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Electrochemical Routes for the Valorization of Biomass-Derived Feedstocks: From Chemistry to Application

Journal Article · · ACS Energy Letters

The drive to reduce consumption of fossil resources, coupled with expanding capacity for renewable electricity, invites the exploration of new routes to utilize this energy for the sustainable production of fuels, chemicals, and materials. Biomass represents a possible source of platform precursors for such commodities due to its inherent ability to fix CO2 in the form of multi-carbon organic molecules. Electrochemical methods for the valorization of biomass are thus intriguing, but there is a need to objectively evaluate this field and define the opportunity space by identifying pathways suited to electrochemistry. In this contribution we offer a comprehensive, critical review of recent advances in low-temperature (liquid phase), electrochemical reduction and oxidation of biomass-derived intermediates (polyols, furans, carboxylic acids, amino acids, and lignin), with emphasis on identifying the state-of-the-art for each documented reaction. Progress in computational modeling is also reviewed. We further suggest a number of possible reactions that have not yet been explored but which are expected to proceed based on established routes to transform specific functional groups. We conclude with a critical discussion of technological challenges for scale-up, fundamental research needs, process intensification opportunities (e.g., by pairing compatible oxidations and reductions), and new benchmarking standards that will be necessary to accelerate progress toward application in this still-nascent field.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1778698
Report Number(s):
NREL/JA--5100-78761; MainId:32678; UUID:f1ae075a-6cee-4ff5-8d49-a91321ae15e4; MainAdminID:19959
Journal Information:
ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 4 Vol. 6; ISSN 2380-8195
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (474)

Catalytic Hydrogenation of Chiral α-Amino and α-Hydroxy Esters at Room Temperature with Nishimura Catalyst without Racemization journal December 2001
Biomass Valorization via Paired Electrosynthesis Over Vanadium Nitride‐Based Electrocatalysts journal August 2019
A Homogeneous Catalyst for Reduction of Optically Active Esters to the Corresponding Chiral Alcohols without Loss of Optical Purities journal January 2010
Electrochemical β‐Selective Hydrocarboxylation of Styrene Using CO 2 and Water journal December 2019
Dehydration of glycerol to acetol via catalytic reactive distillation journal January 2006
New group contribution method for estimating properties of pure compounds journal October 1994
Does a Thermoneutral Electrocatalyst Correspond to the Apex of a Volcano Plot for a Simple Two‐Electron Process? journal May 2020
Elucidation of the Electrochemical Activation of Water over Pd by First Principles journal January 2006
Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals journal September 2007
Valeric Biofuels: A Platform of Cellulosic Transportation Fuels journal June 2010
Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone journal June 2011
Simultaneous H 2 Generation and Biomass Upgrading in Water by an Efficient Noble-Metal-Free Bifunctional Electrocatalyst journal July 2016
Electrocatalytic Oxidation of 5-(Hydroxymethyl)furfural Using High-Surface-Area Nickel Boride journal July 2018
Selective Synthesis of 2,5-Diformylfuran by Sustainable 4-acetamido-TEMPO/Halogen-Mediated Electrooxidation of 5-Hydroxymethylfurfural journal August 2016
Jatropha cultivation in southern India: assessing farmers' experiences journal February 2012
Chemicals from lignocellulosic biomass: opportunities, perspectives, and potential of biorefinery systems journal May 2011
Eine Neue Darstellungsweise von Aminen aus α-Aminocarbonsäuren journal July 1957
Mechanism of the Catalytic Oxidation of Glycerol on Polycrystalline Gold and Platinum Electrodes journal May 2011
Enzymatic Decarboxylation-An Emerging Reaction for Chemicals Production from Renewable Resources journal January 2014
Metal Catalysts for the Efficient Transformation of Biomass-derived HMF and Furfural to Value Added Chemicals journal March 2018
Paired Electrosynthesis of Diacid and Diol Precursors Using Dienes and CO 2 as the Carbon Source journal November 2014
Carboxylic Acids Production via Electrochemical Depolymerization of Lignin journal January 2019
Electrocatalytic Fixation of Carbon Dioxide with Amines and Arylketones journal February 2019
Identification of More Benign Cathode Materials for the Electrochemical Reduction of Levulinic Acid to Valeric Acid journal July 2019
Electrodeposited Tin‐Antimony Alloys as Novel Electrocatalysts for Selective and Stable Carbon Dioxide Reduction to Formate journal August 2020
Insight into the Mechanism of Hydrogenation of Amino Acids to Amino Alcohols Catalyzed by a Heterogeneous MoO x -Modified Rh Catalyst journal December 2014
Electrocatalytic Upgrading of Biomass‐Derived Intermediate Compounds to Value‐Added Products journal June 2018
Electrochemical Reduction and Carboxylation of Ethyl Cinnamate in MeCN journal September 2008
Electrosyntheses of α -Hydroxycarboxylic Acids from Carbon Dioxide and Aromatic Ketones Using Nickel as the Cathode journal August 2009
Electrocarboxylation of Carbon Dioxide with Polycyclic Aromatic Hydrocarbons Using Ni as the Cathode journal October 2010
Photochemical and Electrochemical Carbon Dioxide Utilization with Organic Compounds journal May 2018
Conversion of Furfuryl Alcohol into Ethyl Levulinate using Solid Acid Catalysts journal May 2009
Synthesis of Biobased Succinonitrile from Glutamic Acid and Glutamine journal May 2011
Electrochemical Synthesis of Adiponitrile from the Renewable Raw Material Glutamic Acid journal March 2012
Electrochemical Valorisation of Glycerol journal October 2012
Electrocatalytic Hydrogenation and Deoxygenation of Glucose on Solid Metal Electrodes journal January 2013
Electricity Storage in Biofuels: Selective Electrocatalytic Reduction of Levulinic Acid to Valeric Acid or γ-Valerolactone journal March 2013
Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity journal November 2013
Selective Glycerol Oxidation by Electrocatalytic Dehydrogenation journal March 2014
Guaiacol Hydrodeoxygenation Mechanism on Pt(111): Insights from Density Functional Theory and Linear Free Energy Relations journal December 2014
The Dilemma of Supporting Electrolytes for Electroorganic Synthesis: A Case Study on Kolbe Electrolysis journal November 2015
A Gross-Margin Model for Defining Technoeconomic Benchmarks in the Electroreduction of CO 2 journal June 2016
Electrochemical Coupling of Biomass-Derived Acids: New C 8 Platforms for Renewable Polymers and Fuels journal December 2016
Electrochemistry for the Generation of Renewable Chemicals: One‐Pot Electrochemical Deoxygenation of Xylose to δ‐Valerolactone journal April 2017
