Separation of alkane and alkene mixtures by metal–organic frameworks

Wang, Hao; Luo, Dawei; Velasco, Ever; Yu, Liang; Li, Jing

doi:10.1039/d1ta04096k

Title: Separation of alkane and alkene mixtures by metal–organic frameworks

Journal Article · Thu Aug 26 00:00:00 EDT 2021 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/d1ta04096k· OSTI ID:1863574

^[1]; Luo, Dawei ^[1]; Velasco, Ever ^[2]; Yu, Liang ^[1];

^[3]

Shenzhen Polytechnic, Guangdong (China)
Rutgers Univ., Piscataway, NJ (United States)
Rutgers Univ., Piscataway, NJ (United States); Shenzhen Polytechnic, Guangdong (China)

The separation of alkane/alkene gas mixtures represents an important yet challenging process in the petrochemical industry to produce valuable chemical feedstocks with sufficiently high purity. These molecules have similar physical properties, making their separation difficult and capital-intensive. The current separation and purification technology relies largely on heat-driven distillations with a huge unit composed of hundreds of trays. Adsorptive separation using porous solids is capable of accomplishing the purification under ambient conditions, offering potential energy and environmental benefits. In particular, metal–organic frameworks (MOFs) hold enormous promise for this separation process in light of their highly tunable pore shape, pore size, and pore surface functionality. In this review article, we provide a comprehensive account of metal–organic frameworks that have been investigated for the separation of alkanes and alkenes with a focus on C₂–C₃ hydrocarbons. Here, the material design rationale, separation mechanisms, and structure–property relations are highlighted. Finally, the existing challenges and possible design strategies for desirable materials are also discussed.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Wake Forest Univ., Winston-Salem, NC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019902

OSTI ID:: 1863574

Alternate ID(s):: OSTI ID: 1820201

Journal Information:: Journal of Materials Chemistry. A, Vol. 9, Issue 37; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (100)

