An indium-based microporous metal–organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

Cui, Hui; Ye, Yingxiang; Lin, Ruibiao; Shi, Yanshu; Alothman, Zeid A.; Alduhaish, Osamah; Wang, Bin; Zhang, Jian; Chen, Banglin

doi:10.1039/d2qi01956f

An indium-based microporous metal–organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

Journal Article · Mon Oct 24 00:00:00 EDT 2022 · Inorganic Chemistry Frontiers (Online)

DOI:https://doi.org/10.1039/d2qi01956f· OSTI ID:2326973

Cui, Hui ^[1]; ^[2]; ^[3]; Shi, Yanshu ^[4]; ^[5]; Alduhaish, Osamah ^[5]; ^[2]; Zhang, Jian ^[6]; ^[4]

University of Texas at San Antonio, TX (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
University of North Texas, Denton, TX (United States)
Sun Yat-Sen University, Guangzhou (China)
University of Texas at San Antonio, TX (United States)
King Saud University, Riyadh (Saudi Arabia)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Foundry

A novel microporous indium-based MOF material with unique 3-way rod-shaped secondary building units (SBUs), UTSA-22, was reported and exhibited high methane (CH₄) and hydrogen (H₂) storage. At 298 K and 65 bar, the total CH₄ volumetric uptake of UTSA-22 is 174 cm³(STP) cm^-3. Moreover, UTSA-22 shows a high CH₄ working capacity of 146 cm³(STP) cm^-3 in a pressure range of 5–65 bar at 298 K. Additionally, UTSA-22 shows a high H₂ gravimetric storage capacity (1.2 wt%) at 298 K and 100 bar.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: Deputyship for Research & Innovation, Ministry of Education, in Saudi Arabia; National Natural Science Foundation of China (NSFC); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); Welch Foundation

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2326973

Alternate ID(s):: OSTI ID: 1897232

Journal Information:: Inorganic Chemistry Frontiers (Online), Journal Name: Inorganic Chemistry Frontiers (Online) Journal Issue: 24 Vol. 9; ISSN 2052-1553

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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