Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide β-diketiminate Halide and Pseudohalide Complexes

Ouellette, Erik T.; Amaro Estrada, Jorge Ivan; Lussier, Daniel J.; Chakarawet, Khetpakorn; Lohrey, Trevor D.; Maron, Laurent; Bergman, Robert G.; Arnold, John

doi:10.1021/acs.organomet.1c00516

Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide β-diketiminate Halide and Pseudohalide Complexes

Journal Article · Fri Nov 12 00:00:00 EST 2021 · Organometallics

DOI:https://doi.org/10.1021/acs.organomet.1c00516· OSTI ID:2326974

^[1]; Amaro Estrada, Jorge Ivan ^[2]; Lussier, Daniel J. ^[3]; ^[3]; ^[1]; ^[2]; ^[3]; ^[1]

University of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
University of Toulouse (France)
University of California, Berkeley, CA (United States)

Here the low-valent rhenium(I) salt Na[Re(η⁵-Cp)(BDI)] (BDI = N,N'-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate) was shown to react with various halide and chalcogenolate reagents, leading to the isolation of a series of rhenium(III)-halide and -pseudohalide complexes: Re(X)(η⁵-Cp)(BDI) (1-X, X = F, Cl, Br, I; 2, X = OTf) and Re(ER)(η⁵-Cp)(BDI) (3-ER, ER = SBn, SeBn, TePh). The ¹H NMR spectra of these complexes displayed sharp resonances shifted several ppm from typical diamagnetic regions, as well as distinct chemical shift trends down both the halide (with the exception of F) and chalcogenolate series, with both Cp and BDI backbone peaks moving downfield with increasing atomic number. Subsequent magnetic susceptibility measurements of the rhenium(III) halides 1-Cl, 1-Br, and 1-I indicated that these complexes display temperature-independent paramagnetism (TIP), with χ_TIPvalues of 7.41(44) × 10^-4 to 1.50(51) × 10^-3cm³mol^-1. Multireference complete active space self-consistent field (CASSCF) computations incorporating spin-orbit state mixing revealed small energy separations (1.7-3.0 kcal/mol) between thermally isolated ground states and the first excited spin-orbit states for the rhenium halides, confirming that low-lying excited states are responsible for the observed TIP behavior.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: National Institutes of Health (NIH); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2326974

Journal Information:: Organometallics, Journal Name: Organometallics Journal Issue: 22 Vol. 41; ISSN 0276-7333

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (56)