Microregulation of Pore Channels in Covalent-Organic Frameworks Used for the Selective and Efficient Separation of Ethane He, Chaohui; Wang, Yong; Chen, Yang ACS Applied Materials & Interfaces, Vol. 12, Issue 47 https://doi.org/10.1021/acsami.0c16575	journal	November 2020
Boosting Ethylene/Ethane Separation within Copper(I)‐Chelated Metal–Organic Frameworks through Tailor‐Made Aperture and Specific π‐Complexation Zhang, Ling; Li, Libo; Hu, Enlai Advanced Science, Vol. 7, Issue 2 https://doi.org/10.1002/advs.201901918	journal	November 2019
New 13X zeolite for propylene/propane separation by vacuum swing adsorption Campo, M. C.; Ribeiro, A. M.; Ferreira, A. Separation and Purification Technology, Vol. 103 https://doi.org/10.1016/j.seppur.2012.10.009	journal	January 2013
Pore Size Reduction in Zirconium Metal–Organic Frameworks for Ethylene/Ethane Separation Wang, Yuxiang; Yuan, Shuai; Hu, Zhigang ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 7 https://doi.org/10.1021/acssuschemeng.9b00062	journal	March 2019
Seven chemical separations to change the world Sholl, David S.; Lively, Ryan P. Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/532435a	journal	April 2016
Boosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal–Organic Frameworks Lin, Rui-Biao; Wu, Hui; Li, Libo Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b07563	journal	September 2018
Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Li, Kunhao; Olson, David H.; Seidel, Jonathan Journal of the American Chemical Society, Vol. 131, Issue 30 https://doi.org/10.1021/ja9039983	journal	August 2009
Room temperature synthesis of Cu(Qc)2 and its application for ethane capture from light hydrocarbons Tang, Yuning; Wang, Sa; Zhou, Xin Chemical Engineering Science, Vol. 213 https://doi.org/10.1016/j.ces.2019.115355	journal	February 2020
Metal–Organic Framework Materials for the Separation and Purification of Light Hydrocarbons Cui, Wen‐Gang; Hu, Tong‐Liang; Bu, Xian‐He Advanced Materials, Vol. 32, Issue 3 https://doi.org/10.1002/adma.201806445	journal	May 2019
Selective Binding of O ₂ over N ₂ in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites Bloch, Eric D.; Murray, Leslie J.; Queen, Wendy L. Journal of the American Chemical Society, Vol. 133, Issue 37 https://doi.org/10.1021/ja205976v	journal	September 2011
Polycatenated Molecular Cage-Based Propane Trap for Propylene Purification with Recorded Selectivity Yang, Lifeng; Cui, Xili; Ding, Qi ACS Applied Materials & Interfaces, Vol. 12, Issue 2 https://doi.org/10.1021/acsami.9b19438	journal	December 2019
Current Status of Microporous Metal–Organic Frameworks for Hydrocarbon Separations Pei, Jiyan; Shao, Kai; Zhang, Ling Topics in Current Chemistry, Vol. 377, Issue 6 https://doi.org/10.1007/s41061-019-0257-0	journal	October 2019
Guest-dependent pressure induced gate-opening effect enables effective separation of propene and propane in a flexible MOF Wang, Xiaoqing; Krishna, Rajamani; Li, Libo Chemical Engineering Journal, Vol. 346 https://doi.org/10.1016/j.cej.2018.03.163	journal	August 2018
Ethane-Selective Behavior Achieved on a Nickel-Based Metal–Organic Framework: Impact of Pore Effect and Hydrogen Bonds Wu, Houxiao; Chen, Yongwei; Yang, Wenyuan Industrial & Engineering Chemistry Research, Vol. 58, Issue 24 https://doi.org/10.1021/acs.iecr.9b00997	journal	May 2019
Adsorptive Separation of Propylene and Propane on a Porous Metal-Organic Framework, Copper Trimesate Yoon, Ji-Woong; Jang, In-Tae; Lee, Kwan-Young Bulletin of the Korean Chemical Society, Vol. 31, Issue 1 https://doi.org/10.5012/bkcs.2010.31.01.220	journal	January 2010
