Ironing out the transition metal contribution to the magnetism of the n = 3 members of the homologous series Prn+1MnGe3n+1 (M = Fe, Co): Pr4Fe3Ge10 vs. Pr4Co3Ge10

Anderson, Melissa G.; Kyrk, Trent M.; Idrees, Muhammad Zaeem; Stoian, Sebastian A.; McCandless, Gregory T.; Baumbach, Ryan E.; Chan, Julia Y.

doi:10.1016/j.jallcom.2023.172974

Ironing out the transition metal contribution to the magnetism of the n = 3 members of the homologous series Pr_n+1M_nGe_3n+1 (M = Fe, Co): Pr₄Fe₃Ge₁₀ vs. Pr₄Co₃Ge₁₀

Journal Article · Thu Nov 30 00:00:00 EST 2023 · Journal of Alloys and Compounds

DOI:https://doi.org/10.1016/j.jallcom.2023.172974· OSTI ID:2339449

Anderson, Melissa G. ^[1]; Kyrk, Trent M. ^[2]; Idrees, Muhammad Zaeem ^[3]; Stoian, Sebastian A. ^[3]; McCandless, Gregory T. ^[2]; Baumbach, Ryan E. ^[4]; Chan, Julia Y. ^[2]

Baylor Univ., Waco, TX (United States); Baylor University
Baylor Univ., Waco, TX (United States)
Univ. of Idaho, Moscow, ID (United States)
Florida State Univ., Tallahassee, FL (United States)

The Ln_n+1M_nX_3n+1 (Ln = lanthanide, M = transition metal, and X = tetrel) homologous series provides a platform to study collective phenomena in quantum materials. Here, in this work, we compare the crystal growth, structure, and magnetic properties of the n = 3 members of the Pr_n+1M_nGe_3n+1 (M = Fe, Co) analogues, Pr₄Fe₃Ge₁₀ (a = 4.3207 (10) Å, b = 35.523 (8) Å, c = 4.2982 (15) Å, and V = 659.7 (3) Å³) and Pr₄Co₃Ge₁₀ (a = 4.3091 (12) Å, b = 35.750 (9) Å, c = 4.2807 (11) Å, and V = 659.4 (3) Å³). We determined that the ideal flux growth conditions for each compound are highly dependent on the concentration of Sn flux and quench temperature. Pr₄Fe₃Ge₁₀ orders ferromagnetically at 10 K along the c-direction while Pr₄Co₃Ge₁₀ orders antiferromagnetically at 16 K along the b-direction. For both compounds, we observed a magnetic moment higher than that expected for only Pr³⁺ ions (3.58 µ_B/Pr), implying that the transition metal ions contribute to magnetic ordering (3.91, 3.48, and 3.69 µ_B/Pr for Pr₄Fe₃Ge₁₀, and 3.76, 4.04, and 3.83 µ_B/Pr for Pr₄Co₃Ge₁₀ measured along the a-, b-, and c-directions, respectively). Moreover, the zero-field Mössbauer spectrum obtained at 4.2 K for Pr₄Fe₃Ge₁₀ demonstrates that the iron sites participate in magnetic ordering.

View Accepted Manuscript (DOE)

Research Organization:: Baylor Univ., Waco, TX (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Contributing Organization:: National High Magnetic Field Laboratory

Grant/Contract Number:: SC0022068; SC0022854

OSTI ID:: 2339449

Alternate ID(s):: OSTI ID: 2503903
OSTI ID: 2228982

Journal Information:: Journal of Alloys and Compounds, Journal Name: Journal of Alloys and Compounds Vol. 976; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Ironing out the transition metal contribution to the magnetism of the n = 3 members of the homologous series Prn+1MnGe3n+1 (M = Fe, Co): Pr4Fe3Ge10 vs. Pr4Co3Ge10

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Ironing out the transition metal contribution to the magnetism of the n = 3 members of the homologous series Pr_n+1M_nGe_3n+1 (M = Fe, Co): Pr₄Fe₃Ge₁₀ vs. Pr₄Co₃Ge₁₀