A Perspective on Solar-Driven Electrochemical Routes for Sustainable Methanol Production

Pendse, Aaditya; Prajapati, Aditya

doi:10.3390/suschem5010002

Title: A Perspective on Solar-Driven Electrochemical Routes for Sustainable Methanol Production

Journal Article · Wed Mar 06 00:00:00 EST 2024 · Sustainable Chemistry

DOI:https://doi.org/10.3390/suschem5010002· OSTI ID:2325217

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Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

The transition towards sustainable and renewable energy sources is imperative in mitigating the environmental impacts of escalating global energy consumption. Methanol, with its versatile applications and potential as a clean energy carrier, a precursor chemical, and a valuable commodity, emerges as a promising solution within the realm of renewable energy technologies. This work explores the integration of electrochemistry with solar power to drive efficient methanol production processes, focusing on electrochemical reduction (ECR) of CO₂ and methane oxidation reaction (MOR) as pathways for methanol synthesis. Through detailed analysis and calculations, we evaluate the thermodynamic limits and realistic solar-to-fuel (STF) efficiencies of ECR and MOR. Our investigation encompasses the characterization of multijunction light absorbers, determination of thermoneutral potentials, and assessment of STF efficiencies under varying conditions. We identify the challenges and opportunities inherent in both ECR and MOR pathways, shedding light on catalyst stability, reaction kinetics, and system optimization, thereby providing insights into the prospects and challenges of solar-driven methanol synthesis, offering a pathway towards a cleaner and more sustainable energy future.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 2325217

Report Number(s):: LLNL-JRNL-860117; 1091141

Journal Information:: Sustainable Chemistry, Vol. 5, Issue 1; ISSN 2673-4079

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

References (67)