Regio- and Stereoselective Nucleophilic Substitutions of Chiral Allylic Alcohol Rhenium Complexes Legoupy, Stéphanie; Crévisy, Christophe; Guillemin, Jean-Claude Chemistry - A European Journal, Vol. 4, Issue 11 https://doi.org/10.1002/(SICI)1521-3765(19981102)4:11<2162::AID-CHEM2162>3.0.CO;2-Y	journal	November 1998
Olefin Metatheses in Metal Coordination Spheres: Versatile New Strategies for the Construction of Novel Monohapto or Polyhapto Cyclic, Macrocyclic, Polymacrocyclic, and Bridging Ligands Ruwwe, Johannes; Martín-Alvarez, José Miguel; Horn, Clemens R. Chemistry - A European Journal, Vol. 7, Issue 18 https://doi.org/10.1002/1521-3765(20010917)7:18<3931::AID-CHEM3931>3.0.CO;2-Y	journal	September 2001
Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John Angewandte Chemie International Edition, Vol. 56, Issue 45 https://doi.org/10.1002/anie.201707957	journal	October 2017
Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen Schendzielorz, Florian; Finger, Markus; Abbenseth, Josh Angewandte Chemie International Edition, Vol. 58, Issue 3 https://doi.org/10.1002/anie.201812125	journal	December 2018
Syntheses, Structures and Reactivities of [CpTc(CO) ₃ X] ⁺ and [CpRe(CO) ₃ X] ⁺ Zobi, Fabio; Spingler, Bernhard; Alberto, Roger European Journal of Inorganic Chemistry, Vol. 2008, Issue 27 https://doi.org/10.1002/ejic.200800258	journal	September 2008
Photochemical Reactions of [(η ⁵ ‐C ₅ R ₅ )Re(CO) ₃ ] (R = Me or H) with Aryl Halides in Benzene: Stoichiometric Formation of Biphenyl Zhu, Bolin; Huang, Xinwei; Hao, Xiaoting European Journal of Inorganic Chemistry, Vol. 2014, Issue 34 https://doi.org/10.1002/ejic.201402793	journal	October 2014
1H NMR study of monomeric chloro-rhenium(III) complexes with triarylphosphines and nitriles Pearson, Céline; Beauchamp, AndréL. Inorganica Chimica Acta, Vol. 237, Issue 1-2 https://doi.org/10.1016/0020-1693(95)04657-U	journal	September 1995
Bis(cyclopentadienyl)rhenium(III)chlorid: Kristallstruktur, Eigenschaften und Reaktivität; Darstellung und Charakterisierung von Cp3Re und Cp2ReH Apostolidis, Christos; Kanellakopulos, Basil; Maier, Ralph Journal of Organometallic Chemistry, Vol. 409, Issue 1-2 https://doi.org/10.1016/0022-328X(91)86150-O	journal	May 1991
Ab initio molecular calculations including spin-orbit coupling. I. Method and atomic tests Teichteil, Christian; Pelissier, Michel; Spiegelmann, Fernand Chemical Physics, Vol. 81, Issue 3 https://doi.org/10.1016/0301-0104(83)85321-X	journal	November 1983
Ab initio molecular calculations including spin-orbit coupling. II. Molecular test on the InH molecule and application to the g states of the Ar2* excimer Teichteil, C.; Spiegelmann, F. Chemical Physics, Vol. 81, Issue 3 https://doi.org/10.1016/0301-0104(83)85322-1	journal	November 1983
Appreciably bent sp carbon chains: synthesis, structure, and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (η5-C5Me5)Re(NO)(PPh3)((CC)n-p-C6H4Me) Dembinski, Roman; Lis, Tadeusz; Szafert, Slawomir Journal of Organometallic Chemistry, Vol. 578, Issue 1-2 https://doi.org/10.1016/S0022-328X(98)01128-0	journal	April 1999
Organometallic oxides: the example of trioxo-(η5-pentamethylcyclopentadienyl)rhenium(VII) Herrmann, Wolfgang A.; Herdtweck, Eberhardt; Flöel, Martina Polyhedron, Vol. 6, Issue 6 https://doi.org/10.1016/S0277-5387(00)80866-9	journal	January 1987
Syntheses and structural analyses of chiral rhenium containing amines of the formula (η5-C5H5)Re(NO)(PPh3)((CH2)nNRR′) (n=0, 1) Seidel, Sabine N.; Prommesberger, Markus; Eichenseher, Sandra Inorganica Chimica Acta, Vol. 363, Issue 3 https://doi.org/10.1016/j.ica.2009.03.047	journal	February 2010