Selective Adsorption of Ethane over Ethylene in PCN-245: Impacts of Interpenetrated Adsorbent Lv, Daofei; Shi, Renfeng; Chen, Yongwei ACS Applied Materials & Interfaces, Vol. 10, Issue 9 https://doi.org/10.1021/acsami.7b19414	journal	February 2018
Topology meets MOF chemistry for pore-aperture fine tuning: ftw -MOF platform for energy-efficient separations via adsorption kinetics or molecular sieving Xue, Dong-Xu; Cadiau, Amandine; Weseliński, Łukasz J. Chemical Communications, Vol. 54, Issue 49 https://doi.org/10.1039/C8CC03841D	journal	January 2018
Selective Aerobic Oxidation of a Metal-Organic Framework Boosts Thermodynamic and Kinetic Propylene/Propane Selectivity Wang, Yu; Huang, Ning-Yu; Zhang, Xue-Wen Angewandte Chemie International Edition, Vol. 58, Issue 23 https://doi.org/10.1002/anie.201902209	journal	May 2019
Separation of ethane-ethylene and propane-propylene by Ag(I) doped and sulfurized microporous carbon Saha, Dipendu; Toof, Brandon; Krishna, Rajamani Microporous and Mesoporous Materials, Vol. 299 https://doi.org/10.1016/j.micromeso.2020.110099	journal	June 2020
Understanding ethane/ethylene adsorption selectivity in ethane-selective microporous materials Xiang, Huan; Fan, Xiaolei; Siperstein, Flor R. Separation and Purification Technology, Vol. 241 https://doi.org/10.1016/j.seppur.2020.116635	journal	June 2020
Efficient Separation of Propene and Propane Using Anion-Pillared Metal–Organic Frameworks Wang, Xiaobing; Zhang, Peixin; Zhang, Zhaoqiang Industrial & Engineering Chemistry Research, Vol. 59, Issue 8 https://doi.org/10.1021/acs.iecr.9b06294	journal	January 2020
Adsorption and separation of binary mixtures in a metal-organic framework Cu-BTC: A computational study Wang, Sanyue; Yang, Qingyuan; Zhong, Chongli Separation and Purification Technology, Vol. 60, Issue 1 https://doi.org/10.1016/j.seppur.2007.07.050	journal	April 2008
A Series of Mesoporous Metal‐Organic Frameworks with Tunable Windows Sizes and Exceptionally High Ethane over Ethylene Adsorption Selectivity Lysova, Anna A.; Samsonenko, Denis G.; Kovalenko, Konstantin A. Angewandte Chemie International Edition, Vol. 59, Issue 46 https://doi.org/10.1002/anie.202008132	journal	September 2020
Direct Functionalization of the Open Metal Sites in Rare Earth-Based Metal–Organic Frameworks Used for the Efficient Separation of Ethylene He, Chaohui; Wang, Yong; Chen, Yang Industrial & Engineering Chemistry Research, Vol. 59, Issue 13 https://doi.org/10.1021/acs.iecr.9b06765	journal	March 2020
Kinetic Separation of Propene and Propane in Metal−Organic Frameworks: Controlling Diffusion Rates in Plate-Shaped Crystals via Tuning of Pore Apertures and Crystallite Aspect Ratios Lee, Chang Yeon; Bae, Youn-Sang; Jeong, Nak Cheon Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja200553m	journal	April 2011
Tuning the Structures of Metal–Organic Frameworks via a Mixed-Linker Strategy for Ethylene/Ethane Kinetic Separation Lyndon, Richelle; You, Wenqin; Ma, Yao Chemistry of Materials, Vol. 32, Issue 9 https://doi.org/10.1021/acs.chemmater.9b04177	journal	April 2020
Role of Electrostatic Effects in the Pure Component and Binary Adsorption of Ethylene and Ethane in Cu-Tricarboxylate Metal-Organic Frameworks Nicholson, Timothy M.; Bhatia, Suresh K. Adsorption Science & Technology, Vol. 25, Issue 8 https://doi.org/10.1260/0263-6174.25.8.607	journal	October 2007
Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption Yoon, Ji Woong; Seo, You-Kyong; Hwang, Young Kyu Angewandte Chemie International Edition, Vol. 49, Issue 34 https://doi.org/10.1002/anie.201001230	journal	June 2010
