Factors Affecting the Electron Conductivity in Single Crystal Li7La3Zr2O12 and Li7P3S11

Demir, Samet; Tekin, Adem; Chan, Yu-Te; Scheurer, Christoph; Reuter, Karsten; Luntz, Alan C.; Voss, Johannes

doi:10.1021/acsaem.3c03092

Factors Affecting the Electron Conductivity in Single Crystal Li₇La₃Zr₂O₁₂ and Li₇P₃S₁₁

Journal Article · Fri Mar 15 00:00:00 EDT 2024 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.3c03092· OSTI ID:2335913

^[1]; Tekin, Adem ^[2]; Chan, Yu-Te ^[3]; Scheurer, Christoph ^[4]; ^[3]; ^[5]; ^[6]

Istanbul Technical University, Istanbul, (Turkey); TÜBİTAK Research Institute for Fundamental Sciences, Gebze, Kocaeli (Turkey); SLAC
Istanbul Technical University, Istanbul, (Turkey); TÜBİTAK Research Institute for Fundamental Sciences, Gebze, Kocaeli (Turkey)
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin (Germany)
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin (Germany); Forschungszentrum Jülich GmbH, Jülich (Germany)
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). SUNCAT Center for Interface Science and Catalysis

One of the serious challenges in all solid-state Li ion batteries is neutral Li intrusion into the solid-state electrolyte that can ultimately cause catastrophic failure. One possibility for this is due to n-type electron conductivity that induces the reaction Li⁺ + e^– → Li⁰ at sites where the potential is less than the Li⁺/Li potential. This paper reports hybrid density functional theory calculations of the electronic conductivity in two prototype single crystalline solid-state electrolytes, cubic Li₇La₃Zr₂O₁₂ (c-LLZO) and Li₇P₃S₁₁ (LPS). The formation energies of important point defects that can affect electron conductivity are determined, and we find that the mechanism of n-type electron conductivity for both solid-state electrolytes is via “small” electron polaron hopping, where the quotes signify that substantial Li ion rearrangement is associated with the polaron formation and its migration. In both electrolytes, the formation energies for the small polarons at the Fermi energy are too high to generate measurable electron conductivity at room temperature. For c-LLZO, the concentration of electron polarons necessary to ensure charge neutrality from positively charged oxygen vacancies formed in synthesis can be significantly higher. Hence, the electron conductivity could be significant when measured with ion-blocking metal electrodes, and we discuss how the synthesis conditions could affect this magnitude. However, in the solid-state battery, these polarons are replaced by negatively charged Li vacancies so that the electron conductivity should remain minimal. For LPS single crystals, the inherent minimal electron conductivity is independent of synthesis conditions. Here we also show that the cost of forming Li⁰ in bulk c-LLZO is enormous due to strain effects so that it could only potentially form at voids, grain boundaries, or around vacancy defects which relax the lattice strain.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); National Center for High Performance Computing of Turkey; Istanbul Technical University

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 2335913

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 6 Vol. 7; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (69)