Novel rhenium(III) complexes with 5,6-diphenyl-3-(2-pyridyl)-1,2,4-trazine: X-ray structures and DFT calculations for [ReCl3(OPPh3)(dppt)] and [ReCl3(PPh3)(dppt)] complexes Machura, B.; Kruszynski, R.; Kusz, J. Polyhedron, Vol. 26, Issue 15 https://doi.org/10.1016/j.poly.2007.05.053	journal	September 2007
Synthesis, spectroscopic characterization, X-ray structure and DFT calculations of rhenium(III) complex with 1-isoquinolinyl phenyl ketone Machura, B.; Kruszynski, R.; Mroziński, J. Polyhedron, Vol. 27, Issue 6 https://doi.org/10.1016/j.poly.2008.02.012	journal	April 2008
Coordination chemistry of di-2-pyridylketone. Synthesis, spectroscopic investigations, X-ray studies and DFT calculations of Re(III) and Re(V) complexes Machura, B.; Mroziński, J.; Kruszynski, R. Polyhedron, Vol. 28, Issue 14 https://doi.org/10.1016/j.poly.2009.06.048	journal	September 2009
Two novel rhenium complexes derived from [ReO(OMe)Cl2(dpphen)] – Synthesis, crystal structure, spectroscopic and magnetic properties Machura, B.; Wolff, M.; Gryca, I. Polyhedron, Vol. 30, Issue 2 https://doi.org/10.1016/j.poly.2010.10.025	journal	February 2011
Electronic and Spin-State Effects on Dinitrogen Splitting to Nitrides in a Rhenium Pincer System Weber, Jeremy E.; Hasanayn, Faraj; Fataftah, Majed Inorganic Chemistry, Vol. 60, Issue 9 https://doi.org/10.1021/acs.inorgchem.0c03778	journal	April 2021
Dinuclear and Mononuclear Rhenium Coordination Compounds upon Employment of a Schiff-Base Triol Ligand: Structural, Magnetic, and Computational Studies Kalofolias, Dimitris A.; Weselski, Marek; Siczek, Milosz Inorganic Chemistry, Vol. 58, Issue 13 https://doi.org/10.1021/acs.inorgchem.9b00886	journal	June 2019
H ₂ Activation and Direct Access to Terminal Nitride and cyclo -P ₃ Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate Lohrey, Trevor D.; Rao, Guodong; Britt, R. David Inorganic Chemistry, Vol. 58, Issue 19 https://doi.org/10.1021/acs.inorgchem.9b02556	journal	September 2019
Multiple bonds between main-group elements and transition metals. 48. Synthesis and structural characterization of trioxo(.eta.5-ethyltetramethylcyclopentadienyl)rhenium, a half-sandwich complex of heptavalent rhenium Okuda, Jun; Herdtweck, Eberhardt; Herrmann, Wolfgang A. Inorganic Chemistry, Vol. 27, Issue 7 https://doi.org/10.1021/ic00280a032	journal	April 1988
Reduction pathways in lateral and diagonal (.eta.5-C5Me5)Re(CO)2Br2. Synthesis, structure, and reactivity of [(.eta.5-C5Me5)Re(CO)2Br-] Nunn, Christine M.; Cowley, Alan H.; Lee, Sang Woo Inorganic Chemistry, Vol. 29, Issue 11 https://doi.org/10.1021/ic00336a015	journal	May 1990
{Re ^III Cl ₃ } Core Complexes with Bifunctional Single Amino Acid Chelates Banerjee, Sangeeta Ray; Wei, Lihui; Levadala, Murali K. Inorganic Chemistry, Vol. 41, Issue 22 https://doi.org/10.1021/ic020391d	journal	November 2002
Crystal and molecular structure of a perfluoropropyl complex of molybdenum: .pi.-C5H5Mo(CO)3C3F7 Churchill, Melvyn R.; Fennessey, James P. Inorganic Chemistry, Vol. 6, Issue 6 https://doi.org/10.1021/ic50052a032	journal	June 1967
Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis Spencer, Liam P.; Yang, Ping; Scott, Brian L. Inorganic Chemistry, Vol. 48, Issue 6 https://doi.org/10.1021/ic802212m	journal	March 2009
Synthesis, structure, and reactivity of stable alkyl and aryl iodide complexes of the formula [(.eta.5-C5H5(Re(NO)(PPh3)(IR)]+BF4- Winter, Charles H.; Veal, William R.; Garner, Charles M. Journal of the American Chemical Society, Vol. 111, Issue 13 https://doi.org/10.1021/ja00195a033	journal	June 1989
Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium Klopsch, Isabel; Finger, Markus; Würtele, Christian Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja502759d	journal	May 2014
Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation Booth, Corwin H.; Walter, Marc D.; Kazhdan, Daniel Journal of the American Chemical Society, Vol. 131, Issue 18 https://doi.org/10.1021/ja809624w	journal	May 2009
Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts Lohrey, Trevor D.; Rao, Guodong; Small, David W. Journal of the American Chemical Society, Vol. 142, Issue 32 https://doi.org/10.1021/jacs.0c04719	journal	July 2020
A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium–Carbon Bonds Settineri, Nicholas S.; Garner, Mary E.; Arnold, John Journal of the American Chemical Society, Vol. 139, Issue 17 https://doi.org/10.1021/jacs.7b02356	journal	April 2017
Mechanism of Chemical and Electrochemical N ₂ Splitting by a Rhenium Pincer Complex Lindley, Brian M.; van Alten, Richt S.; Finger, Markus Journal of the American Chemical Society, Vol. 140, Issue 25 https://doi.org/10.1021/jacs.8b03755	journal	May 2018
Heterotetrametallic Re–Zn–Zn–Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate Lohrey, Trevor D.; Maron, Laurent; Bergman, Robert G. Journal of the American Chemical Society, Vol. 141, Issue 2 https://doi.org/10.1021/jacs.8b12494	journal	December 2018
A Uranium Tri-Rhenium Triple Inverse Sandwich Compound Boreen, Michael A.; Lohrey, Trevor D.; Rao, Guodong Journal of the American Chemical Society, Vol. 141, Issue 13 https://doi.org/10.1021/jacs.9b01331	journal	March 2019
Dinitrogen Reduction to Ammonium at Rhenium Utilizing Light and Proton-Coupled Electron Transfer Bruch, Quinton J.; Connor, Gannon P.; Chen, Chun-Hsing Journal of the American Chemical Society, Vol. 141, Issue 51 https://doi.org/10.1021/jacs.9b10031	journal	November 2019
Synthesis, structure, and dynamic behavior of rhenium sulfide and sulfoxide complexes of the formula [(.eta.5-C5H5)Re(NO)(L)(XRR')]+X'- (X = S, SO) Quiros Mendez, N.; Arif, Atta M.; Gladysz, J. A. Organometallics, Vol. 10, Issue 7 https://doi.org/10.1021/om00053a024	journal	July 1991
Piano-stool complexes of the CpML4 type Kubacek, Pavel; Hoffmann, Roald; Havlas, Zdenek Organometallics, Vol. 1, Issue 1 https://doi.org/10.1021/om00061a029	journal	January 1982
Syntheses, x-ray structures, and cis-trans isomerism of (pentamethylcyclopentadienyl)dicarbonylrhenium dihalides (.eta.-C5Me5)Re(CO)2X2 (X = Cl, Br, I) Einstein, Frederick W. B.; Klahn-Oliva, A. Hugo; Sutton, Derek Organometallics, Vol. 5, Issue 1 https://doi.org/10.1021/om00132a009	journal	January 1986
A New Family of Chelating Diphosphines with Transition-Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System Kromm, Klemenz; Hampel, Frank; Gladysz, J. A. Organometallics, Vol. 21, Issue 20 https://doi.org/10.1021/om020431l	journal	August 2002
Synthesis and Reactivity of Chromium Cyclopentadienyl β-Diketiminato Compounds Doherty, Jayne C.; Ballem, Katherine H. D.; Patrick, Brian O. Organometallics, Vol. 23, Issue 7 https://doi.org/10.1021/om034065x	journal	March 2004
Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions: A New Strategy for High-Activity Systems Eichenseher, Sandra; Delacroix, Olivier; Kromm, Klemenz Organometallics, Vol. 24, Issue 2 https://doi.org/10.1021/om0492956	journal	December 2004
Solid-State Reactivity and Single-Crystal Structure Studies. The Case of diag − lat Isomerization in [Re(η ⁵ -C ₅ H ₄ Me)(CO)(P(OPh ₃ )Br ₂ ] and [Re(η ⁵ -C ₅ H ₄ ^t Bu)(CO) ₂ Br ₂ ] Smith, Jeremy M.; Cheng, Lin; Coville, Neil J. Organometallics, Vol. 19, Issue 13 https://doi.org/10.1021/om990959z	journal	May 2000
The importance of inter-molecular forces in crystal structure analysis: Solid state study of the diag-to-lat isomerization of (η⁵-C₅H₄Me)Re(CO)₂Br₂ Boeyens, Jan C. A.; Cheng, Lin; Coville, Neil J. Journal of Chemical Crystallography, Vol. 28, Issue 3, p. 185-191 https://doi.org/10.1023/A:1022466126100	journal	January 1998