Ultrahigh Electrocatalytic Conversion of Methane at Room Temperature Ma, Ming; Jin, Bing Jun; Li, Ping Advanced Science, Vol. 4, Issue 12 https://doi.org/10.1002/advs.201700379	journal	September 2017
Over a 15.9% Solar-to-CO Conversion from Dilute CO ₂ Streams Catalyzed by Gold Nanoclusters Exhibiting a High CO ₂ Binding Affinity Kim, Beomil; Seong, Hoeun; Song, Jun Tae ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.9b02511	journal	December 2019
Nonstoichiometric Perovskite Oxides for Solar Thermochemical H2 and CO Production McDaniel, A. H.; Ambrosini, A.; Coker, E. N. Energy Procedia, Vol. 49 https://doi.org/10.1016/j.egypro.2014.03.213	journal	January 2014
Two Pathways for Near Room Temperature Electrochemical Conversion of Methane to Methanol Omasta, T. J.; Rigdon, W. A.; Lewis, C. A. ECS Transactions, Vol. 66, Issue 8 https://doi.org/10.1149/06608.0129ecst	journal	August 2015
Photocatalytic CO ₂ Reduction to Formic Acid Using a Ru(II)–Re(I) Supramolecular Complex in an Aqueous Solution Nakada, Akinobu; Koike, Kazuhide; Nakashima, Takuya Inorganic Chemistry, Vol. 54, Issue 4 https://doi.org/10.1021/ic502707t	journal	January 2015
Water Splitting Exceeding 17% Solar-to-Hydrogen Conversion Efficiency Using Solution-Processed Ni-Based Electrocatalysts and Perovskite/Si Tandem Solar Cell Park, Hoonkee; Park, Ik Jae; Lee, Mi Gyoung ACS Applied Materials & Interfaces, Vol. 11, Issue 37 https://doi.org/10.1021/acsami.9b09344	journal	August 2019
Electrochemical Reduction of Carbon Dioxide to Methane, Methanol, and CO on Ru Electrodes Frese, K. W. Journal of The Electrochemical Society, Vol. 132, Issue 1 https://doi.org/10.1149/1.2113780	journal	January 1985
Fundamental insight into electrochemical oxidation of methane towards methanol on transition metal oxides Prajapati, Aditya; Collins, Brianna A.; Goodpaster, Jason D. Proceedings of the National Academy of Sciences, Vol. 118, Issue 8 https://doi.org/10.1073/pnas.2023233118	journal	February 2021
Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review) Ganesh, Ibram Renewable and Sustainable Energy Reviews, Vol. 31 https://doi.org/10.1016/j.rser.2013.11.045	journal	March 2014
Assessment of Artificial Photosynthetic Systems for Integrated Carbon Capture and Conversion Prajapati, Aditya; Singh, Meenesh R. ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 6 https://doi.org/10.1021/acssuschemeng.8b04969	journal	February 2019
Ten-percent solar-to-fuel conversion with nonprecious materials Cox, Casandra R.; Lee, Jungwoo Z.; Nocera, Daniel G. Proceedings of the National Academy of Sciences, Vol. 111, Issue 39 https://doi.org/10.1073/pnas.1414290111	journal	September 2014
Active direct methanol fuel cell: An overview Alias, M. S.; Kamarudin, S. K.; Zainoodin, A. M. International Journal of Hydrogen Energy, Vol. 45, Issue 38 https://doi.org/10.1016/j.ijhydene.2020.04.202	journal	July 2020
Tandem reactors and reactions for CO2 conversion Garg, Samay; Xie, Zhenhua; Chen, Jingguang G. Nature Chemical Engineering, Vol. 1, Issue 2 https://doi.org/10.1038/s44286-023-00020-2	journal	February 2024
Best practices for experiments and reporting in photocatalytic CO2 reduction Bonchio, Marcella; Bonin, Julien; Ishitani, Osamu Nature Catalysis, Vol. 6, Issue 8 https://doi.org/10.1038/s41929-023-00992-7	journal	August 2023
Electrochemical reduction of CO₂ on RuO₂/TiO₂ nanotubes composite modified Pt electrode Qu, Jianping; Zhang, Xiaogang; Wang, Yonggang Electrochimica Acta, Vol. 50, Issue 16-17, p. 3576-3580 https://doi.org/10.1016/j.electacta.2004.11.061	journal	May 2005
A large-sized cell for solar-driven CO2 conversion with a solar-to-formate conversion efficiency of 7.2% Kato, Naohiko; Mizuno, Shintaro; Shiozawa, Masahito Joule, Vol. 5, Issue 3 https://doi.org/10.1016/j.joule.2021.01.002	journal	March 2021
Enhanced Photocatalytic CO ₂ -Reduction Activity of Anatase TiO ₂ by Coexposed {001} and {101} Facets Yu, Jiaguo; Low, Jingxiang; Xiao, Wei Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja5044787	journal	June 2014
Solar-driven electrochemical synthesis of ammonia using nitrate with 11% solar-to-fuel efficiency at ambient conditions Kani, Nishithan C.; Gauthier, Joseph A.; Prajapati, Aditya Energy & Environmental Science, Vol. 14, Issue 12 https://doi.org/10.1039/D1EE01879E	journal	January 2021