Materials Data on Li7La3Zr2O12 by Materials Project No authors listed LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States) https://doi.org/10.17188/1313215	dataset	January 2020
Critical Current Density in Solid‐State Lithium Metal Batteries: Mechanism, Influences, and Strategies Lu, Yang; Zhao, Chen‐Zi; Yuan, Hong Advanced Functional Materials, Vol. 31, Issue 18 https://doi.org/10.1002/adfm.202009925	journal	February 2021
Reducing Interfacial Resistance between Garnet-Structured Solid-State Electrolyte and Li-Metal Anode by a Germanium Layer Luo, Wei; Gong, Yunhui; Zhu, Yizhou Advanced Materials, Vol. 29, Issue 22 https://doi.org/10.1002/adma.201606042	journal	April 2017
Lithium/Sulfide All‐Solid‐State Batteries using Sulfide Electrolytes Wu, Jinghua; Liu, Sufu; Han, Fudong Advanced Materials, Vol. 33, Issue 6 https://doi.org/10.1002/adma.202000751	journal	August 2020
The Electronic Conductivity of Single Crystalline Ga‐Stabilized Cubic Li ₇ La ₃ Zr ₂ O ₁₂ : A Technologically Relevant Parameter for All‐Solid‐State Batteries Philipp, Martin; Gadermaier, Bernhard; Posch, Patrick Advanced Materials Interfaces https://doi.org/10.1002/admi.202000450	journal	June 2020
Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes Porz, Lukas; Swamy, Tushar; Sheldon, Brian W. Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201701003	journal	July 2017
Revealing the Short‐Circuiting Mechanism of Garnet‐Based Solid‐State Electrolyte Song, Yongli; Yang, Luyi; Zhao, Wenguang Advanced Energy Materials, Vol. 9, Issue 21 https://doi.org/10.1002/aenm.201900671	journal	April 2019
The Fast Charge Transfer Kinetics of the Lithium Metal Anode on the Garnet‐Type Solid Electrolyte Li _6.25 Al _0.25 La ₃ Zr ₂ O ₁₂ Krauskopf, Thorben; Mogwitz, Boris; Hartmann, Hannah Advanced Energy Materials, Vol. 10, Issue 27 https://doi.org/10.1002/aenm.202000945	journal	June 2020
Relations between the Concentrations of Imperfections in Crystalline Solids Kröger, F. A.; Vink, H. J. Solid State Physics https://doi.org/10.1016/S0081-1947(08)60135-6	book	January 1956
Electrolysis of water on (oxidized) metal surfaces Rossmeisl, J.; Logadottir, A.; Nørskov, J. K. Chemical Physics, Vol. 319, Issue 1-3, p. 178-184 https://doi.org/10.1016/j.chemphys.2005.05.038	journal	December 2005
Practical Challenges and Future Perspectives of All-Solid-State Lithium-Metal Batteries Xia, Shuixin; Wu, Xinsheng; Zhang, Zhichu Chem, Vol. 5, Issue 4 https://doi.org/10.1016/j.chempr.2018.11.013	journal	April 2019
Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte Ren, Yaoyu; Shen, Yang; Lin, Yuanhua Electrochemistry Communications, Vol. 57 https://doi.org/10.1016/j.elecom.2015.05.001	journal	August 2015
Imposed currents in galvanic cells Biesheuvel, P. M.; van Soestbergen, M.; Bazant, M. Z. Electrochimica Acta, Vol. 54, Issue 21 https://doi.org/10.1016/j.electacta.2009.03.073	journal	August 2009
Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte Cheng, Eric Jianfeng; Sharafi, Asma; Sakamoto, Jeff Electrochimica Acta, Vol. 223 https://doi.org/10.1016/j.electacta.2016.12.018	journal	January 2017
A review of the effect of external pressure on all-solid-state batteries Zhang, Fengyu; Guo, Yunna; Zhang, Liqiang eTransportation, Vol. 15 https://doi.org/10.1016/j.etran.2022.100220	journal	January 2023
Preparation and ionic conductivity of Li₇P₃S_11−z glass-ceramic electrolytes Hayashi, Akitoshi; Minami, Keiichi; Ujiie, Satoshi Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49, p. 2670-2673 https://doi.org/10.1016/j.jnoncrysol.2010.04.048	journal	October 2010