A Robust Ethane-Trapping Metal–Organic Framework with a High Capacity for Ethylene Purification Qazvini, Omid T.; Babarao, Ravichandar; Shi, Zhao-Lin Journal of the American Chemical Society, Vol. 141, Issue 12 https://doi.org/10.1021/jacs.9b00913	journal	March 2019
Synthesis of zeolitic imidazolate framework-69 for adsorption separation of ethane and ethylene Yuan, Wenhui; Zhang, Xiaotao; Li, Li Journal of Solid State Chemistry, Vol. 251 https://doi.org/10.1016/j.jssc.2017.04.018	journal	July 2017
Adsorption of Ethane, Ethylene, Propane, and Propylene on a Magnesium-Based Metal–Organic Framework Bao, Zongbi; Alnemrat, Sufian; Yu, Liang Langmuir, Vol. 27, Issue 22 https://doi.org/10.1021/la2030473	journal	November 2011
Algae-derived N-doped porous carbons with ultrahigh specific surface area for highly selective separation of light hydrocarbons Zhang, Peixin; Wen, Xin; Wang, Liang Chemical Engineering Journal, Vol. 381 https://doi.org/10.1016/j.cej.2019.122731	journal	February 2020
Moisture stability of ethane‐selective Ni(II), Fe(III), Zr(IV)‐based metal–organic frameworks Lv, Daofei; Chen, Jiayu; Chen, Yongwei AIChE Journal, Vol. 65, Issue 8 https://doi.org/10.1002/aic.16616	journal	April 2019
Synthesis and modification of moisture-stable coordination pillared-layer metal-organic framework (CPL-MOF) CPL-2 for ethylene/ethane separation Xiang, Huan; Ameen, Ahmed; Shang, Jin Microporous and Mesoporous Materials, Vol. 293 https://doi.org/10.1016/j.micromeso.2019.109784	journal	February 2020
Efficient kinetic separation of propene and propane using two microporous metal organic frameworks Peng, Junjie; Wang, Hao; Olson, David H. Chemical Communications, Vol. 53, Issue 67 https://doi.org/10.1039/C7CC03529B	journal	January 2017
Kinetic separation of propylene over propane in a microporous metal-organic framework Li, Libo; Lin, Rui-Biao; Wang, Xiaoqing Chemical Engineering Journal, Vol. 354 https://doi.org/10.1016/j.cej.2018.08.108	journal	December 2018
M ₂ ( m -dobdc) (M = Mn, Fe, Co, Ni) Metal–Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations Bachman, Jonathan E.; Kapelewski, Matthew T.; Reed, Douglas A. Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b06397	journal	October 2017
Hydrocarbon Separations in Metal–Organic Frameworks Herm, Zoey R.; Bloch, Eric D.; Long, Jeffrey R. Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm402897c	journal	September 2013
Copper and nickel doped MIL-101: Highly efficient adsorbents for separation of ethylene-ethane mixture Bigdelou, Hossein; Khosravi-Nikou, Mohammad Reza; Shariati, Ahmad Chemical Engineering Research and Design, Vol. 159 https://doi.org/10.1016/j.cherd.2020.03.013	journal	July 2020
Efficient purification of ethene by an ethane-trapping metal-organic framework Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9697	journal	October 2015
An Ultramicroporous Metal–Organic Framework for High Sieving Separation of Propylene from Propane Liang, Bin; Zhang, Xin; Xie, Yi Journal of the American Chemical Society, Vol. 142, Issue 41 https://doi.org/10.1021/jacs.0c09466	journal	September 2020
Room-Temperature Synthesis of Pyr _1/3 @Cu–BTC with Enhanced Stability and Its Excellent Performance for Separation of Propylene/Propane Sun, Yiwei; Ke, Zhanfan; Tang, Yuning Industrial & Engineering Chemistry Research, Vol. 59, Issue 13 https://doi.org/10.1021/acs.iecr.0c00096	journal	March 2020
High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites Bae, Youn-Sang; Lee, Chang Yeon; Kim, Ki Chul Angewandte Chemie International Edition, Vol. 51, Issue 8, p. 1857-1860 https://doi.org/10.1002/anie.201107534	journal	January 2012
Adsorptive separation of C2H6/C2H4 on metal-organic frameworks (MOFs) with pillared-layer structures Xiang, Huan; Shao, Yan; Ameen, Ahmed Separation and Purification Technology, Vol. 242 https://doi.org/10.1016/j.seppur.2020.116819	journal	July 2020
