Comparing Ammonium and Tetraaminophosphonium Anion-Exchange Membranes Derived from Vinyl-Addition Polynorbornene Copolymers

Gaitor, Jamie C.; Yang-Neyerlin, Ami C.; Markovich, Danielle; Fors, Brett P.; Coates, Geoffrey W.; Kourkoutis, Lena F.; Pivovar, Bryan S.; Kowalewski, Tomasz; Noonan, Kevin J. T.

doi:10.1021/acsaem.3c02822

Comparing Ammonium and Tetraaminophosphonium Anion-Exchange Membranes Derived from Vinyl-Addition Polynorbornene Copolymers

Journal Article · Tue Feb 13 00:00:00 EST 2024 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.3c02822· OSTI ID:2301753

Gaitor, Jamie C. ^[1]; Yang-Neyerlin, Ami C. ^[2]; Markovich, Danielle ^[3]; ^[4]; ^[4]; ^[3]; Pivovar, Bryan S. ^[2]; ^[1]; ^[1]

Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, Pennsylvania 15213, United States
Chemistry and Nanoscience Center, National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, Colorado 80401, United States
School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, United States
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, United States

Not Available

View Journal Article

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC36-08GO28308; SC0019445

OSTI ID:: 2301753

Alternate ID(s):: OSTI ID: 2324799

Report Number(s):: NREL/JA--5900-86720

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 4 Vol. 7; ISSN 2574-0962

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (48)

