Enhancing the activity of Fe-N-C oxygen reduction reaction electrocatalysts by high-throughput exploration of synthesis parameters

Ferrandon, Magali S.; Park, Jae Hyung; Wang, Xiaoping; Coleman, Eric; Kropf, A. Jeremy; Myers, Deborah J.

doi:10.1016/j.electacta.2023.141850

Enhancing the activity of Fe-N-C oxygen reduction reaction electrocatalysts by high-throughput exploration of synthesis parameters

Journal Article · Wed Jan 04 04:00:00 EST 2023 · Electrochimica Acta

DOI:https://doi.org/10.1016/j.electacta.2023.141850· OSTI ID:2375491

Ferrandon, Magali S. ^[1]; Park, Jae Hyung ^[1]; Wang, Xiaoping ^[1]; Coleman, Eric ^[1]; Kropf, A. Jeremy ^[1]; Myers, Deborah J. ^[1]

Argonne National Laboratory (ANL), Argonne, IL (United States)

Here, the most active class of platinum group metal-free (PGM-free) oxygen reduction reaction (ORR) electrocatalysts in acidic electrolytes are those synthesized by heat treatment of iron, carbon, nitrogen precursors (Fe-N-C). Due to the large number of possible precursor compounds, a small fraction of the synthesis variable space has been explored. Correlation of synthesis variables with Fe speciation and ORR activity has been limited. In this work, an automation platform and a multi-port ball-milling were utilized to evaluate the effects of synthesis variables, such as identity of iron precursor, iron loading, and carbon and nitrogen sources on the ORR activity of iron -nitrogen-carbon catalysts in acidic electrolyte. The ORR activity is correlated with catalyst Fe speciation determined using Fe K-edge X-ray absorption spectroscopy (XAFS).

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Hydrogen Fuel Cell Technologies Office (HFTO); USDOE Office of Science (SC), Office of Workforce Development for Teachers & Scientists (WDTS)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2375491

Journal Information:: Electrochimica Acta, Journal Name: Electrochimica Acta Vol. 441; ISSN 0013-4686

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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