhou, Hong-Cai Inorganic Chemistry, Vol. 61, Issue 18 https://doi.org/10.1021/acs.inorgchem.2c00838	journal	April 2022
Hydroxylation and molecular adsorption behavior of SnO2 (110) crystal plane Yang, Chunxu; Li, Ziheng; Liu, Jiahui Materials Research Bulletin, Vol. 150 https://doi.org/10.1016/j.materresbull.2022.111787	journal	June 2022
Nuclear quadrupole coupling constants and hydrogen bonding. Molecular orbital study of oxygen-17 and deuterium field gradients in formaldehyde-water hydrogen bonding Butler, Leslie G.; Brown, Theodore L. Journal of the American Chemical Society, Vol. 103, Issue 22 https://doi.org/10.1021/ja00412a001	journal	November 1981
Peculiarities of Quadrupolar Relaxation in Electrolyte Solutions Pavlova, Maria; Chizhik, Vladimir Hyperfine Interactions, Vol. 158, Issue 1-4 https://doi.org/10.1007/s10751-005-9016-4	journal	November 2004
Zirconium Phosphate with a High Surface Area as a Water-Tolerant Solid Acid Kamiya, Yuichi; Sakata, Shoko; Yoshinaga, Yusuke Catalysis Letters, Vol. 94, Issue 1/2 https://doi.org/10.1023/B:CATL.0000019329.82828.e4	journal	April 2004
On the mechanism of diffusion and ionic transport in crystalline insoluble acid salts of tetravalent metals—I Electrical conductance of zirconium bis (monohydrogen ortho-phosphate) monohydrate with a layered structure Alberti, G.; Casciola, M.; Costantino, U. Journal of Inorganic and Nuclear Chemistry, Vol. 40, Issue 3 https://doi.org/10.1016/0022-1902(78)80437-0	journal	January 1978
Zirconium Phosphate: The Pathway from Turbostratic Disorder to Crystallinity Contreras-Ramirez, Aida; Tao, Songsheng; Day, Gregory S. Inorganic Chemistry, Vol. 58, Issue 20 https://doi.org/10.1021/acs.inorgchem.9b02442	journal	October 2019
Dynamic 2H nuclear magnetic resonance of rotating solids Weintraub, O.; Vega, S. Solid State Nuclear Magnetic Resonance, Vol. 4, Issue 6 https://doi.org/10.1016/0926-2040(95)00007-D	journal	August 1995
Theoretical Studies on Proton Transfer among a High Density of Acid Groups: Surface of Zirconium Phosphate with Adsorbed Water Molecules Ogawa, Takaya; Ushiyama, Hiroshi; Lee, Ju-Myeung The Journal of Physical Chemistry C, Vol. 115, Issue 13 https://doi.org/10.1021/jp107767d	journal	March 2011

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Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State ¹ H, ² H, ³¹ P, and ¹¹⁹ Sn MAS NMR Techniques