Stable Aqueous Photoelectrochemical CO ₂ Reduction by a Cu ₂ O Dark Cathode with Improved Selectivity for Carbonaceous Products Chang, Xiaoxia; Wang, Tuo; Zhang, Peng Angewandte Chemie International Edition, Vol. 55, Issue 31 https://doi.org/10.1002/anie.201602973	journal	May 2016
Photocatalytic oxidation of methane to methanol by tungsten trioxide-supported atomic gold at room temperature Zeng, Yi; Tang, Zhiyuan; Wu, Xingyang Applied Catalysis B: Environmental, Vol. 306 https://doi.org/10.1016/j.apcatb.2021.120919	journal	June 2022
Efficient and selective formation of methanol from methane in a fuel cell-type reactor Lee, Byungik; Hibino, Takashi Journal of Catalysis, Vol. 279, Issue 2, p. 233-240 https://doi.org/10.1016/j.jcat.2010.12.020	journal	April 2011
Trace-Level Cobalt Dopants Enhance CO₂ Electroreduction and Ethylene Formation on Copper Kim, Beomil; Tan, Ying Chuan; Ryu, Yeonkyeong ACS Energy Letters, Vol. 8, Issue 8 https://doi.org/10.1021/acsenergylett.3c00418	journal	July 2023
Role of renewable, non-renewable energy consumption and carbon emission in energy efficiency and productivity change: Evidence from G20 economies Shah, Wasi Ul Hassan; Hao, Gang; Yan, Hong Geoscience Frontiers https://doi.org/10.1016/j.gsf.2023.101631	journal	May 2023
Enabling the Methanol Economy: Opportunities and Challenges for Heterogeneous Catalysis in the Production of Liquid Fuels via Methanol Filosa, Claudia; Gong, Xuan; Bavykina, Anastasiya Accounts of Chemical Research, Vol. 56, Issue 23 https://doi.org/10.1021/acs.accounts.3c00551	journal	November 2023
Nanostructured Photocatalysts for the Production of Methanol from Methane and Water Villa, Katherine; Galán‐Mascarós, José Ramón ChemSusChem, Vol. 14, Issue 9 https://doi.org/10.1002/cssc.202100192	journal	March 2021
Progress and Perspectives of Electrochemical CO ₂ Reduction on Copper in Aqueous Electrolyte Nitopi, Stephanie; Bertheussen, Erlend; Scott, Soren B. Chemical Reviews, Vol. 119, Issue 12 https://doi.org/10.1021/acs.chemrev.8b00705	journal	April 2019
Carbon Nitride‐Based Ruthenium Single Atom Photocatalyst for CO ₂ Reduction to Methanol Sharma, Priti; Kumar, Subodh; Tomanec, Ondrej Small, Vol. 17, Issue 16 https://doi.org/10.1002/smll.202006478	journal	March 2021
CO2-free high-purity ethylene from electroreduction of CO2 with 4% solar-to-ethylene and 10% solar-to-carbon efficiencies Prajapati, Aditya; Kani, Nishithan C.; Gauthier, Joseph A. Cell Reports Physical Science, Vol. 3, Issue 9 https://doi.org/10.1016/j.xcrp.2022.101053	journal	September 2022
Solar-driven photoelectrochemical reduction of carbon dioxide to methanol at CuInS2 thin film photocathode Yuan, Jiongliang; Hao, Cunjiang Solar Energy Materials and Solar Cells, Vol. 108 https://doi.org/10.1016/j.solmat.2012.09.024	journal	January 2013
Structure‐Tailored Surface Oxide on Cu–Ga Intermetallics Enhances CO₂ Reduction Selectivity to Methanol at Ultralow Potential Bagchi, Debabrata; Raj, Jithu; Singh, Ashutosh Kumar Advanced Materials, Vol. 34, Issue 19 https://doi.org/10.1002/adma.202109426	journal	April 2022
Towards the electrochemical conversion of carbon dioxide into methanol Albo, J.; Alvarez-Guerra, M.; Castaño, P. Green Chemistry, Vol. 17, Issue 4 https://doi.org/10.1039/C4GC02453B	journal	January 2015
Electrochemical Reoxidation Enables Continuous Methane-to-Methanol Catalysis with Aqueous Pt Salts Kim, R. Soyoung; Surendranath, Yogesh ACS Central Science, Vol. 5, Issue 7 https://doi.org/10.1021/acscentsci.9b00273	journal	June 2019
Solar-Driven Reduction of 1 atm of CO ₂ to Formate at 10% Energy-Conversion Efficiency by Use of a TiO ₂ -Protected III–V Tandem Photoanode in Conjunction with a Bipolar Membrane and a Pd/C Cathode Zhou, Xinghao; Liu, Rui; Sun, Ke ACS Energy Letters, Vol. 1, Issue 4 https://doi.org/10.1021/acsenergylett.6b00317	journal	September 2016
A Feasibility Study of the Electro-recycling of Greenhouse Gases: Design and Characterization of a (TiO2/RuO2)/PTFE Gas Diffusion Electrode for the Electrosynthesis of Methanol from Methane Rocha, Robson Silva; Camargo, Luciana Martins; Lanza, Marcos Roberto Vasconcelos Electrocatalysis, Vol. 1, Issue 4 https://doi.org/10.1007/s12678-010-0029-7	journal	September 2010