Characterizing the Li-Solid-Electrolyte Interface Dynamics as a Function of Stack Pressure and Current Density Wang, Michael J.; Choudhury, Rishav; Sakamoto, Jeff Joule, Vol. 3, Issue 9 https://doi.org/10.1016/j.joule.2019.06.017	journal	September 2019
Controlling dendrite propagation in solid-state batteries with engineered stress Fincher, Cole D.; Athanasiou, Christos E.; Gilgenbach, Colin Joule, Vol. 6, Issue 12 https://doi.org/10.1016/j.joule.2022.10.011	journal	December 2022
Synthesis and structure analysis of tetragonal Li₇La₃Zr₂O₁₂ with the garnet-related type structure Awaka, Junji; Kijima, Norihito; Hayakawa, Hiroshi Journal of Solid State Chemistry, Vol. 182, Issue 8, p. 2046-2052 https://doi.org/10.1016/j.jssc.2009.05.020	journal	August 2009
Li Penetration in Ceramic Solid Electrolytes: Operando Microscopy Analysis of Morphology, Propagation, and Reversibility Kazyak, Eric; Garcia-Mendez, Regina; LePage, William S. Matter, Vol. 2, Issue 4 https://doi.org/10.1016/j.matt.2020.02.008	journal	April 2020
Lithium Dendrite in All-Solid-State Batteries: Growth Mechanisms, Suppression Strategies, and Characterizations Cao, Daxian; Sun, Xiao; Li, Qiang Matter, Vol. 3, Issue 1 https://doi.org/10.1016/j.matt.2020.03.015	journal	July 2020
Understanding metal propagation in solid electrolytes due to mixed ionic-electronic conduction Tu, Qingsong; Shi, Tan; Chakravarthy, Srinath Matter, Vol. 4, Issue 10 https://doi.org/10.1016/j.matt.2021.08.004	journal	October 2021
Crystal structure of a superionic conductor, Li7P3S11 Yamane, H.; Shibata, M.; Shimane, Y. Solid State Ionics, Vol. 178, Issue 15-18 https://doi.org/10.1016/j.ssi.2007.05.020	journal	June 2007
The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂ Rangasamy, Ezhiyl; Wolfenstine, Jeff; Sakamoto, Jeffrey Solid State Ionics, Vol. 206, p. 28-32 https://doi.org/10.1016/j.ssi.2011.10.022	journal	January 2012
Devil is in the Defects: Electronic Conductivity in Solid Electrolytes Gorai, Prashun; Famprikis, Theodosios; Singh, Baltej Chemistry of Materials, Vol. 33, Issue 18 https://doi.org/10.1021/acs.chemmater.1c02345	journal	September 2021
Elastic Properties of the Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO) Yu, Seungho; Schmidt, Robert D.; Garcia-Mendez, Regina Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b03854	journal	December 2015
Oxygen Vacancies in Fast Lithium-Ion Conducting Garnets Kubicek, Markus; Wachter-Welzl, Andreas; Rettenwander, Daniel Chemistry of Materials, Vol. 29, Issue 17 https://doi.org/10.1021/acs.chemmater.7b01281	journal	August 2017
Particle Morphology and Lithium Segregation to Surfaces of the Li ₇ La ₃ Zr ₂ O ₁₂ Solid Electrolyte Canepa, Pieremanuele; Dawson, James A.; Sai Gautam, Gopalakrishnan Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.8b00649	journal	April 2018
Super-Ionic Conduction in Solid-State Li ₇ P ₃ S ₁₁ -Type Sulfide Electrolytes Chang, Donghee; Oh, Kyungbae; Kim, Sung Joo Chemistry of Materials, Vol. 30, Issue 24 https://doi.org/10.1021/acs.chemmater.8b03000	journal	November 2018
Native Defects and their Doping Response in the Lithium Solid Electrolyte Li 7 La 3 Zr 2 O 12 Squires, Alexander G.; Scanlon, David O.; Morgan, Benjamin J. Chemistry of Materials https://doi.org/10.1021/acs.chemmater.9b04319	journal	December 2019
Garnet-Type Solid-State Electrolytes: Materials, Interfaces, and Batteries Wang, Chengwei; Fu, Kun; Kammampata, Sanoop Palakkathodi Chemical Reviews, Vol. 120, Issue 10 https://doi.org/10.1021/acs.chemrev.9b00427	journal	April 2020
Interfacial Challenges in Solid-State Li Ion Batteries Luntz, Alan C.; Voss, Johannes; Reuter, Karsten The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b02352	journal	October 2015
