Accurate energy eigenvalues for enclosed hydrogen atom within spherical impenetrable boxes
Journal Article
·
· International Journal of Quantum Chemistry
OSTI ID:232341
- Universidad Autonoma Metropolitana-Iztapalapa, Apdo (Mexico)
The authors studies the hydrogen atom confined within spherical impenetrable walls. The potential in the box is the Coulombian potential and outside the box the potential is infinite. To compute the energy eigenvalues of the Schroedinger`s equations, the authors use a method proposed few years ago by Campoy and Palma to solve free quantum systems. The energy eigenvalues are computed with great accuracy for different box sizes, in addition the authors also compute few position expectation values that are related with the hyperfine splitting, nuclear magnetic shielding, polarizability, and pressure. These results are more accurate than the literature calculations. 22 refs., 1 fig., 5 tabs.
- OSTI ID:
- 232341
- Journal Information:
- International Journal of Quantum Chemistry, Journal Name: International Journal of Quantum Chemistry Journal Issue: 2 Vol. 54; ISSN IJQCB2; ISSN 0020-7608
- Country of Publication:
- United States
- Language:
- English
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