Innovative biphasic solvent systems for lignocellulosic biorefinery

Cai, Tingting; Liu, Chao; Jiang, Jianchun; Meng, Xianzhi; Ragauskas, Arthur J.; Wang, Kui

doi:10.1016/j.trechm.2024.03.003

Innovative biphasic solvent systems for lignocellulosic biorefinery

Journal Article · Tue Apr 09 00:00:00 EDT 2024 · Trends in Chemistry

DOI:https://doi.org/10.1016/j.trechm.2024.03.003· OSTI ID:2406725

Cai, Tingting ^[1]; Liu, Chao ^[1]; Jiang, Jianchun ^[1]; Meng, Xianzhi ^[2]; ^[3]; Wang, Kui ^[1]

Chinese Academy of Forestry (China); Nanjing Forestry Univ. (China)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Joint Institute for Biological Sciences (JIBS)

Bioconversion of lignocellulosics to ethanol is significantly hindered by biomass recalcitrance and, therefore, often requires a biomass pretreatment step. Furan-based compounds such as furfural (FF) and 5-hydroxymethylfurfural (HMF) are versatile building blocks for fuels and chemicals. However, their production during pretreatment often suffers from low yield and low separation efficiency. Biphasic solvent systems are capable of reducing biomass recalcitrance and extracting furans into the organic phase, thus preventing their degradation, increasing their yield, and allowing much easier separation. The development of a sustainable biphasic solvent system is essential to the furan-driven biorefinery and has drawn significant attention. Finally, this review systematically summarizes recent advances in the development of biphasic solvent systems in lignocellulosic biorefinery for improving the production of liquid fuels and furan-based compounds.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2406725

Journal Information:: Trends in Chemistry, Journal Name: Trends in Chemistry Journal Issue: 5 Vol. 6; ISSN 2589-5974

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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