Solar Cell-Powered Electrochemical Methane-to-Methanol Conversion with CuO/CeO₂ Catalysts Lee, Jaehyun; Yang, Jiwoo; Moon, Jun Hyuk ACS Energy Letters, Vol. 6, Issue 3 https://doi.org/10.1021/acsenergylett.0c02553	journal	February 2021
Structure-Sensitive Electrocatalytic Reduction of CO₂ to Methanol over Carbon-Supported Intermetallic PtZn Nano-Alloys Payra, Soumitra; Shenoy, Sulakshana; Chakraborty, Chanchal ACS Applied Materials & Interfaces, Vol. 12, Issue 17 https://doi.org/10.1021/acsami.0c00521	journal	April 2020
Chloride-Promoted High-Rate Ambient Electrooxidation of Methane to Methanol on Patterned Cu–Ti Bimetallic Oxides Prajapati, Aditya; Sartape, Rohan; Kani, Nishithan C. ACS Catalysis, Vol. 12, Issue 22 https://doi.org/10.1021/acscatal.2c03619	journal	November 2022
Electrochemical Methane Activation and Conversion to Oxygenates at Room Temperature Spinner, Neil; Mustain, William E. ECS Transactions, Vol. 53, Issue 23 https://doi.org/10.1149/05323.0001ecst	journal	October 2013
Electrocatalytic oxidation of methane to ethanol via NiO/Ni interface Song, Yanfang; Zhao, Yonghui; Nan, Guizhen Applied Catalysis B: Environmental, Vol. 270 https://doi.org/10.1016/j.apcatb.2020.118888	journal	August 2020
General Techno-Economic Analysis of CO ₂ Electrolysis Systems Jouny, Matthew; Luc, Wesley; Jiao, Feng Industrial & Engineering Chemistry Research, Vol. 57, Issue 6 https://doi.org/10.1021/acs.iecr.7b03514	journal	February 2018
Electrochemical Reduction of Carbon Dioxide on Conductive Metallic Oxides Bandi, A. Journal of The Electrochemical Society, Vol. 137, Issue 7 https://doi.org/10.1149/1.2086903	journal	July 1990
Tandem photo-electrode of InGaN with two Si p-n junctions for CO ₂ conversion to HCOOH with the efficiency greater than biological photosynthesis Sekimoto, Takeyuki; Shinagawa, Shuichi; Uetake, Yusuke Applied Physics Letters, Vol. 106, Issue 7 https://doi.org/10.1063/1.4910510	journal	February 2015
Hydrogel protection strategy to stabilize water-splitting photoelectrodes Tan, Jeiwan; Kang, Byungjun; Kim, Kyungmin Nature Energy, Vol. 7, Issue 6 https://doi.org/10.1038/s41560-022-01042-5	journal	June 2022
Addressing the stability challenge of photo(electro)catalysts towards solar water splitting Xiao, Mu; Wang, Zhiliang; Maeda, Kazuhiko Chemical Science, Vol. 14, Issue 13 https://doi.org/10.1039/D2SC06981D	journal	January 2023
Core–Shell Covalently Linked Graphitic Carbon Nitride–Melamine–Resorcinol–Formaldehyde Microsphere Polymers for Efficient Photocatalytic CO₂ Reduction to Methanol Ding, Jie; Tang, Qingli; Fu, Yanghe Journal of the American Chemical Society, Vol. 144, Issue 22 https://doi.org/10.1021/jacs.1c13301	journal	May 2022
Designing CO ₂ reduction electrode materials by morphology and interface engineering Pan, Fuping; Yang, Yang Energy & Environmental Science, Vol. 13, Issue 8 https://doi.org/10.1039/D0EE00900H	journal	January 2020
Photoelectrochemical Reduction of CO ₂ Coupled to Water Oxidation Using a Photocathode with a Ru(II)–Re(I) Complex Photocatalyst and a CoO _x /TaON Photoanode Sahara, Go; Kumagai, Hiromu; Maeda, Kazuhiko Journal of the American Chemical Society, Vol. 138, Issue 42 https://doi.org/10.1021/jacs.6b09212	journal	October 2016
Electrolytic cell design for electrochemical CO2 reduction Liang, Shuyu; Altaf, Naveed; Huang, Liang Journal of CO2 Utilization, Vol. 35 https://doi.org/10.1016/j.jcou.2019.09.007	journal	January 2020
Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders Inoue, Tooru; Fujishima, Akira; Konishi, Satoshi Nature, Vol. 277, Issue 5698 https://doi.org/10.1038/277637a0	journal	February 1979
Pitfalls and Protocols: Evaluating Catalysts for CO₂ Reduction in Electrolyzers Based on Gas Diffusion Electrodes Tan, Ying Chuan; Quek, Wei Kang; Kim, Beomil ACS Energy Letters, Vol. 7, Issue 6 https://doi.org/10.1021/acsenergylett.2c00763	journal	May 2022
Electrochemical Reduction of CO 2 at Intentionally Oxidized Copper Electrodes Frese, Karl W. Journal of The Electrochemical Society, Vol. 138, Issue 11 https://doi.org/10.1149/1.2085411	journal	November 1991
