Tricyclononenes and tricyclononadienes as efficient monomers for controlled ROMP: understanding structure–propagation rate relationships and enabling facile post-polymerization modification

Kilgallon, Landon J.; McFadden, Timothy P.; Sigman, Matthew S.; Johnson, Jeremiah A.

doi:10.1039/D4SC01986E

Tricyclononenes and tricyclononadienes as efficient monomers for controlled ROMP: understanding structure–propagation rate relationships and enabling facile post-polymerization modification

Journal Article · Wed Jun 05 00:00:00 EDT 2024 · Chemical Science

DOI:https://doi.org/10.1039/D4SC01986E· OSTI ID:2352764

^[1]; ^[2]; Sigman, Matthew S. ^[2]; ^[3]

Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, USA
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA, Koch Institute for Integrative Cancer Research, Massachusetts Institute of Technology, 500 Main Street, Cambridge, MA 02139, USA, Broad Institute of MIT and Harvard, Cambridge, MA, 02142, USA

A tricyclononene and tricyclononadiene monomer library is studied experimentally and computationally to deepen understanding of structure propagation rate relationships in ROMP. A novel poly(tricyclononadiene) post-ROMP functionalization is explored.

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Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0023457

OSTI ID:: 2352764

Alternate ID(s):: OSTI ID: 2472280

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 22 Vol. 15; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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