Metal–Organic Frameworks for C6 Alkane Separation

Xie, Feng; Yu, Liang; Wang, Hao; Li, Jing

doi:10.1002/anie.202300722

Metal–Organic Frameworks for C6 Alkane Separation

Journal Article · Wed Feb 15 23:00:00 EST 2023 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202300722· OSTI ID:2305683

Xie, Feng ^[1]; Yu, Liang ^[2]; Wang, Hao ^[2]; ^[3]

Rutgers University, Piscataway, NJ (United States); Rutgers University
Shenzhen Polytechnic, Guangdong (China)
Rutgers University, Piscataway, NJ (United States); Shenzhen Polytechnic, Guangdong (China)

The separation of alkane isomers is an important yet challenging process in the petrochemical industry. Being a crucial step to produce premium gasoline components as well as optimum ethylene feed, the current industrial separation by distillation is extremely energy intensive. Adsorptive separation based on zeolite is limited by insufficient adsorption capacity. Metal-organic frameworks (MOFs) hold enormous promise as alternative adsorbents due to their diverse structural tunability and exceptional porosity. Precise control of their pore geometry/dimensions has led to superior performance. In this minireview, we highlight the recent progresses in developing MOFs for the separation of C6 alkane isomers. Representative MOFs are reviewed based on their separation mechanisms. Emphasis is put on the material design rationale for achieving optimal separation capability. Lastly, we briefly discuss the existing challenges, possible solutions, and future directions of this important field.

View Accepted Manuscript (DOE)

Research Organization:: Wake Forest University, Winston-Salem, NC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019902

OSTI ID:: 2305683

Alternate ID(s):: OSTI ID: 1983417

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 20 Vol. 62; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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