Hydroxyacetone: A Glycerol-Based Platform for Electrocatalytic Hydrogenation and Hydrodeoxygenation Processes journal July 2017
Electrochemical Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid (FDCA) in Acidic Media Enabling Spontaneous FDCA Separation journal June 2018
Transition Metal-Free CO 2 Fixation into New Carbon-Carbon Bonds journal August 2018
Protein‐Rich Biomass Waste as a Resource for Future Biorefineries: State of the Art, Challenges, and Opportunities journal April 2019
Synthesis of Biomass‐Derived Ethers for Use as Fuels and Lubricants journal May 2019
Continuous Hydrogenation of Ethyl Levulinate to 1,4‐Pentanediol over 2.8Cu‐3.5Fe/SBA‐15 Catalyst at Low Loading: The Effect of Fe Doping journal July 2019
Electrocatalytic Hydrogenation of Guaiacol in Diverse Electrolytes Using a Stirred Slurry Reactor journal December 2019
Microwave-Assisted Paal-Knorr Reaction - Three-Step Regiocontrolled Synthesis of Polysubstituted Furans, Pyrroles and Thiophenes journal December 2005
Decarboxylation of a Wide Range of Amino Acids with Electrogenerated Hypobromite: Electrochemical Decarboxylation of Amino Acids journal September 2014
Electrochemical Decomposition of Wheat Straw Lignin into Guaiacyl‐, Syringyl‐, and Phenol‐Type Compounds Using Pb/PbO 2 Anode and Alloyed Steel Cathode in Alkaline Solution journal November 2018
L-Valinol undL-Tyrosinol journal January 1949
Reduktionen einiger einfacher Peptide mit Lithiumaluminiumhydrid journal August 1952
Improved grid-based algorithm for Bader charge allocation journal January 2007
Nanostructured electrocatalysts for electrochemical carboxylation with CO 2 journal July 2020
Electrochemical oxidation and cleavage of peptides analyzed with on-line mass spectrometric detection journal January 2003
Is It Appropriate to Use the Nafion Membrane in Electrocatalytic N 2 Reduction? journal August 2019
Universality in Heterogeneous Catalysis journal July 2002
Selective Catalysis for Renewable Feedstocks and Chemicals book January 2014
Biorefinery of Alternative Resources: Targeting Green Fuels and Platform Chemicals book January 2020
Kinetic study of electrochemical reactions at catalyst-recast ionomer interfaces from thin active layer modelling journal September 1994
Simultaneous electrolytic production of xylitol and xylonic acid from xylose journal April 1991
The use of a porous hydrogen diffusion anode in the electrochemical reduction of glucose to sorbitol journal January 1992
Biomass in the manufacture of industrial products—the use of proteins and amino acids journal March 2007
Distillers’ dried grains with solubles (DDGS) and its potential as fermentation feedstock journal May 2020
TEMPO mediated oxidation of carbohydrates using electrochemical methods journal April 2010
Electrochemical reduction selectivity of crotonaldehyde on copper journal April 2020
A comparative study of thermal- and electrocatalytic conversion of furfural: methylfuran as a primary and major product journal April 2020
Electrochemical oxidative valorization of lignin by the nanostructured PbO2/MWNTs electrocatalyst in a low-energy depolymerization process journal July 2020
Dehydration of glycerol with silica–phosphate-supported copper catalyst journal April 2020
Density Functional Theory Study of Selectivity Considerations for C–C Versus C–O Bond Scission in Glycerol Decomposition on Pt(111) journal May 2012
Synthesis and performance evaluation of silica-supported copper chromite catalyst for glycerol dehydration to acetol journal August 2019
Lignin Pyrolysis Components and Upgrading—Technology Review journal February 2013
Infra red spectroscopy of the electrode-electrolyte interphase journal April 1980
The electrochemistry of l-cystine and l-cysteine part 2 : Electrosynthesis of l-cysteine at solid electrodes journal September 1994
Electro-oxidation of d-mannitol on platinum single crystal surfaces journal July 2001
Electroreduction of aliphatic esters using new paired electrolysis systems journal July 2001
Electrochemical reduction of butyraldehyde in the presence of CO2 journal July 2002
Electrocatalysis of methanol oxidation journal August 2002
An evaluation of the macro-homogeneous and agglomerate model for oxygen reduction in PEMFCs journal August 1998
On the oxidation of d-sorbitol on platinum single crystal electrodes: a voltammetric and in situ FTIRS study journal October 1998
Electrocatalytic oxidation of d-sorbitol on platinum in acid medium: analysis of the reaction products journal July 1997
Electrochemical and in situ FTIR studies on the adsorption and oxidation of glycine and lysine in alkaline medium journal June 1998
In-situ FTIR studies on the electrochemical oxidation of histidine and tyrosine journal March 1999
The Synthesis of Vicinal Amino Alcohols journal April 2000
Synthesis of l-cysteic acid by indirect electrooxidation and an example of paired synthesis: L-cysteic and l-cysteine from l-cystine journal January 1991
Electrochemical carboxylation of aldehydes and ketones with sacrificial aluminum anodes. journal January 1986
Surface science studies of model fuel cell electrocatalysts journal April 2002
A review of the state-of-the-art of the methanol crossover in direct methanol fuel cells journal November 1999
Use of electrocatalytic membrane reactor for synthesis of sorbitol journal February 2000
Industrial processes for manufacturing amines journal November 2001
Low-pressure hydrogenolysis of glycerol to propylene glycol journal March 2005
CO methanation over supported bimetallic Ni–Fe catalysts: From computational studies towards catalyst optimization journal March 2007
A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts journal March 2005
The methanol oxidation reaction on platinum alloys with the first row transition metals journal March 2006
Catalytic hydroconversion of a wheat straw soda lignin: Characterization of the products and the lignin residue journal February 2014
Selective electro-oxidation of glycerol to tartronate or mesoxalate on Au nanoparticle catalyst via electrode potential tuning in anion-exchange membrane electro-catalytic flow reactor journal April 2014
Carbon nanotube supported PdAg nanoparticles for electrocatalytic oxidation of glycerol in anion exchange membrane fuel cells journal August 2017
Highly efficient and selective electrooxidation of glucose and xylose in alkaline medium at carbon supported alloyed PdAu nanocatalysts journal April 2019
Valorization of wood biomass-lignin via selective bond scission: A minireview journal November 2019
Selecting emerging CO2 utilization products for short- to mid-term deployment journal February 2019
Recent progress in electrochemical oxidation of saccharides at gold and copper electrodes in alkaline solutions journal September 2009
Review of fast pyrolysis of biomass and product upgrading journal March 2012
Availability of protein-derived amino acids as feedstock for the production of bio-based chemicals journal September 2012
Critical parameters in cost-effective alkaline extraction for high protein yield from leaves journal August 2014
Electrochemical conversion of lignin to useful chemicals journal May 2016