Phenyl‐Free Polynorbornenes for Potential Anion Exchange Ionomers for Fuel Cells and Electrolyzers Leonard, Daniel P.; Lehmann, Michelle; Klein, Jeffrey M. Advanced Energy Materials https://doi.org/10.1002/aenm.202203488	journal	December 2022
Direct Insertion Polymerization of Ionic Monomers: Rapid Production of Anion Exchange Membranes Hsu, Jesse H.; Peltier, Cheyenne R.; Treichel, Megan Angewandte Chemie International Edition, Vol. 62, Issue 30 https://doi.org/10.1002/anie.202304778	journal	June 2023
Extremely Base-Resistant Organic Phosphazenium Cations Schwesinger, Reinhard; Link, Reinhard; Wenzl, Peter Chemistry - A European Journal, Vol. 12, Issue 2 https://doi.org/10.1002/chem.200500837	journal	January 2006
Synthesis and Rheological Properties of Poly(5-n-hexylnorbornene) Müller, Kerstin; Kreiling, Stefan; Dehnicke, Kurt Macromolecular Chemistry and Physics, Vol. 207, Issue 2 https://doi.org/10.1002/macp.200500228	journal	January 2006
Endo/Exo Reactivity Ratios in Living Vinyl Addition Polymerization of Substituted Norbornenes Tsai, Steven D.; Register, Richard A. Macromolecular Chemistry and Physics, Vol. 219, Issue 11 https://doi.org/10.1002/macp.201800059	journal	April 2018
Metal catalysts for the vinyl/addition polymerization of norbornene Blank, Frederik; Janiak, Christoph Coordination Chemistry Reviews, Vol. 253, Issue 7-8 https://doi.org/10.1016/j.ccr.2008.05.010	journal	April 2009
Understanding how high-performance anion exchange membrane fuel cells were achieved: Component, interfacial, and cell-level factors Mustain, William E. Current Opinion in Electrochemistry, Vol. 12 https://doi.org/10.1016/j.coelec.2018.11.010	journal	December 2018
Water limiting current measurements in anion exchange membrane fuel cells (AEMFCs); part 1: Water limiting current method development He, Cheng; Yang-Neyerlin, Ami C.; Pivovar, Bryan Journal of Power Sources, Vol. 539 https://doi.org/10.1016/j.jpowsour.2022.231534	journal	August 2022
Anionic multiblock copolymer membrane based on vinyl addition polymerization of norbornenes: Applications in anion-exchange membrane fuel cells Mandal, Mrinmay; Huang, Garrett; Kohl, Paul A. Journal of Membrane Science, Vol. 570-571 https://doi.org/10.1016/j.memsci.2018.10.041	journal	January 2019
Dithiol cross-linked polynorbornene-based anion-exchange membranes with high hydroxide conductivity and alkaline stability Wang, Ting; Wang, Yu; You, Wei Journal of Membrane Science, Vol. 685 https://doi.org/10.1016/j.memsci.2023.121916	journal	November 2023
High Tg sulfonated insertion polynorbornene ionomers prepared by catalytic insertion polymerization Pierre, Florian; Commarieu, Basile; Tavares, Ana C. Polymer, Vol. 86 https://doi.org/10.1016/j.polymer.2016.01.047	journal	March 2016
Addition polymerization of functionalized norbornenes as a powerful tool for assembling molecular moieties of new polymers with versatile properties Bermeshev, M. V.; Chapala, P. P. Progress in Polymer Science, Vol. 84 https://doi.org/10.1016/j.progpolymsci.2018.06.003	journal	September 2018
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies Yang, Yao; Peltier, Cheyenne R.; Zeng, Rui Chemical Reviews, Vol. 122, Issue 6 https://doi.org/10.1021/acs.chemrev.1c00331	journal	February 2022
Degradation of Organic Cations under Alkaline Conditions You, Wei; Hugar, Kristina M.; Selhorst, Ryan C. The Journal of Organic Chemistry, Vol. 86, Issue 1 https://doi.org/10.1021/acs.joc.0c02051	journal	November 2020
Exploring the Effects of Bulky Cations Tethered to Semicrystalline Polymers: The Case of Tetraaminophosphoniums with Ring-Opened Polynorbornenes Treichel, Megan; Tyler Womble, C.; Selhorst, Ryan Macromolecules, Vol. 53, Issue 19 https://doi.org/10.1021/acs.macromol.0c00422	journal	September 2020
Rapid Analysis of Tetrakis(dialkylamino)phosphonium Stability in Alkaline Media Womble, C. Tyler; Kang, Jamie; Hugar, Kristina M. Organometallics, Vol. 36, Issue 20 https://doi.org/10.1021/acs.organomet.7b00663	journal	October 2017
