A robust soc-MOF platform exhibiting high gravimetric uptake and volumetric deliverable capacity for on-board methane storage

Verma, Gaurav; Kumar, Sanjay; Vardhan, Harsh; Ren, Junyu; Niu, Zheng; Pham, Tony; Wojtas, Lukasz; Butikofer, Sydney; Echeverria Garcia, Jose C.; Chen, Yu-Sheng; Space, Brian; Ma, Shengqian

doi:10.1007/s12274-020-2794-9

A robust soc-MOF platform exhibiting high gravimetric uptake and volumetric deliverable capacity for on-board methane storage

Journal Article · Fri Apr 24 00:00:00 EDT 2020 · Nano Research

DOI:https://doi.org/10.1007/s12274-020-2794-9· OSTI ID:3000164

Verma, Gaurav ^[1]; Kumar, Sanjay ^[2]; Vardhan, Harsh ^[1]; Ren, Junyu ^[1]; Niu, Zheng ^[1]; Pham, Tony ^[3]; Wojtas, Lukasz ^[1]; Butikofer, Sydney ^[4]; Echeverria Garcia, Jose C. ^[1]; Chen, Yu-Sheng ^[5]; Space, Brian ^[1]; Ma, Shengqian ^[1]

University of South Florida, Tampa, FL (United States)
Multani Mal Modi College, Patiala (India); University of South Florida, Tampa, FL (United States)
The University of Tampa, FL (United States); University of South Florida, Tampa, FL (United States)
University of Illinois at Urbana-Champaign, IL (United States); University of South Florida, Tampa, FL (United States)
The University of Chicago, IL (United States)

Emerging as an outperformed class of metal-organic frameworks (MOFs), square-octahedron (soc) topology MOFs (soc-MOFs) feature superior properties of high porosity, large gas storage capacity, and excellent thermal/chemical stability. We report here an iron based soc-MOF, denoted as Fe-pbpta (H₄pbpta = 4,4′,4″,4‴-(1,4-phenylenbis(pyridine-4,2-6-triyl))-tetrabenzoic acid) possessing a very high Brunauer, Emmett and Teller (BET) surface area of 4,937 m²/g and a large pore volume of 2.15 cm³/g. Here, the MOF demonstrates by far the highest gravimetric uptake of 369 cm³(STP)/g under the DOE operational storage conditions (35 bar and 298 K) and a high volumetric deliverable capacity of 192 cc/cc at 298 K and 65 bar. Furthermore, Fe-pbpta exhibits high thermal and aqueous stability making it a promising candidate for on-board methane storage.

View Accepted Manuscript (DOE)

Research Organization:: North Carolina State University, Raleigh, NC (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Hydrogen Fuel Cell Technologies Office (HFTO); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Science Foundation (NSF)

Grant/Contract Number:: EE0008812; AC02-06CH11357

OSTI ID:: 3000164

Alternate ID(s):: OSTI ID: 1734908

Report Number(s):: 1EE0008812

Journal Information:: Nano Research, Journal Name: Nano Research Journal Issue: 2 Vol. 14; ISSN unk; ISSN 1998-0000; ISSN 1998-0124

Publisher:: Tsinghua University PressCopyright Statement

Country of Publication:: United States

Language:: English

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A robust soc-MOF platform exhibiting high gravimetric uptake and volumetric deliverable capacity for on-board methane storage

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