A metal-organic framework-based splitter for separating propylene from propane Cadiau, A.; Adil, K.; Bhatt, P. M. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf6323	journal	July 2016
Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion Wang, Hao; Dong, Xinglong; Colombo, Valentina Advanced Materials, Vol. 30, Issue 49 https://doi.org/10.1002/adma.201805088	journal	October 2018
Molecular Sieving of Ethane from Ethylene through the Molecular Cross-Section Size Differentiation in Gallate-based Metal-Organic Frameworks Bao, Zongbi; Wang, Jiawei; Zhang, Zhiguo Angewandte Chemie International Edition, Vol. 57, Issue 49 https://doi.org/10.1002/anie.201808716	journal	November 2018
Separation of propylene and propane with a microporous metal–organic framework via equilibrium‐kinetic synergetic effect Ding, Qi; Zhang, Zhaoqiang; Yu, Cong AIChE Journal, Vol. 67, Issue 1 https://doi.org/10.1002/aic.17094	journal	October 2020
Enhancement of Ethane Selectivity in Ethane–Ethylene Mixtures by Perfluoro Groups in Zr-Based Metal-Organic Frameworks Pires, João; Fernandes, Joana; Dedecker, Kevin ACS Applied Materials & Interfaces, Vol. 11, Issue 30 https://doi.org/10.1021/acsami.9b07115	journal	July 2019
Facile loading of Cu(I) in MIL-100(Fe) through redox-active Fe(II) sites and remarkable propylene/propane separation performance Kim, Ah-Reum; Yoon, Tae-Ung; Kim, Eun-Jung Chemical Engineering Journal, Vol. 331 https://doi.org/10.1016/j.cej.2017.09.016	journal	January 2018
Introduction of π-Complexation into Porous Aromatic Framework for Highly Selective Adsorption of Ethylene over Ethane Li, Baiyan; Zhang, Yiming; Krishna, Rajamani Journal of the American Chemical Society, Vol. 136, Issue 24 https://doi.org/10.1021/ja502119z	journal	June 2014
Designer Metal–Organic Frameworks for Size‐Exclusion‐Based Hydrocarbon Separations: Progress and Challenges Wang, Hao; Liu, Yunling; Li, Jing Advanced Materials, Vol. 32, Issue 44 https://doi.org/10.1002/adma.202002603	journal	July 2020
Dealuminated Cs-ZK-5 zeolite for propylene/propane separation Gi Min, Jung; Christian Kemp, K.; Kencana, Kevin S. Chemical Engineering Journal, Vol. 413 https://doi.org/10.1016/j.cej.2020.127422	journal	June 2021
Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites Li, Libo; Lin, Rui-Biao; Krishna, Rajamani Science, Vol. 362, Issue 6413 https://doi.org/10.1126/science.aat0586	journal	October 2018
Propane-selective design of zirconium-based MOFs for propylene purification Wang, Sa; Zhang, Yufan; Tang, Yuning Chemical Engineering Science, Vol. 219 https://doi.org/10.1016/j.ces.2020.115604	journal	June 2020
Design and control of gas diffusion process in a nanoporous soft crystal Gu, Cheng; Hosono, Nobuhiko; Zheng, Jia-Jia Science, Vol. 363, Issue 6425 https://doi.org/10.1126/science.aar6833	journal	January 2019
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites Bloch, E. D.; Queen, W. L.; Krishna, R. Science, Vol. 335, Issue 6076, p. 1606-1610 https://doi.org/10.1126/science.1217544	journal	March 2012
Pore-Space-Partition-Enabled Exceptional Ethane Uptake and Ethane-Selective Ethane–Ethylene Separation Yang, Huajun; Wang, Yanxiang; Krishna, Rajamani Journal of the American Chemical Society, Vol. 142, Issue 5 https://doi.org/10.1021/jacs.9b12924	journal	January 2020
Ethane Selective IRMOF-8 and Its Significance in Ethane–Ethylene Separation by Adsorption Pires, João; Pinto, Moisés L.; Saini, Vipin K. ACS Applied Materials & Interfaces, Vol. 6, Issue 15 https://doi.org/10.1021/am502686g	journal	July 2014