Multiblock Copolymer Anion-Exchange Membranes Derived from Vinyl Addition Polynorbornenes Selhorst, Ryan; Gaitor, Jamie; Lee, Minjung ACS Applied Energy Materials, Vol. 4, Issue 9 https://doi.org/10.1021/acsaem.1c02094	journal	September 2021
Quaternized Polynorbornene Random Copolymers for Fuel Cell Devices Lehmann, Michelle; Leonard, Daniel; Zheng, Jackie ACS Applied Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1021/acsaem.2c03682	journal	January 2023
Anion Exchange Membranes’ Evolution toward High Hydroxide Ion Conductivity and Alkaline Resiliency Arges, Christopher G.; Zhang, Le ACS Applied Energy Materials, Vol. 1, Issue 7 https://doi.org/10.1021/acsaem.8b00387	journal	June 2018
Highly Conductive Anion-Exchange Membranes Based on Cross-Linked Poly(norbornene): Vinyl Addition Polymerization Mandal, Mrinmay; Huang, Garrett; Kohl, Paul A. ACS Applied Energy Materials, Vol. 2, Issue 4 https://doi.org/10.1021/acsaem.8b02051	journal	March 2019
Suppressing Water Uptake and Increasing Hydroxide Conductivity in Ring-Opened Polynorbornene Ion-Exchange Materials via Backbone Design Gaitor, Jamie C.; Treichel, Megan; Kowalewski, Tomasz ACS Applied Polymer Materials, Vol. 4, Issue 11 https://doi.org/10.1021/acsapm.2c00297	journal	October 2022
Living Vinyl Addition Polymerization of Substituted Norbornenes by a t -Bu ₃ P-Ligated Methylpalladium Complex Kim, Dong-Gyun; Bell, Andrew; Register, Richard A. ACS Macro Letters, Vol. 4, Issue 3 https://doi.org/10.1021/acsmacrolett.5b00079	journal	February 2015
Accessing Siloxane Functionalized Polynorbornenes via Vinyl-Addition Polymerization for CO ₂ Separation Membranes Gmernicki, Kevin R.; Hong, Eunice; Maroon, Christopher R. ACS Macro Letters, Vol. 5, Issue 7 https://doi.org/10.1021/acsmacrolett.6b00435	journal	June 2016
Phosphonium-Functionalized Polyethylene: A New Class of Base-Stable Alkaline Anion Exchange Membranes Noonan, Kevin J. T.; Hugar, Kristina M.; Kostalik, Henry A. Journal of the American Chemical Society, Vol. 134, Issue 44 https://doi.org/10.1021/ja307466s	journal	October 2012
Addition polymerization of norbornene catalyzed by palladium(2+) compounds. A polymerization reaction with rare chain transfer and chain termination Mehler, Christof; Risse, Wilhelm Macromolecules, Vol. 25, Issue 16 https://doi.org/10.1021/ma00042a030	journal	August 1992
Addition Polymerization of Norbornene-Type Monomers. High Activity Cationic Allyl Palladium Catalysts Lipian, John; Mimna, Richard A.; Fondran, John C. Macromolecules, Vol. 35, Issue 24 https://doi.org/10.1021/ma0209287	journal	November 2002
Versatile Route to Functionalized Vinylic Addition Polynorbornenes Martínez-Arranz, Sheila; Albéniz, Ana C.; Espinet, Pablo Macromolecules, Vol. 43, Issue 18 https://doi.org/10.1021/ma101137z	journal	September 2010
Novel, Efficient, Palladium-Based System for the Polymerization of Norbornene Derivatives: Scope and Mechanism Hennis, April D.; Polley, Jennifer D.; Long, Gregory S. Organometallics, Vol. 20, Issue 13 https://doi.org/10.1021/om010232m	journal	May 2001
Addition Polymerization of Functionalized Norbornenes: The Effect of Size, Stereochemistry, and Coordinating Ability of the Substituent Funk, Jeffrey K.; Andes, Cecily E.; Sen, Ayusman Organometallics, Vol. 23, Issue 8 https://doi.org/10.1021/om049943l	journal	March 2004
Syntheses and Structures of Bulky Monophosphine-Ligated Methylpalladium Complexes: Application to Homo- and Copolymerization of Norbornene and/or Methoxycarbonylnorbornene Yamashita, Makoto; Takamiya, Ikuko; Jin, Koichiro Organometallics, Vol. 25, Issue 19 https://doi.org/10.1021/om060347w	journal	September 2006
Anion-exchange membranes in electrochemical energy systems Varcoe, John R.; Atanassov, Plamen; Dekel, Dario R. Energy & Environmental Science, Vol. 7, Issue 10, p. 3135-3191 https://doi.org/10.1039/C4EE01303D	journal	January 2014
Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs Omasta, Travis J.; Park, Andrew M.; LaManna, Jacob M. Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/C8EE00122G	journal	January 2018