Hydrothermal liquefaction of biomass: Developments from batch to continuous process journal February 2015
Microbial electrolysis cells for waste biorefinery: A state of the art review journal September 2016
Biodegradation of lignin by fungi, bacteria and laccases journal November 2016
Conversion of biomass to hydroxymethylfurfural: A review of catalytic systems and underlying mechanisms journal August 2017
Catalytic production of 1,4-pentanediol from corn stover journal December 2017
Bioconversion of biomass waste into high value chemicals journal February 2020
Microbial strategies for bio-transforming food waste into resources journal March 2020
Medium chain carboxylic acids production from waste biomass: Current advances and perspectives journal September 2019
Glycerol electro-oxidation to dihydroxyacetone on phosphorous-doped Pd/CNT nanoparticles in alkaline medium journal May 2020
Homogeneous and heterogeneous ruthenium catalysts in the synthesis of fine chemicals journal March 2007
Enhanced activity for electrochemical hydrogenation and hydrogenolysis of furfural to biofuel using electrodeposited Cu catalysts journal February 2019
Electro-reduction of organics on metal cathodes: A multiscale-modeling study of benzaldehyde on Au (111) journal June 2020
First-principle investigation on catalytic hydrogenation of benzaldehyde over Pt-group metals journal July 2020
Molecular-level descriptions of surface chemistry in kinetic models using density functional theory journal November 2004
Electrochemical carboxylation with carbon dioxide journal February 2017
Electro-conversion as sustainable method for the fine chemical production from the biopolymer lignin journal December 2018
A fast and robust algorithm for Bader decomposition of charge density journal June 2006
Electrocarboxylation of activated olefins in ionic liquid BMIMBF4 journal September 2007
Synthesis of dialkyl carbonates from CO2 and alcohols via electrogenerated N-heterocyclic carbenes journal November 2012
Electrochemical surface area measurements of platinum- and palladium-based nanoparticles journal June 2013
Controlled depolymerization of lignin in an electrochemical membrane reactor journal December 2015
Mechanistic aspects of glycerol electrooxidation on Pt(111) electrode in alkaline media journal January 2018
Electrochemical investigations of the oxidation–reduction of furfural in aqueous medium journal January 2004
Electro-oxidation of d-xylose on platinum and gold electrodes in alkaline medium journal April 2004
Selective electroreduction of pyruvic acid on lead electrode in acid medium journal April 2005
Efficient electrochemical synthesis of 2-arylsuccinic acids from CO2 and aryl-substituted alkenes with nickel as the cathode journal January 2008
Highly regioselective electrochemical synthesis of dioic acids from dienes and carbon dioxide journal January 2011
A homogeneous redox catalytic process for the paired synthesis of l-cysteine and l-cysteic acid from l-cystine journal November 2011
Modeling analysis of electrode fouling during electrolysis of phenolic compounds journal April 2013
Electrocatalytic hydrogenation of furfural to furfuryl alcohol using platinum supported on activated carbon fibers journal July 2014
Fabrication of La-doped TiO2 Film Electrode and investigation of its electrocatalytic activity for furfural reduction journal January 2015
Electrochemical conversion of corn stover lignin to biomass-based chemicals between Cu/Ni Mo Co cathode and Pb/PbO 2 anode in alkali solution journal February 2018
A theoretical analysis of the optimal electrode thickness and porosity journal February 2019
Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock journal November 2008
Hydrothermal liquefaction of biomass: A review of subcritical water technologies journal May 2011
How long does innovation and commercialisation in the energy sectors take? Historical case studies of the timescale from invention to widespread commercialisation in energy supply and end use technology journal December 2018
A review over the role of catalysts for selective short-chain polyglycerol production from biodiesel derived waste glycerol journal August 2020
An overview of the chemical composition of biomass journal May 2010
Biomass modelling: Estimating thermodynamic properties from the elemental composition journal October 2016
Electrochemical valorization of crude glycerol in alkaline medium for energy conversion using Pd, Au and PdAu nanomaterials journal February 2020
Advancement in technologies for the depolymerization of lignin journal December 2018
The battle for biomass: A systematic review of food-feed-fuel competition journal June 2020
Utilization of food waste streams for the production of biopolymers journal September 2020
Hydrothermal degradation of lignin: Products analysis for phenol formaldehyde adhesive synthesis journal January 2015
Highly selective BTX from catalytic fast pyrolysis of lignin over supported mesoporous silica journal October 2016
Glycerol electrooxidation on Pd, Pt and Au nanoparticles supported on carbon ceramic electrode in alkaline media journal November 2012
Biomass to fuel cells state of the art: A review of the most innovative technology solutions journal December 2014
Non-precious metal nanoparticle electrocatalysts for electrochemical modification of lignin for low-energy and cost-effective production of hydrogen journal April 2015
A review of catalytic aqueous-phase reforming of oxygenated hydrocarbons derived from biorefinery water fractions journal July 2016
Pt and Pt–Rh nanowires supported on carbon and SnO2:Sb nanoparticles for ethanol electrochemical oxidation in acidic media journal January 2018
Promotional effect of auxiliary metals Bi on Pt, Pd, and Ag on Au, for glycerol electrolysis journal September 2020
Kraft-lignin pyrolysis and fractional condensation of its bio-oil vapors journal March 2014
Review of microwave-assisted lignin conversion for renewable fuels and chemicals journal May 2016
Toward computational screening in heterogeneous catalysis: Pareto-optimal methanation catalysts journal April 2006
Mild electrocatalytic hydrogenation of lactic acid to lactaldehyde and propylene glycol journal February 2007
Pitfalls and best practices in measurements of the electrochemical surface area of platinum-based nanostructured electro-catalysts journal January 2017
Electrochemical production of lactic acid from glycerol oxidation catalyzed by AuPt nanoparticles journal December 2017
Hydrogenation of benzaldehyde via electrocatalysis and thermal catalysis on carbon-supported metals journal March 2018
Density functional theory study of furfural electrochemical oxidation on the Pt (1 1 1) surface journal May 2019
Electro-oxidation of furfural on gold is limited by furoate self-assembly journal November 2020
A review on photochemical, biochemical and electrochemical transformation of CO2 into value-added products journal October 2019
Biomass gasification technology: The state of the art overview journal January 2016