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations Zhu, Yizhou; He, Xingfeng; Mo, Yifei ACS Applied Materials & Interfaces, Vol. 7, Issue 42 https://doi.org/10.1021/acsami.5b07517	journal	October 2015
Insights into the Performance Limits of the Li ₇ P ₃ S ₁₁ Superionic Conductor: A Combined First-Principles and Experimental Study Chu, Iek-Heng; Nguyen, Han; Hy, Sunny ACS Applied Materials & Interfaces, Vol. 8, Issue 12 https://doi.org/10.1021/acsami.6b00833	journal	March 2016
Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries—An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li _6.25 Al _0.25 La ₃ Zr ₂ O ₁₂ Krauskopf, Thorben; Hartmann, Hannah; Zeier, Wolfgang G. ACS Applied Materials & Interfaces, Vol. 11, Issue 15 https://doi.org/10.1021/acsami.9b02537	journal	March 2019
Critical Current Densities for High-Performance All-Solid-State Li-Metal Batteries: Fundamentals, Mechanisms, Interfaces, Materials, and Applications Sarkar, Subhajit; Thangadurai, Venkataraman ACS Energy Letters, Vol. 7, Issue 4 https://doi.org/10.1021/acsenergylett.2c00003	journal	March 2022
Electrochemical Window of the Li-Ion Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ Thompson, Travis; Yu, Seungho; Williams, Logan ACS Energy Letters, Vol. 2, Issue 2 https://doi.org/10.1021/acsenergylett.6b00593	journal	January 2017
Controlling Dendrite Growth in Solid-State Electrolytes Liu, He; Cheng, Xin-Bing; Huang, Jia-Qi ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.9b02660	journal	February 2020
Challenges in Lithium Metal Anodes for Solid-State Batteries Hatzell, Kelsey B.; Chen, Xi Chelsea; Cobb, Corie L. ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.9b02668	journal	February 2020
Lithium Distribution in Aluminum-Free Cubic Li ₇ La ₃ Zr ₂ O ₁₂ Xie, Hui; Alonso, Jose A.; Li, Yutao Chemistry of Materials, Vol. 23, Issue 16 https://doi.org/10.1021/cm201671k	journal	August 2011
A solid future for battery development Janek, Jürgen; Zeier, Wolfgang G. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.141	journal	September 2016
High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes Han, Fudong; Westover, Andrew S.; Yue, Jie Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-018-0312-z	journal	January 2019
Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte Weber, Rochelle; Genovese, Matthew; Louli, A. J. Nature Energy, Vol. 4, Issue 8 https://doi.org/10.1038/s41560-019-0428-9	journal	July 2019
Semi-solid alkali metal electrodes enabling high critical current densities in solid electrolyte batteries Park, Richard J. -Y.; Eschler, Christopher M.; Fincher, Cole D. Nature Energy, Vol. 6, Issue 3 https://doi.org/10.1038/s41560-021-00786-w	journal	March 2021
Author Correction: Mechanical regulation of lithium intrusion probability in garnet solid electrolytes McConohy, Geoff; Xu, Xin; Cui, Teng Nature Energy, Vol. 8, Issue 4 https://doi.org/10.1038/s41560-023-01235-6	journal	March 2023
Direct correlation between void formation and lithium dendrite growth in solid-state electrolytes with interlayers Raj, Vikalp; Venturi, Victor; Kankanallu, Varun R. Nature Materials, Vol. 21, Issue 9 https://doi.org/10.1038/s41563-022-01264-8	journal	June 2022
Tetragonal vs. cubic phase stability in Al – free Ta doped Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO) Thompson, Travis; Wolfenstine, Jeff; Allen, Jan L. J. Mater. Chem. A, Vol. 2, Issue 33 https://doi.org/10.1039/C4TA02099E	journal	January 2014
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries Zhu, Yizhou; He, Xingfeng; Mo, Yifei Journal of Materials Chemistry A, Vol. 4, Issue 9 https://doi.org/10.1039/C5TA08574H	journal	January 2016