Boosting the performance of Cu2O photocathodes for unassisted solar water splitting devices Pan, Linfeng; Kim, Jin Hyun; Mayer, Matthew T. Nature Catalysis, Vol. 1, Issue 6 https://doi.org/10.1038/s41929-018-0077-6	journal	May 2018
Recent Advances in Solar-Driven Carbon Dioxide Conversion: Expectations versus Reality He, Jie; Janáky, Csaba ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00645	journal	May 2020
Selective Solar-Driven Reduction of CO ₂ to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell Barton, Emily E.; Rampulla, David M.; Bocarsly, Andrew B. Journal of the American Chemical Society, Vol. 130, Issue 20 https://doi.org/10.1021/ja0776327	journal	May 2008
Best practices for electrochemical reduction of carbon dioxide Seger, Brian; Robert, Marc; Jiao, Feng Nature Sustainability, Vol. 6, Issue 3 https://doi.org/10.1038/s41893-022-01034-z	journal	January 2023
Efficient photosynthesis of carbon monoxide from CO2 using perovskite photovoltaics Schreier, Marcel; Curvat, Laura; Giordano, Fabrizio Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8326	journal	June 2015
Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts Yang, Dexin; Zhu, Qinggong; Chen, Chunjun Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08653-9	journal	February 2019
Tailoring Copper Oxide Semiconductor Nanorod Arrays for Photoelectrochemical Reduction of Carbon Dioxide to Methanol Rajeshwar, Krishnan; de Tacconi, Norma R.; Ghadimkhani, Ghazaleh ChemPhysChem, Vol. 14, Issue 10 https://doi.org/10.1002/cphc.201300080	journal	May 2013
Reduction of Carbon Dioxide to Methanol on n- and p-GaAs and p-InP. Effect of Crystal Face, Electrolyte and Current Density Canfield, D. Journal of The Electrochemical Society, Vol. 130, Issue 8 https://doi.org/10.1149/1.2120090	journal	January 1983
Electrosynthesis of methanol from methane: The role of V₂O₅ in the reaction selectivity for methanol of a TiO₂/RuO₂/V₂O₅ gas diffusion electrode Rocha, Robson S.; Reis, Rafael M.; Lanza, Marcos R. V. Electrochimica Acta, Vol. 87, p. 606-610 https://doi.org/10.1016/j.electacta.2012.09.113	journal	January 2013
Oxygen exchange materials for solar thermochemical splitting of H2O and CO2: a review Scheffe, Jonathan R.; Steinfeld, Aldo Materials Today, Vol. 17, Issue 7 https://doi.org/10.1016/j.mattod.2014.04.025	journal	September 2014
Barriers of Electrochemical CO ₂ Reduction on Transition Metals Shi, Chuan; Chan, Karen; Yoo, Jong Suk Organic Process Research & Development, Vol. 20, Issue 8 https://doi.org/10.1021/acs.oprd.6b00103	journal	July 2016
Bridging fundamental science and applied science to accelerate CO2 electrolyzer scale-up Goldman, Maxwell; Prajapati, Aditya; Duoss, Eric Current Opinion in Electrochemistry, Vol. 39 https://doi.org/10.1016/j.coelec.2023.101248	journal	June 2023
Highly Efficient Electroreduction of CO ₂ to Methanol on Palladium-Copper Bimetallic Aerogels Lu, Lu; Sun, Xiaofu; Ma, Jun Angewandte Chemie, Vol. 130, Issue 43 https://doi.org/10.1002/ange.201808964	journal	October 2018
Directed Assembly of Nanoparticle Catalysts on Nanowire Photoelectrodes for Photoelectrochemical CO ₂ Reduction Kong, Qiao; Kim, Dohyung; Liu, Chong Nano Letters, Vol. 16, Issue 9 https://doi.org/10.1021/acs.nanolett.6b02321	journal	August 2016
Comparative well-to-pump assessment of fueling pathways for zero-carbon transportation in China: Hydrogen economy or methanol economy? Li, Jiaxuan; Zhu, Xun; Djilali, Ned Renewable and Sustainable Energy Reviews, Vol. 169 https://doi.org/10.1016/j.rser.2022.112935	journal	November 2022
Reduction of CO[sub 2] on n-GaAs Electrodes and Selective Methanol Synthesis Frese, K. W. Journal of The Electrochemical Society, Vol. 131, Issue 11 https://doi.org/10.1149/1.2115351	journal	January 1984

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30 DIRECT ENERGY CONVERSION
methanol production
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renewable energy integration
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Title: A Perspective on Solar-Driven Electrochemical Routes for Sustainable Methanol Production

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