Electrocatalytic oxidation of d-galactose in alkaline medium journal May 2004
The electrochemical oxidation of xylitol on Pt (111) in acid medium journal September 2004
Vibrational frequencies of CO on Pt(111) in electric field: A periodic DFT study journal September 2007
Electrooxidation of xylitol on platinum single crystal electrodes: A voltammetric and in situ FTIRS study journal October 2007
Electro-oxidation of d-mannose on platinum, gold and nickel electrodes in aqueous medium journal December 2007
Influences of the operative parameters and the nature of the substrate on the electrocarboxylation of benzophenones journal January 2012
Efficient electrocarboxylation of benzophenone on silver nanoparticles deposited boron doped diamond electrode journal November 2015
What Should We Make with CO2 and How Can We Make It? journal May 2018
First-principles based microkinetic modeling of borohydride oxidation on a Au(111) electrode journal November 2011
Electrochemical fabrication of dendritic silver–copper bimetallic nanomaterials in protic ionic liquid for electrocarboxylation journal June 2018
Sugarcane vinasse processing: Toward a status shift from waste to valuable resource. A review journal August 2018
Synthesis of 2,5-furandicarboxylic acid by catalytic carbonylation of renewable furfural derived 5-bromofuroic acid journal August 2018
Direct conversion of furfuryl alcohol to butyl levulinate using tin exchanged tungstophosphoric acid catalysts journal June 2020
A review on gasification of biomass journal January 2009
Glycerol: Production, consumption, prices, characterization and new trends in combustion journal November 2013
Glycerol production and its applications as a raw material: A review journal November 2013
A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin journal October 2014
Technologies and developments of third generation biofuel production journal November 2015
Wastes and biomass materials as sustainable-renewable energy resources for Jordan journal January 2017
A review on hydrothermal liquefaction of biomass journal January 2018
From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis journal October 2018
Microalgae lipid and biomass for biofuel production: A comprehensive review on lipid enhancement strategies and their effects on fatty acid composition journal December 2018
Lignin utilization: A review of lignin depolymerization from various aspects journal June 2019
A review of recent developments on kinetics parameters for glycerol electrochemical conversion – A by-product of biodiesel journal February 2020
JDFTx: Software for joint density-functional theory journal January 2017
High pressure water reforming of biomass for energy and chemicals: A short review journal January 2015
One-pot electrocatalytic oxidation of glycerol to DHA journal September 2006
Electrochemical direct carboxylation of benzyl alcohols having an electron-withdrawing group on the phenyl ring: one-step formation of phenylacetic acids from benzyl alcohols under mild conditions journal December 2015
Assessment of the beneficial combination of electrochemical and ultrasonic activation of compounds originating from biomass journal May 2020
The use of sub-critical water hydrolysis for the recovery of peptides and free amino acids from food processing wastes. Review of sources and main parameters journal March 2016
Beyond plucking: Feathers bioprocessing into valuable protein hydrolysates journal July 2019
Uncompensated Resistance. 1. The Effect of Cell Geometry journal September 2000
Uncompensated Resistance. 2. The Effect of Reference Electrode Nonideality journal September 2000
Combining Voltammetry with HPLC: Application to Electro-Oxidation of Glycerol journal July 2010
Electrochemical Oxidation and Cleavage of Tyrosine- and Tryptophan-Containing Tripeptides journal September 2010
Common Pitfalls of Catalysis Manuscripts Submitted to Chemistry of Materials journal May 2018
Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review journal September 2020
Selectivity between Oxygen and Chlorine Evolution in the Chlor-Alkali and Chlorate Processes journal February 2016
Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance journal October 2017
Tetramethylpiperidine N -Oxyl (TEMPO), Phthalimide N -Oxyl (PINO), and Related N -Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions journal April 2018
How Catalysts and Experimental Conditions Determine the Selective Hydroconversion of Furfural and 5-Hydroxymethylfurfural journal October 2018
Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O 2 and Oxidation of H 2 , Alcohols, Biomass, and Complex Fuels journal March 2020
Minireview on Bio-Oil Upgrading via Electrocatalytic Hydrogenation: Connecting Biofuel Production with Renewable Power journal June 2020
General Techno-Economic Analysis of CO 2 Electrolysis Systems journal February 2018
110th Anniversary: Microkinetic Modeling of the Vapor Phase Upgrading of Biomass-Derived Oxygenates journal July 2019
Unified Approach to Implicit and Explicit Solvent Simulations of Electrochemical Reaction Energetics journal October 2019
Automatic Generation of Microkinetic Mechanisms for Heterogeneous Catalysis journal May 2017
Mechanistic Insights Evaluating Ag, Pb, and Ni as Electrocatalysts for Furfural Reduction from First-Principles Methods journal November 2017
Group Additivity for Aqueous Phase Thermochemical Properties of Alcohols on Pt(111) journal September 2017
Controlled-Potential Simulation of Elementary Electrochemical Reactions: Proton Discharge on Metal Surfaces journal May 2018
Electrooxidation of Glycerol on Gold in Acidic Medium: A Combined Experimental and DFT Study journal April 2018
Insights into the Electrochemical Oxygen Evolution Reaction with ab Initio Calculations and Microkinetic Modeling: Beyond the Limiting Potential Volcano journal July 2019
Electrochemical Barriers Made Simple journal June 2015
Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO 2 : New Theoretical Insights from an Improved Electrochemical Model journal April 2016
Potential Dependence of Electrochemical Barriers from ab Initio Calculations journal April 2016
Building Blocks for High Performance in Electrocatalytic CO 2 Reduction: Materials, Optimization Strategies, and Device Engineering journal August 2017
Calculations of the pH-Dependent Onset Potential for CO Electrooxidation on Au(111) journal November 2018
Electrochemical Screening for Electroorganic Synthesis journal December 2015
Highly Modular Flow Cell for Electroorganic Synthesis journal May 2017
Electrocatalytic Hydrogenation of Oxygenated Compounds in Aqueous Phase journal September 2018
Ternary Pt 9 RhFe x Nanoscale Alloys as Highly Efficient Catalysts with Enhanced Activity and Excellent CO-Poisoning Tolerance for Ethanol Oxidation journal March 2017
Selective Electro-Oxidation of Glycerol to Dihydroxyacetone by PtAg Skeletons journal July 2019
Modification of Nickel Surfaces by Bismuth: Effect on Electrochemical Activity and Selectivity toward Glycerol journal March 2020