Isoreticular Three-Dimensional Kagome Metal–Organic Frameworks with Open-Nitrogen-Donor Pillars for Selective Gas Adsorption Dinh, Andy; Yang, Huajun; Peng, Fang Crystal Growth & Design, Vol. 20, Issue 5 https://doi.org/10.1021/acs.cgd.0c00352	journal	April 2020
Adsorption of propane, propylene and isobutane on a metal–organic framework: Molecular simulation and experiment Lamia, Nabil; Jorge, Miguel; Granato, Miguel A. Chemical Engineering Science, Vol. 64, Issue 14, p. 3246-3259 https://doi.org/10.1016/j.ces.2009.04.010	journal	July 2009
Observation of Olefin/Paraffin Selectivity in Azo Compound and Its Application into a Metal–Organic Framework Kim, Seo-Yul; Yoon, Tae-Ung; Kang, Jo Hong ACS Applied Materials & Interfaces, Vol. 10, Issue 32 https://doi.org/10.1021/acsami.8b09739	journal	July 2018
Highly Adsorptive Separation of Ethane/Ethylene by An Ethane-Selective MOF MIL-142A Chen, Yongwei; Wu, Houxiao; Lv, Daofei Industrial & Engineering Chemistry Research, Vol. 57, Issue 11 https://doi.org/10.1021/acs.iecr.7b05260	journal	March 2018
An indium-based ethane-trapping MOF for efficient selective separation of C2H6/C2H4 mixture Wu, Houxiao; Chen, Yongwei; Lv, Daofei Separation and Purification Technology, Vol. 212 https://doi.org/10.1016/j.seppur.2018.11.005	journal	April 2019
A calcium-based microporous metal-organic framework for efficient adsorption separation of light hydrocarbons Li, Liangying; Guo, Lidong; Pu, Siyu Chemical Engineering Journal, Vol. 358 https://doi.org/10.1016/j.cej.2018.10.034	journal	February 2019
Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene Bereciartua, Pablo J.; Cantín, Ángel; Corma, Avelino Science, Vol. 358, Issue 6366 https://doi.org/10.1126/science.aao0092	journal	November 2017
A silver(i) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity Yu, Chao; Cowan, Matthew G.; Noble, Richard D. Chemical Communications, Vol. 50, Issue 43 https://doi.org/10.1039/c4cc02143f	journal	January 2014
Alkaline-earth squarates III.CaC4O4 · 2.5H2O, a novel polymer complex with zeolitic properties (1) Robl, Christian; Weiss, Armin Materials Research Bulletin, Vol. 22, Issue 3 https://doi.org/10.1016/0025-5408(87)90055-9	journal	March 1987
A Rod‐Packing Hydrogen‐Bonded Organic Framework with Suitable Pore Confinement for Benchmark Ethane/Ethylene Separation Zhang, Xu; Wang, Jia‐Xin; Li, Libo Angewandte Chemie International Edition, Vol. 60, Issue 18 https://doi.org/10.1002/anie.202100342	journal	March 2021
Selective adsorption of ethylene over ethane and propylene over propane in the metal–organic frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn) Geier, Stephen J.; Mason, Jarad A.; Bloch, Eric D. Chemical Science, Vol. 4, Issue 5 https://doi.org/10.1039/c3sc00032j	journal	January 2013
Microporous metal-organic framework with specific functional sites for efficient removal of ethane from ethane/ethylene mixtures Yang, Ling; Wang, Yong; Chen, Yang Chemical Engineering Journal, Vol. 387 https://doi.org/10.1016/j.cej.2020.124137	journal	May 2020
Separation of ethane and ethylene by a robust ethane-selective calcium-based metal–organic framework Lin, Yuhan; Li, Yuzhe; Wang, Hao New Journal of Chemistry, Vol. 44, Issue 28 https://doi.org/10.1039/D0NJ02655G	journal	January 2020
Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal–Organic Framework Adsorbents CPO-27 and ZIF-8 Böhme, Ulrike; Barth, Benjamin; Paula, Carolin Langmuir, Vol. 29, Issue 27 https://doi.org/10.1021/la401471g	journal	June 2013
Microporous Metal–Organic Framework with a Completely Reversed Adsorption Relationship for C ₂ Hydrocarbons at Room Temperature Sun, Fang-Zhou; Yang, Shan-Qing; Krishna, Rajamani ACS Applied Materials & Interfaces, Vol. 12, Issue 5 https://doi.org/10.1021/acsami.9b22410	journal	January 2020