Defect chemistry and electrical properties of garnet-type Li ₇ La ₃ Zr ₂ O ₁₂ Zhan, Xiaowen; Lai, Shen; Gobet, Mallory P. Physical Chemistry Chemical Physics, Vol. 20, Issue 3 https://doi.org/10.1039/C7CP06768B	journal	January 2018
Combining Landau–Zener theory and kinetic Monte Carlo sampling for small polaron mobility of doped BiVO ₄ from first-principles Wu, Feng; Ping, Yuan Journal of Materials Chemistry A, Vol. 6, Issue 41 https://doi.org/10.1039/C8TA07437B	journal	January 2018
Inorganic sulfide solid electrolytes for all-solid-state lithium secondary batteries Lian, Peng-Jie; Zhao, Bo-Sheng; Zhang, Lian-Qi Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/C9TA04555D	journal	January 2019
Probing into the origin of an electronic conductivity surge in a garnet solid-state electrolyte Song, Yongli; Yang, Luyi; Tao, Lei Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/C9TA10269H	journal	January 2019
Hybrid functionals based on a screened Coulomb potential Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias The Journal of Chemical Physics, Vol. 118, Issue 18 https://doi.org/10.1063/1.1564060	journal	May 2003
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Improved tetrahedron method for Brillouin-zone integrations Blöchl, Peter E.; Jepsen, O.; Andersen, O. K. Physical Review B, Vol. 49, Issue 23 https://doi.org/10.1103/PhysRevB.49.16223	journal	June 1994
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Exploring the impact of semicore level electronic relaxation on polaron dynamics: An adiabatic ab initio study of FePO 4 Wang, Zi; Bevan, Kirk H. Physical Review B, Vol. 93, Issue 2 https://doi.org/10.1103/PhysRevB.93.024303	journal	January 2016
Fully Ab Initio Finite-Size Corrections for Charged-Defect Supercell Calculations Freysoldt, Christoph; Neugebauer, Jörg; Van de Walle, Chris G. Physical Review Letters, Vol. 102, Issue 1 https://doi.org/10.1103/PhysRevLett.102.016402	journal	January 2009
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Low electronic conductivity of Li7La3Zr2O12 solid electrolytes from first principles Squires, Alexander G.; Davies, Daniel W.; Kim, Sunghyun Physical Review Materials, Vol. 6, Issue 8 https://doi.org/10.1103/PhysRevMaterials.6.085401	journal	August 2022
Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang Science Advances, Vol. 3, Issue 4 https://doi.org/10.1126/sciadv.1601659	journal	April 2017
Handbook of Solid State Batteries Dudney, Nancy J.; West, William C.; Nanda, Jagjit Materials and Energy https://doi.org/10.1142/9487	book	January 2015
Nudged elastic band method for finding minimum energy paths of transitions JÓNsson, Hannes; Mills, Greg; Jacobsen, Karsten W. Proceedings of the International School of Physics, Classical and Quantum Dynamics in Condensed Phase Simulations https://doi.org/10.1142/9789812839664_0016	conference	November 2011
An Analysis of Solid-State Electrodeposition-Induced Metal Plastic Flow and Predictions of Stress States in Solid Ionic Conductor Defects Barroso-Luque, Luis; Tu, Qingsong; Ceder, Gerbrand Journal of The Electrochemical Society, Vol. 167, Issue 2 https://doi.org/10.1149/1945-7111/ab6c5b	journal	January 2020
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.1571707jes	journal	January 2017
Computer Modeling of Crystalline Electrolytes: Lithium Thiophosphates and Phosphates Lepley, N. D.; Holzwarth, N. A. W. Journal of The Electrochemical Society, Vol. 159, Issue 5 https://doi.org/10.1149/2.jes113225	journal	January 2012
Frontiers of solid-state batteries Nanda, Jagjit; Wang, Chongmin; Liu, Ping MRS Bulletin, Vol. 43, Issue 10 https://doi.org/10.1557/mrs.2018.234	journal	October 2018

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Factors Affecting the Electron Conductivity in Single Crystal Li₇La₃Zr₂O₁₂ and Li₇P₃S₁₁