Recent advances in biomass pretreatment using biphasic solvent systems

Li, Ruolin; Zheng, Yayue; Zhao, Xiaoxue; Yong, Qiang; Meng, Xianzhi; Ragauskas, Arthur; Huang, Caoxing

doi:10.1039/d3gc00271c

Recent advances in biomass pretreatment using biphasic solvent systems

Journal Article · Thu Feb 23 23:00:00 EST 2023 · Green Chemistry

DOI:https://doi.org/10.1039/d3gc00271c· OSTI ID:1999040

Li, Ruolin ^[1]; Zheng, Yayue ^[1]; Zhao, Xiaoxue ^[1]; Yong, Qiang ^[1]; ^[2]; ^[3]; Huang, Caoxing ^[1]

Nanjing Forestry Univ. (China)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

The complexity and recalcitrance of lignocellulosic biomass seriously hinder its subsequent conversion to liquid fuels. To achieve high-value utilization of lignocellulosic biomass, the physical–chemical barrier should be overcome through appropriate pretreatment techniques to improve the accessibility of cellulose for efficient enzymatic hydrolysis. With the rapid emergence of novel pretreatment solvents, biphasic solvent pretreatments represent a nascent and green pretreatment method that has shown outstanding advantages and broad application prospects in the biorefinery of lignocellulosic substrates due to its ability to provide economically viable biomass upgrading, the separation process for products in the solvent phase, and the reutilization of solvents. Herein, different types of biphasic solvents (e.g., 2-methyltetrahydrofuran, methyl isobutyl ketone, 1-butanol, phenoxyethanol, ionic liquids, and deep eutectic solvents) were reviewed systematically, including the fundamental designs of biphasic solvents for biomass pretreatment, their effect on the fractionation of individual biomass components (e.g., carbohydrate and lignin) and the enzymatic hydrolysis performance, and the coproduction of furan and hydroxymethylfurfural. Finally, the main pros and cons of these different biphasic solvent systems are summarized, and the future development direction is also proposed. Finally, this review can provide a reference for designing and selecting effective biphasic pretreatment methods for various types of lignocellulosic biomass.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); National Natural Science Foundation of China (NSFC); Natural Science Foundation of Jiangsu Province

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1999040

Alternate ID(s):: OSTI ID: 1961726

Journal Information:: Green Chemistry, Journal Name: Green Chemistry Journal Issue: 7 Vol. 25; ISSN 1463-9262

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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