A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re( i ) complexes Hernández, José G.; Macdonald, Neil A. J.; Mottillo, Cristina Green Chem., Vol. 16, Issue 3 https://doi.org/10.1039/C3GC42104J	journal	January 2014
Synthesis, crystal structure and magnetic properties of the complex [ReCl ₃ (tppz)]·MeCN Palion-Gazda, J.; Gryca, I.; Machura, B. RSC Advances, Vol. 5, Issue 123 https://doi.org/10.1039/C5RA21466A	journal	January 2015
Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John Dalton Transactions, Vol. 48, Issue 48 https://doi.org/10.1039/C9DT04489B	journal	January 2019
σ or π? Bonding interactions in a series of rhenium metallotetrylenes Ouellette, Erik T.; Carpentier, Ambre; Joseph Brackbill, I. Dalton Transactions, Vol. 50, Issue 6 https://doi.org/10.1039/D1DT00129A	journal	January 2021
Synthesis and characterisation of half-sandwich tantalum compounds in oxidation states (I)–(V): tertiary phosphine, acetylene, butadiene, carbonyl, and oxo derivatives. X-Ray crystal structures of [Ta(C ₅ Me ₅ )Cl ₃ (PMe ₃ )] and [Ta(C ₅ Me ₅ )Cl ₂ (CO) ₂ (PMe ₃ )] Gibson, Vernon C.; Kee, Terence P.; Clegg, William J. Chem. Soc., Dalton Trans., Issue 11 https://doi.org/10.1039/DT9900003199	journal	January 1990
The preparation and reactions of trihaolgeno(alkanonitrile)bis(triphenylphosphine)rhenium(III) complexes Rouschias, G.; Wilkinson, G. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/J19670000993	journal	January 1967
Configurations of some complexes of rhenium, ruthenium, osmium, rhodium, iridium, and platinum halides with mono(tertiary phosphines) and mono(tertiary arsines) Chatt, J.; Leigh, G. J.; Mingos, D. M. P. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/J19690001674	journal	January 1969
Nuclear magnetic resonance spectra of d 4-complexes of rhenium(III) and osmium(IV) with phosphine and arsine ligands Randall, E. W.; Shaw, D. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/J19690002867	journal	January 1969
Magnetic susceptibilities of some rhenium(III) and osmium(IV) halide complexes; preparation of some new d 4 complexes Gunz, H. P.; Leigh, G. J. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/J19710002229	journal	January 1971
The biomedical chemistry of technetium and rhenium R. Dilworth, Jonathan; J. Parrott, Suzanne Chemical Society Reviews, Vol. 27, Issue 1 https://doi.org/10.1039/a827043z	journal	January 1998
Towards molecular imaging and treatment of disease with radionuclides: the role of inorganic chemistry Blower, Phil Dalton Transactions, Issue 14 https://doi.org/10.1039/b516860k	journal	January 2006
Second-order paramagnetic rhenium(III) complexes: solid-state structure and assignment of the carbon-13 magnetic resonance spectra in solution Mitsopoulou, Christiana A.; Mahieu, Nathalie; Motevalli, Majid Journal of the Chemical Society, Dalton Transactions, Issue 24 https://doi.org/10.1039/dt9960004563	journal	January 1996
602. The magnetic properties of some d 3-complexes Figgis, B. N.; Lewis, J.; Mabbs, F. E. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9610003138	journal	January 1961
Temperature dependence of contact and dipolar NMR chemical shifts in paramagnetic molecules Martin, Bob; Autschbach, Jochen The Journal of Chemical Physics, Vol. 142, Issue 5 https://doi.org/10.1063/1.4906318	journal	February 2015

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Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide β-diketiminate Halide and Pseudohalide Complexes

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