Electrostatically Mediated Specific Adsorption of Small Molecules in Metallo-Organic Frameworks Nicholson, Timothy M.; Bhatia, Suresh K. The Journal of Physical Chemistry B, Vol. 110, Issue 49 https://doi.org/10.1021/jp065102b	journal	December 2006
Ethylene/ethane separation in a stable hydrogen-bonded organic framework through a gating mechanism Yang, Yisi; Li, Libo; Lin, Rui-Biao Nature Chemistry https://doi.org/10.1038/s41557-021-00740-z	journal	July 2021
Selective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework Zhang, Xu; Li, Libo; Wang, Jia-Xin Journal of the American Chemical Society, Vol. 142, Issue 1 https://doi.org/10.1021/jacs.9b12428	journal	December 2019
Selective adsorption of olefin–paraffin on diamond-like frameworks: diamondyne and PAF-302 Huang, Ling; Cao, Dapeng Journal of Materials Chemistry A, Vol. 1, Issue 33 https://doi.org/10.1039/c3ta11205e	journal	January 2013
Molecular sieving of ethylene from ethane using a rigid metal–organic framework Lin, Rui-Biao; Li, Libo; Zhou, Hao-Long Nature Materials, Vol. 17, Issue 12 https://doi.org/10.1038/s41563-018-0206-2	journal	November 2018
Ethane selective adsorbent Ni(bdc)(ted)0.5 with high uptake and its significance in adsorption separation of ethane and ethylene Liang, Wanwen; Xu, Feng; Zhou, Xin Chemical Engineering Science, Vol. 148 https://doi.org/10.1016/j.ces.2016.04.016	journal	July 2016
Modification of the pore environment in UiO-type metal-organic framework toward boosting the separation of propane/propylene He, Chaohui; Wang, Yong; Chen, Yang Chemical Engineering Journal, Vol. 403 https://doi.org/10.1016/j.cej.2020.126428	journal	January 2021
Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship Adil, Karim; Belmabkhout, Youssef; Pillai, Renjith S. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00153C	journal	January 2017
Comparing SiCHA and 4A Zeolite for Propylene/Propane Separation using a Surrogate-Based Simulation/Optimization Approach Khalighi, Mona; Karimi, I. A.; Farooq, S. Industrial & Engineering Chemistry Research, Vol. 53, Issue 44 https://doi.org/10.1021/ie404392j	journal	August 2014
Potential of microporous metal–organic frameworks for separation of hydrocarbon mixtures Bao, Zongbi; Chang, Ganggang; Xing, Huabin Energy & Environmental Science, Vol. 9, Issue 12 https://doi.org/10.1039/C6EE01886F	journal	January 2016
Adsorptive Separation of Olefin/Paraffin Mixtures with ZIF-4 Hartmann, Martin; Böhme, Ulrike; Hovestadt, Maximilian Langmuir, Vol. 31, Issue 45 https://doi.org/10.1021/acs.langmuir.5b02907	journal	November 2015
Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal−Organic Framework ZIF-7 through a Gate-Opening Mechanism Gücüyener, Canan; van den Bergh, Johan; Gascon, Jorge Journal of the American Chemical Society, Vol. 132, Issue 50 https://doi.org/10.1021/ja1089765	journal	December 2010
Effect of Ligand Functionalization on the Separation of Small Hydrocarbons and CO ₂ by a Series of MUF-15 Analogues Qazvini, Omid T.; Macreadie, Lauren K.; Telfer, Shane G. Chemistry of Materials, Vol. 32, Issue 15 https://doi.org/10.1021/acs.chemmater.0c02402	journal	July 2020
Reversed ethane/ethylene adsorption in a metal–organic framework via introduction of oxygen Yang, Ling; Zhou, Wei; Li, Hao Chinese Journal of Chemical Engineering, Vol. 28, Issue 2 https://doi.org/10.1016/j.cjche.2019.09.005	journal	February 2020
Exploiting equilibrium-kinetic synergetic effect for separation of ethylene and ethane in a microporous metal-organic framework Ding, Qi; Zhang, Zhaoqiang; Yu, Cong Science Advances, Vol. 6, Issue 15 https://doi.org/10.1126/sciadv.aaz4322	journal	April 2020
