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U.S. Department of Energy
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Decontamination of actinides and fission products from stainless steel surfaces

Conference ·
OSTI ID:230280
; ; ; ;  [1]; ; ; ;  [2]
  1. Argonne National Lab., IL (United States)
  2. Illinois Univ., Urbana, IL (United States). Dept. of Nuclear Engineering

Seven in situ decontamination processes were evaluated as possible candidates to reduce radioactivity levels in nuclear facilities throughout the DOE complex. These processes were tested using stainless steel coupons (Type 304) contaminated with actinides (Pu and Am) or fission products (a mixture of Cs, Sr, and Gd). The seven processes were decontamination with nitric acid, nitric acid plus hydrofluoric acid, fluoboric acid, silver(II) persulfate, hydrogen peroxide plus oxalic acid plus hydrofluoric acid, alkaline persulfate followed by citric acid plus oxalic acid, and electropolishing using nitric acid electrolyte. Of the seven processes, the nitric acid plus hydrofluoric acid and fluoboric acid solutions gave the best results; the decontamination factors for 3- to 6-h contacts at 80{degree}C were as high as 600 for plutonium, 5500 for americium, 700 for cesium, 15000 for strontium, and 1100 for gadolinium.

Research Organization:
Argonne National Lab., IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
230280
Report Number(s):
ANL/CMT/CP--87865; CONF-960443--5; ON: DE96008402
Country of Publication:
United States
Language:
English