Effect of Collective Dynamics and Anharmonicity on Entropy in Heterogenous Catalysis: Building the Case for Advanced Molecular Simulations journal July 2020
Status of Biocatalysis in the Production of 2,5-Furandicarboxylic Acid journal July 2020
Efficient and Selective Electrochemical and Photoelectrochemical Reduction of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan using Water as the Hydrogen Source journal February 2016
Structure Sensitivity in Catalytic Hydrogenation at Platinum Surfaces Measured by Shell-Isolated Nanoparticle Enhanced Raman Spectroscopy (SHINERS) journal February 2016
Toward Benchmarking in Catalysis Science: Best Practices, Challenges, and Opportunities journal March 2016
Furfural: A Promising Platform Compound for Sustainable Production of C 4 and C 5 Chemicals journal October 2016
Electrocatalytic Conversion of Furanic Compounds journal September 2016
Combined EC-NMR and In Situ FTIR Spectroscopic Studies of Glycerol Electrooxidation on Pt/C, PtRu/C, and PtRh/C journal October 2016
PdPb-Catalyzed Decarboxylation of Proline to Pyrrolidine: Highly Selective Formation of a Biobased Amine in Water journal September 2016
Efficient H 2 Evolution Coupled with Oxidative Refining of Alcohols via A Hierarchically Porous Nickel Bifunctional Electrocatalyst journal June 2017
Mechanism of CO 2 Reduction at Copper Surfaces: Pathways to C 2 Products journal January 2018
A Combined Experimental and Theoretical Study on the Activity and Selectivity of the Electrocatalytic Hydrogenation of Aldehydes journal June 2018
Electrochemical Oxidation of 5-Hydroxymethylfurfural with NiFe Layered Double Hydroxide (LDH) Nanosheet Catalysts journal May 2018
Recent Advances in Thermo-, Photo-, and Electrocatalytic Glycerol Oxidation journal May 2018
Challenges in Modeling Electrochemical Reaction Energetics with Polarizable Continuum Models journal November 2018
Enzymatic Carboxylation of 2-Furoic Acid Yields 2,5-Furandicarboxylic Acid (FDCA) journal February 2019
Elucidating Acidic Electro-Oxidation Pathways of Furfural on Platinum journal September 2019
Understanding the Role of Metal and Molecular Structure on the Electrocatalytic Hydrogenation of Oxygenated Organic Compounds journal September 2019
Light-Driven Depolymerization of Native Lignin Enabled by Proton-Coupled Electron Transfer journal November 2019
Conversion of Furfural Derivatives to 1,4-Pentanediol and Cyclopentanol in Aqueous Medium Catalyzed by trans -[(2,9-Dipyridyl-1,10-phenanthroline)(CH 3 CN) 2 Ru](OTf) 2 journal January 2020
Redox Catalysis Facilitates Lignin Depolymerization journal June 2017
Condensation of α-Carbonyl Aldehydes Leads to the Formation of Solid Humins during the Hydrothermal Degradation of Carbohydrates journal April 2019
Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide journal February 2020
Controlling Selectivity in the Electrocatalytic Hydrogenation of Adiponitrile through Electrolyte Design journal June 2020
Selective Production of Maleic Acid from Furfural via a Cascade Approach Combining Photochemistry and Electro- or Biochemistry journal July 2020
Electrochemical Conversion of Muconic Acid to Biobased Diacid Monomers journal May 2016
Electrocatalytic Hydrogenation and Hydrogenolysis of Furfural and the Impact of Homogeneous Side Reactions of Furanic Compounds in Acidic Electrolytes journal October 2016
Unravelling Electrochemical Lignin Depolymerization journal May 2018
Anion Exchange Membrane Electrolyzers as Alternative for Upgrading of Biomass-Derived Molecules journal May 2018
Technoeconomics of Commodity Chemical Production Using Sunlight journal April 2018
Electrochemical Valorization of Furfural to Maleic Acid journal June 2018
Advances in the Use of Protein-Based Materials: Toward Sustainable Naturally Sourced Absorbent Materials journal January 2019
Electrocatalytic Upgrading of Phenolic Compounds Observed after Lignin Pyrolysis journal March 2019
Sacrificial Anode-Free Electrosynthesis of α-Hydroxy Acids via Electrocatalytic Coupling of Carbon Dioxide to Aromatic Alcohols journal September 2019
Alkaline Bromine Oxidation of Amino Acids and Peptides: Formation of α-Ketoacyl Peptides and Their Cleavage by Hydrogen Peroxide * journal January 1962
Catalytic Upgrading of Fermentation-Derived Organic Acids journal October 1999
Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation journal October 2007
Chemical Routes for the Transformation of Biomass into Chemicals journal June 2007
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal September 2006
Probing Liquid/Solid Interfaces at the Molecular Level journal January 2012
Reactivity Theory of Transition-Metal Surfaces: A Brønsted−Evans−Polanyi Linear Activation Energy−Free-Energy Analysis journal December 2009
1,2-Amino Alcohols and Their Heterocyclic Derivatives as Chiral Auxiliaries in Asymmetric Synthesis journal January 1996
Underpotential Deposition at Single Crystal Surfaces of Au, Pt, Ag and Other Materials journal July 2001
Highly Selective Electro-Oxidation of Glycerol to Dihydroxyacetone on Platinum in the Presence of Bismuth journal April 2012
DFT Study of Furfural Conversion to Furan, Furfuryl Alcohol, and 2-Methylfuran on Pd(111) journal October 2012
Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals journal April 2013
Role of Lewis and Brønsted Acid Sites in the Dehydration of Glycerol over Niobia journal August 2014
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review journal May 2006
Thermochemistry of Compounds Formed during Fast Pyrolysis of Lignocellulosic Biomass journal October 2008
Rule-Based Generation of Thermochemical Routes to Biomass Conversion journal November 2010
Life Cycle Optimization of Biomass-to-Liquid Supply Chains with Distributed–Centralized Processing Networks journal September 2011
Surface-enhanced infrared absorption of p-nitrobenzoic acid deposited on silver island films: contributions of electromagnetic and chemical mechanisms journal November 1991
Electrochemical Reactions and Mechanisms in Organic Chemistry By James Grimshaw (The Queen's University of Belfast). Elsevier:  Amsterdam and New York. 2000. xii + 401 pp. $251.50. ISBN 0-444-72007-3. journal March 2002
Formate, an Active Intermediate for Direct Oxidation of Methanol on Pt Electrode journal April 2003
Ni-Catalyzed Cleavage of Aryl Ethers in the Aqueous Phase journal December 2012
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices journal March 2015
Multiple Mechanisms Mapped in Aryl Alkyl Ether Cleavage via Aqueous Electrocatalytic Hydrogenation over Skeletal Nickel journal February 2020
A General Strategy for Decoupled Hydrogen Production from Water Splitting by Integrating Oxidative Biomass Valorization journal October 2016
Mechanisms of Furfural Reduction on Metal Electrodes: Distinguishing Pathways for Selective Hydrogenation of Bioderived Oxygenates journal September 2017
Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide journal August 2017
Suppressing Ion Transfer Enables Versatile Measurements of Electrochemical Surface Area for Intrinsic Activity Comparisons journal February 2018