An ethane-trapping MOF PCN-250 for highly selective adsorption of ethane over ethylene Chen, Yongwei; Qiao, Zhiwei; Wu, Houxiao Chemical Engineering Science, Vol. 175 https://doi.org/10.1016/j.ces.2017.09.032	journal	January 2018
Bimetallic ions regulate pore size and chemistry of zeolites for selective adsorption of ethylene from ethane Liu, Yuzong; Wu, Ying; Liang, Wanwen Chemical Engineering Science, Vol. 220 https://doi.org/10.1016/j.ces.2020.115636	journal	July 2020
Selective adsorption of ethane over ethylene on M(bdc)(ted)0.5 (M = Co, Cu, Ni, Zn) metal-organic frameworks (MOFs) Xiang, Huan; Ameen, Ahmed; Gorgojo, Patricia Microporous and Mesoporous Materials, Vol. 292 https://doi.org/10.1016/j.micromeso.2019.109724	journal	January 2020
Supramolecular binding and separation of hydrocarbons within a functionalized porous metal–organic framework Yang, Sihai; Ramirez-Cuesta, Anibal J.; Newby, Ruth Nature Chemistry, Vol. 7, Issue 2 https://doi.org/10.1038/nchem.2114	journal	December 2014
Cage-Interconnected Metal–Organic Framework with Tailored Apertures for Efficient C ₂ H ₆ /C ₂ H ₄ Separation under Humid Conditions Zeng, Heng; Xie, Xiao-Jing; Xie, Mo Journal of the American Chemical Society, Vol. 141, Issue 51 https://doi.org/10.1021/jacs.9b10923	journal	November 2019
A pillar-layer metal-organic framework for efficient adsorption separation of propylene over propane Chen, Yongwei; Wu, Houxiao; Lv, Daofei Separation and Purification Technology, Vol. 204 https://doi.org/10.1016/j.seppur.2018.04.046	journal	October 2018
Effect of framework rigidity in metal-organic frameworks for adsorptive separation of ethane/ethylene Cho, Kyung Ho; Yoon, Ji Woong; Lee, Jeong Hyeon Microporous and Mesoporous Materials, Vol. 307 https://doi.org/10.1016/j.micromeso.2020.110473	journal	November 2020
Silver-Decorated Hafnium Metal–Organic Framework for Ethylene/Ethane Separation Wang, Yuxiang; Hu, Zhigang; Cheng, Youdong Industrial & Engineering Chemistry Research, Vol. 56, Issue 15 https://doi.org/10.1021/acs.iecr.7b00517	journal	April 2017
Synergistic sorbent separation for one-step ethylene purification from a four-component mixture Chen, Kai-Jie; Madden, David G.; Mukherjee, Soumya Science, Vol. 366, Issue 6462 https://doi.org/10.1126/science.aax8666	journal	October 2019
Immobilization of Ag( i ) into a metal–organic framework with –SO ₃ H sites for highly selective olefin–paraffin separation at room temperature Chang, Ganggang; Huang, Minhui; Su, Ye Chemical Communications, Vol. 51, Issue 14 https://doi.org/10.1039/C4CC09679G	journal	January 2015
Confinement of Ag(I) Sites within MIL-101 for Robust Ethylene/Ethane Separation Yin, Yu; Zhang, Zhuangzhuang; Xu, Chunli ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 2 https://doi.org/10.1021/acssuschemeng.9b04901	journal	November 2019

Similar Records

Metal–Organic Frameworks for C6 Alkane Separation

Journal Article · Thu Feb 16 00:00:00 EST 2023 · Angewandte Chemie (International Edition) · OSTI ID:1863574

Xie, Feng; Yu, Liang; Wang, Hao; +1 more

Metal‐Organic Frameworks for C6 Alkane Separation

Journal Article · Mon Mar 06 00:00:00 EST 2023 · Angewandte Chemie · OSTI ID:1863574

Xie, Feng; Yu, Liang; Wang, Hao; +1 more

Microporous metal–organic frameworks for the purification of propylene

Journal Article · Thu Jan 05 00:00:00 EST 2023 · Journal of Materials Chemistry. A · OSTI ID:1863574

Xie, Feng; Wang, Hao; Li, Jing

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Separation of alkane and alkene mixtures by metal–organic frameworks

Citation Formats

References (100)

Similar Records

Related Subjects