Scanning electrochemical probe microscopy investigation of two-dimensional materials

Adanigbo, Pelumi; Romo-Jimenez, Jorge; Zhang, Kaidi; Maroo, Sonal; Bediako, Kwabena; Yu, Yun

doi:10.1088/2053-1583/ad4e45

Scanning electrochemical probe microscopy investigation of two-dimensional materials

Journal Article · Tue Jun 04 00:00:00 EDT 2024 · 2D Materials

DOI:https://doi.org/10.1088/2053-1583/ad4e45· OSTI ID:2396888

Adanigbo, Pelumi ^[1]; Romo-Jimenez, Jorge ^[1]; ^[2]; Maroo, Sonal ^[2]; ^[3]; ^[1]

George Mason Univ., Fairfax, VA (United States)
Univ. of California, Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Research interests in two-dimensional (2D) materials have seen exponential growth owing to their unique and fascinating properties. The highly exposed lattice planes coupled with tunable electronic states of 2D materials have created manifold opportunities in the design of new platforms for energy conversion and sensing applications. Still, challenges in understanding the electrochemical (EC) characteristics of these materials arise from the complexity of both intrinsic and extrinsic heterogeneities that can obscure structure–activity correlations. Scanning EC probe microscopic investigations offer unique benefits in disclosing local EC reactivities at the nanoscale level that are otherwise inaccessible with macroscale methods. This review summarizes recent progress in applying techniques of scanning EC microscopy (SECM) and scanning EC cell microscopy (SECCM) to obtain distinctive insights into the fundamentals of 2D electrodes. We showcase the capabilities of EC microscopies in addressing the roles of defects, thickness, environments, strain, phase, stacking, and many other aspects in the heterogeneous electron transfer, ion transport, electrocatalysis, and photoelectrochemistry of representative 2D materials and their derivatives. Perspectives for the advantages, challenges, and future opportunities of scanning EC probe microscopy investigation of 2D structures are discussed.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC02-05CH11231; SC0021049

OSTI ID:: 2396888

Journal Information:: 2D Materials, Journal Name: 2D Materials Journal Issue: 3 Vol. 11; ISSN 2053-1583

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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