Electroorganic chemistry. 134. Facile electroreduction of methyl esters and N,N-dimethylamides of aliphatic carboxylic acids to primary alcohols journal February 1992
Electrochemically Promoted C−N Bond Formation from Amines and CO 2 in Ionic Liquid BMIm−BF 4 :  Synthesis of Carbamates journal January 2007
Electrochemical Cleavage of Aryl Ethers Promoted by Sodium Borohydride journal October 2014
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode journal November 2004
New Oscillatory Electrocatalytic Oxidation of Amino Compounds on a Nanoporous Film Electrode of Electrodeposited Nickel Hydroxide Nanoflakes journal November 2007
Decomposition Pathways of Glycerol via C–H, O–H, and C–C Bond Scission on Pt(111): A Density Functional Theory Study journal September 2011
In Situ Ru K-Edge X-ray Absorption Spectroscopy Study of Methanol Oxidation Mechanisms on Model Submonolayer Ru on Pt Nanoparticle Electrocatalyst journal September 2013
How Much Supporting Electrolyte Is Required to Make a Cyclic Voltammetry Experiment Quantitatively “Diffusional”? A Theoretical and Experimental Investigation journal June 2009
In Situ SHINERS at Electrochemical Single-Crystal Electrode/Electrolyte Interfaces: Tuning Preparation Strategies and Selected Applications journal September 2013
Photocatalytic Decarboxylative Reduction of Carboxylic Acids and Its Application in Asymmetric Synthesis journal July 2014
Energy: Reimagine fuel cells journal September 2015
Carbon dioxide utilization via carbonate-promoted C–H carboxylation journal March 2016
The promoting effect of adsorbed carbon monoxide on the oxidation of alcohols on a gold catalyst journal December 2011
Effects of correlated parameters and uncertainty in electronic-structure-based chemical kinetic modelling journal February 2016
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts journal September 2009
To address surface reaction network complexity using scaling relations machine learning and DFT calculations journal March 2017
Using carbon dioxide as a building block in organic synthesis journal January 2015
Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts journal October 2015
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution journal October 2006
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces journal February 2007
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts journal May 2012
Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone journal April 2019
General technoeconomic analysis for electrochemical coproduction coupling carbon dioxide reduction with organic oxidation journal November 2019
Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold journal January 2020
Efficient electrochemical production of glucaric acid and H2 via glucose electrolysis journal January 2020
A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements journal May 2019
Sustainable Electrochemical Depolymerization of Lignin in Reusable Ionic Liquids journal July 2017
Biomass waste utilisation in low-carbon products: harnessing a major potential resource journal October 2019
Machine learning in catalysis journal April 2018
Complete electron economy by pairing electrolysis with hydrogenation journal June 2018
Distributed processes for biomass conversion could aid UN Sustainable Development Goals journal October 2018
Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products journal March 2019
Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion journal September 2015
Conversion of biomass-derived sorbitol to glycols over carbon-materials supported Ru-based catalysts journal November 2015
Electrochemical activation of CO2 in ionic liquid (BMIMBF4): synthesis of organic carbonates under mild conditions journal January 2008
The critical role of heterogeneous catalysis in lignocellulosic biomass conversion journal January 2009
Electrochemistry at nanoporous interfaces: new opportunity for electrocatalysis journal January 2012
Electrochemistry for biofuel generation: Electrochemical conversion of levulinic acid to octane journal January 2012
Automated identification of energetically feasible mechanisms of complex reaction networks in heterogeneous catalysis: application to glycerol conversion on transition metals journal January 2014
Integrated electrocatalytic processing of levulinic acid and formic acid to produce biofuel intermediate valeric acid journal January 2014
Electrocarboxylation of acetophenone in ionic liquids: the influence of proton availability on product distribution journal January 2014
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions journal January 2015
Scaling relations between adsorption energies for computational screening and design of catalysts journal January 2014
Cellulose and hemicellulose valorisation: an integrated challenge of catalysis and reaction engineering journal January 2014
A general framework for the assessment of solar fuel technologies journal January 2015
Electrocatalytic upgrading of model lignin monomers with earth abundant metal electrodes journal January 2015
Pd-catalyzed decarboxylation of glutamic acid and pyroglutamic acid to bio-based 2-pyrrolidone journal January 2015
Synthesis of biomass-derived methylcyclopentane as a gasoline additive via aldol condensation/hydrodeoxygenation of 2,5-hexanedione journal January 2015
Electrochemical depolymerization of lignin into renewable aromatic compounds in a non-diaphragm electrolytic cell journal January 2014
Electrochemistry for the generation of renewable chemicals: electrochemical conversion of levulinic acid journal January 2015
Ruthenium-catalyzed aerobic oxidative decarboxylation of amino acids: a green, zero-waste route to biobased nitriles journal January 2015
Electrochemical reduction of aromatic ketones in 1-butyl-3-methylimidazolium-based ionic liquids in the presence of carbon dioxide: the influence of the ketone substituent and the ionic liquid anion on bulk electrolysis product distribution journal January 2015
Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels journal January 2016
Highly selective transformation of glycerol to dihydroxyacetone without using oxidants by a PtSb/C-catalyzed electrooxidation process journal January 2016
Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers journal January 2015
Electrochemical reductive biomass conversion: direct conversion of 5-hydroxymethylfurfural (HMF) to 2,5-hexanedione (HD) via reductive ring-opening journal January 2016
An integrated electrochemical process to convert lignin to value-added products under mild conditions journal January 2016
Electrochemical depolymerisation of lignin in a deep eutectic solvent journal January 2016
Electrocatalytic upgrading of itaconic acid to methylsuccinic acid using fermentation broth as a substrate solution journal January 2017
The importance of grand-canonical quantum mechanical methods to describe the effect of electrode potential on the stability of intermediates involved in both electrochemical CO 2 reduction and hydrogen evolution journal January 2018
