Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing

Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John

doi:10.1039/C9DT04489B

Title: Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing

Journal Article · Tue Dec 10 00:00:00 EST 2019 · Dalton Transactions

DOI:https://doi.org/10.1039/C9DT04489B· OSTI ID:1576825

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Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
Department of Chemistry, University of California, Berkeley, USA

The rhenium( i ) salt Na[Re(η ⁵ -Cp)(BDI)] can be cooled in solution under a dinitrogen atmosphere to selectively access complexes containing rhenium( iii ) centers bound to direduced, doubly-bonded N ₂ ( i.e. diazenide) fragments.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1576825

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Vol. 48 Journal Issue: 48; ISSN 1477-9226

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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