A switchable route to valuable commodity chemicals from glycerol via electrocatalytic oxidation with an earth abundant metal oxidation catalyst journal January 2017
Emulsion electro-oxidation of kraft lignin journal January 2017
Selective hydrodeoxygenation of 5-hydroxy-2(5H)-furanone to γ-butyrolactone over Pt/mesoporous solid acid bifunctional catalyst journal January 2017
Study on the cleavage of alkyl-O-aryl bonds by in situ generated hydroxyl radicals on an ORR cathode journal January 2017
Towards a sustainable electrochemical activation for recycling CO 2 : synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines journal January 2017
Electrochemical hydrogenation of non-aromatic carboxylic acid derivatives as a sustainable synthesis process: from catalyst design to device construction journal January 2019
Hydrodeoxygenation of guaiacol over bimetallic Fe-alloyed (Ni, Pt) surfaces: reaction mechanism, transition-state scaling relations and descriptor for predicting C–O bond scission reactivity journal January 2018
Electrocatalytic degradation of rice straw lignin in alkaline solution through oxidation on a Ti/SnO 2 –Sb 2 O 3 /α-PbO 2 /β-PbO 2 anode and reduction on an iron or tin doped titanium cathode journal January 2018
Electrocatalytic valorisation of biomass derived chemicals journal January 2018
Coproduction of succinic acid and cadaverine using lysine as a neutralizer and CO 2 donor with l -lysine decarboxylase overexpressed Escherichia coli AFP111 journal January 2018
Electrochemical cross-coupling of biogenic di-acids for sustainable fuel production journal January 2019
Towards selective electrochemical conversion of glycerol to 1,3-propanediol journal January 2018
Efficient cleavage of aryl ether C–O linkages by Rh–Ni and Ru–Ni nanoscale catalysts operating in water journal January 2018
Surface engineering in PbS via partial oxidation: towards an advanced electrocatalyst for reduction of levulinic acid to γ-valerolactone journal January 2019
Recent advances in the electrooxidation of biomass-based organic molecules for energy, chemicals and hydrogen production journal January 2020
Electrochemical conversion of a bio-derivable hydroxy acid to a drop-in oxygenate diesel fuel journal January 2019
Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO 2 utilization journal January 2020
High-efficiency electrochemical hydrodeoxygenation of bio-phenols to hydrocarbon fuels by a superacid-noble metal particle dual-catalyst system journal January 2020
Paired electrocatalytic hydrogenation and oxidation of 5-(hydroxymethyl)furfural for efficient production of biomass-derived monomers journal January 2019
Early-stage evaluation of emerging CO 2 utilization technologies at low technology readiness levels journal January 2020
Electrocatalytic cleavage of lignin model dimers using ruthenium supported on activated carbon cloth journal January 2020
Electrochemically catalyzed conversion of cornstalk lignin to aromatic compounds: an integrated process of anodic oxidation of a Pb/PbO 2 electrode and hydrogenation of a nickel cathode in sodium hydroxide solution journal January 2020
Recent catalytic routes for the preparation and the upgrading of biomass derived furfural and 5-hydroxymethylfurfural journal January 2020
Catalytic production of 1,4-pentanediol from furfural in a fixed-bed system under mild conditions journal January 2020
Structure of the water/platinum interface––a first principles simulation under bias potential journal January 2008
Catalytic upgrading of levulinic acid to 5-nonanone journal January 2010
Organic electrosynthesis: a promising green methodology in organic chemistry journal January 2010
Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing journal January 2011
Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance journal January 2012
Top ten fundamental challenges of biomass pyrolysis for biofuels journal January 2012
Tunable copper-catalyzed chemoselective hydrogenolysis of biomass-derived γ-valerolactone into 1,4-pentanediol or 2-methyltetrahydrofuran journal January 2012
Selective electro-conversion of glycerol to glycolate on carbon nanotube supported gold catalyst journal January 2012
Mild electrocatalytic hydrogenation and hydrodeoxygenation of bio-oil derived phenolic compounds using ruthenium supported on activated carbon cloth journal January 2012
Electrochemical synthesis of a novel compound, 5-acetyl-2,9-decanedione, and theoretical analysis of its lithium ion complex journal January 2012
Aqueous phase hydrogenation of levulinic acid to 1,4-pentanediol journal January 2014
Electrochemistry for biofuel generation: production of furans by electrocatalytic hydrogenation of furfurals journal January 2013
Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass journal January 2013
Electrochemical dicarboxylation of conjugated fatty acids as an efficient valorization of carbon dioxide journal January 2013
Lignin depolymerization via an integrated approach of anode oxidation and electro-generated H2O2 oxidation journal January 2014
Electrochemical activation of carbon dioxide: synthesis of carbamates journal January 1996
Cathodic reduction of glucose
  • bin Kassim, Annvar; Rice, Colin L.; Kuhn, Anselm T.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 77, Issue 3 https://doi.org/10.1039/f19817700683
journal January 1981
702. 1 : 2-Dicarboxylic acids. Part I. Positional isomerides derived from methylsuccinic acid; with a note on the rearrangement of unsymmetrical compounds of this type journal January 1953
Organic electrochemistry journal January 1969
Inertia and driving force of chemical reactions journal January 1938
On the Oxidation of Amino-acids and of related substances with chloramine-T journal August 1917
One-pot Sequence for the Decarboxylation of α-Amino Acids journal January 2003
Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points journal December 2000
Efficient methods for finding transition states in chemical reactions: Comparison of improved dimer method and partitioned rational function optimization method journal December 2005
Accurate and efficient algorithm for Bader charge integration journal February 2011
Revised self-consistent continuum solvation in electronic-structure calculations journal February 2012
A dimer method for finding saddle points on high dimensional potential surfaces using only first derivatives journal October 1999
Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways journal February 2014
Weighted-density functionals for cavity formation and dispersion energies in continuum solvation models journal October 2014
Spicing up continuum solvation models with SaLSA: The spherically averaged liquid susceptibility ansatz journal February 2015
The charge-asymmetric nonlocally determined local-electric (CANDLE) solvation model journal February 2015
Grand canonical electronic density-functional theory: Algorithms and applications to electrochemistry journal March 2017
Implicit self-consistent electrolyte model in plane-wave density-functional theory journal December 2019
Density functional theory in surface chemistry and catalysis journal January 2011
Ab initio molecular dynamics of solvation effects on reactivity at electrified interfaces journal August 2016
Mechanistic insights into electrochemical reduction of CO 2 over Ag using density functional theory and transport models journal October 2017
Synergy between Fe and Ni in the optimal performance of (Ni,Fe)OOH catalysts for the oxygen evolution reaction journal May 2018
Climate change mitigation potential of carbon capture and utilization in the chemical industry journal May 2019
Simple Methodology for the Preparation of Amino Alcohols from Amino Acid Esters Using NaBH 4 –Methanol in THF journal April 2011
Rapid Conventional and Microwave-Assisted Decarboxylation of L-Histidine and Other Amino Acids via Organocatalysis with R-Carvone Under Superheated Conditions journal November 2015
Estimation of Pure-Component Properties from Group-Contributions journal July 1987
Electro-oxidation of waste glycerol to tartronic acid over Pt/CNT nanocatalyst: study of effect of reaction time on product distribution journal November 2019
Atomic scale simulations of heterogeneous electrocatalysis: recent advances journal May 2017
Conversion of α‐Amino Acids into Nitriles by Oxidative Decarboxylation with Trichloroisocyanuric Acid journal January 2004
A grid-based Bader analysis algorithm without lattice bias journal January 2009
The importance of nonlinear fluid response in joint density-functional theory studies of battery systems journal October 2013
Adsorbate-substrate and adsorbate-adsorbate interactions of Na and K adlayers on Al(111) journal December 1992
Surface-diffusion mechanism versus electric field: Pt/Pt(001) journal September 2001
Reconstruction of charged surfaces: General trends and a case study of Pt(110) and Au(110) journal December 2003
Effect of external electric field on the surface energetics of Ag ∕ Si ( 111 ) journal January 2005
First-principles calculations of charged surfaces and interfaces: A plane-wave nonrepeated slab approach journal March 2006
First principles reaction modeling of the electrochemical interface: Consideration and calculation of a tunable surface potential from atomic and electronic structure journal April 2006
Green’s function method for elimination of the spurious multipole interaction in the surface/interface slab model journal October 2009
Physical and Chemical Nature of the Scaling Relations between Adsorption Energies of Atoms on Metal Surfaces journal March 2012
Scaling Properties of Adsorption Energies for Hydrogen-Containing Molecules on Transition-Metal Surfaces journal July 2007
Ammonia Synthesis from First-Principles Calculations journal January 2005
The Path Forward for Biofuels and Biomaterials journal January 2006
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene journal June 2008
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells journal April 2009
Valorization of Biomass: Deriving More Value from Waste journal August 2012
Assessing the reliability of calculated catalytic ammonia synthesis rates journal July 2014
What would it take for renewably powered electrosynthesis to displace petrochemical processes? journal April 2019
Concentration and distribution of oxygen-containing compounds in crude oils from the southeastern part of Western Siberia journal July 2012
Anodic Oxidation of Serine Anion on Smooth and Platinized Platinum journal July 2018
Electrochemical Conversion of Biomass-Based Oxygenated Compounds journal June 2019
Unraveling Reaction Pathways and Specifying Reaction Kinetics for Complex Systems journal July 2012
Theoretical Heterogeneous Catalysis: Scaling Relationships and Computational Catalyst Design journal June 2016
Trends in the Exchange Current for Hydrogen Evolution journal January 2005
Flow Reactor Studies of the Paired Electro‐Oxidation and Electroreduction of Glucose journal August 1985
Polarographic Studies in Acetonitrile and Dimethylformamide journal January 1960
Simultaneous Hydrogen Evolution and Lignin Depolymerization using NiSn Electrocatalysts in a Biomass-Depolarized Electrolyzer journal January 2020
Elementary Mechanisms in Electrocatalysis: Revisiting the ORR Tafel Slope journal January 2012
Electrochemical Generation of ROS in Ionic Liquid for the Degradation of Lignin Model Compound journal January 2018
Electrochemical Manufacturing in the Chemical Industry journal January 2014
Bio-oil based biorefinery strategy for the production of succinic acid journal January 2013
Biomass and lipid induction strategies in microalgae for biofuel production and other applications journal October 2019
Recent developments in maleic acid synthesis from bio-based chemicals journal June 2015
Synthesis of L-Cysteine and L-Cysteic Acid by Paired Electrolysis Method journal March 2004
Studies on Optically Active Amino Acids. V. Synthesis of Optically Active α-Aminoalcohols by the Reduction of α-Amino Acid Esters with Sodium Borohydride journal January 1965
Oxidative decarboxylation of α-amino acids to nitriles using o-iodoxybenzoic acid in aqueous ammonia journal January 2011
Aqueous-phase oxidation of 5-hydroxymethylfurfural over Pt/ZrO2 catalysts: exploiting the alkalinity of the reaction medium and catalyst basicity journal January 2016
A review of recent progress on electrocatalysts toward efficient glycerol electrooxidation journal January 2020
Electrochemical Lignin Degradation in Ionic Liquids on Ternary Mixed Metal Electrodes journal February 2018
Top Value-Added Chemicals from Biomass - Volume II—Results of Screening for Potential Candidates from Biorefinery Lignin report October 2007
Bioenergy II: Suitability of Wood Chips and Various Biomass Types for Use in Plant of BtL Production by Gasification journal April 2010
Biochemical Conversion Processes of Lignocellulosic Biomass to Fuels and Chemicals – A Review journal October 2015
Selective Electrooxidation of Glycerol Into Value-Added Chemicals: A Short Overview journal February 2019
Glycerol Electro-Oxidation in Alkaline Media and Alkaline Direct Glycerol Fuel Cells journal November 2019
A Review of Microwave Assisted Liquefaction of Ligninin Hydrogen Donor Solvents: Effect of Solvents and Catalysts journal October 2018
Laccases as a Potential Tool for the Efficient Conversion of Lignocellulosic Biomass: A Review journal May 2017
Thermal Conductivity of Protein-Based Materials: A Review journal March 2019
Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids journal January 2014
Highly selective generation of vanillin by anodic degradation of lignin: a combined approach of electrochemistry and product isolation by adsorption journal January 2015
Electroreductive Intramolecular Cyclization of Olefinic Esters and its Application to the Synthesis of Muscone. journal January 1999
Non-Crystalline Copper Oxide Highly Dispersed on Mesoporous Alumina: Synthesis, Characterization and Catalytic Activity in Glycerol Conversion to Acetol journal January 2016

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