Enhanced water transport in AEMs based on poly(styrene–ethylene–butylene–styrene) triblock copolymer for high fuel cell performance Gao, Xueqiang; Yu, Hongmei; Qin, Bowen Polymer Chemistry, Vol. 10, Issue 15 https://doi.org/10.1039/C8PY01618F	journal	January 2019
Poly(norbornene) anion conductive membranes: homopolymer, block copolymer and random copolymer properties and performance Mandal, Mrinmay; Huang, Garrett; Hassan, Noor Ul Journal of Materials Chemistry A, Vol. 8, Issue 34 https://doi.org/10.1039/D0TA04756B	journal	January 2020
Asymmetric electrode ionomer for low relative humidity operation of anion exchange membrane fuel cells Leonard, Daniel P.; Maurya, Sandip; Park, Eun Joo Journal of Materials Chemistry A https://doi.org/10.1039/D0TA05807F	journal	January 2020
Substituted polynorbornene membranes: a modular template for targeted gas separations Wang, Xinyi; Wilson, Trevor J.; Alentiev, Dmitry Polymer Chemistry, Vol. 12, Issue 20 https://doi.org/10.1039/D1PY00278C	journal	January 2021
Oxidative instability of ionomers in hydroxide-exchange-membrane water electrolyzers Lindquist, Grace A.; Gaitor, Jamie C.; Thompson, Willow L. Energy & Environmental Science, Vol. 16, Issue 10 https://doi.org/10.1039/D3EE01293J	journal	January 2023
Alkaline polymer electrolyte membranes for fuel cell applications Wang, Yan-Jie; Qiao, Jinli; Baker, Ryan Chemical Society Reviews, Vol. 42, Issue 13 https://doi.org/10.1039/c3cs60053j	journal	January 2013
Characterizing polymer structure with small-angle neutron scattering: A Tutorial Wei, Yuan; Hore, Michael J. A. Journal of Applied Physics, Vol. 129, Issue 17 https://doi.org/10.1063/5.0045841	journal	May 2021
Substituted polynorbornenes as promising materials for gas separation membranes Finkelshtein, Evgenii Sh; Bermeshev, Maksim V.; Gringolts, Mariya L. Russian Chemical Reviews, Vol. 80, Issue 4 https://doi.org/10.1070/RC2011v080n04ABEH004203	journal	April 2011
Revealing the Internal Architecture of Alkaline Fuel Cell Membranes with Cryo-4D-STEM and Cryo-STEM-EELS Markovich, Danielle; Colletta, Michael; Yu, Yue Microscopy and Microanalysis, Vol. 29, Issue Supplement_1 https://doi.org/10.1093/micmic/ozad067.652	journal	July 2023
Synthesis and Characterization of Perfluorinated Anion Exchange Membranes Park, Andrew Michael; Owczarczyk, Zbyslaw R.; Garner, L. E. ECS Transactions, Vol. 80, Issue 8 https://doi.org/10.1149/08008.0957ecst	journal	August 2017
Ionomer Optimization for Water Uptake and Swelling in Anion Exchange Membrane Electrolyzer: Oxygen Evolution Electrode Huang, Garrett; Mandal, Mrinmay; Hassan, Noor Ul Journal of The Electrochemical Society, Vol. 167, Issue 16 https://doi.org/10.1149/1945-7111/abcde3	journal	December 2020
Ionomer Optimization for Water Uptake and Swelling in Anion Exchange Membrane Electrolyzer: Hydrogen Evolution Electrode Huang, Garrett; Mandal, Mrinmay; Hassan, Noor Ul Journal of The Electrochemical Society, Vol. 168, Issue 2 https://doi.org/10.1149/1945-7111/abde7b	journal	February 2021
Editors’ Choice—Examining Performance and Durability of Anion Exchange Membrane Fuel Cells with Novel Spirocyclic Anion Exchange Membranes Yang-Neyerlin, Ami C.; Medina, Samantha; Meek, Kelly M. Journal of The Electrochemical Society, Vol. 168, Issue 4 https://doi.org/10.1149/1945-7111/abf77f	journal	April 2021
Composite Poly(norbornene) Anion Conducting Membranes for Achieving Durability, Water Management and High Power (3.4 W/cm ² ) in Hydrogen/Oxygen Alkaline Fuel Cells Huang, Garrett; Mandal, Mrinmay; Peng, Xiong Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.1301910jes	journal	January 2019
Investigating the Impact of the Ionomer on Alkaline Membrane Fuel Cell (AEMFC) Electrode Performance He, Cheng; Yang-Neyerlin, Ami C.; Pivovar, Bryan S. ECS Meeting Abstracts, Vol. MA2021-02, Issue 36 https://doi.org/10.1149/MA2021-02361055mtgabs	journal	October 2021
Vinyl-Addition Homopolymeization of Norbornenes with Bromoalkyl Groups Lunin, Artyom O.; Andreyanov, Fedor A.; Makarov, Igor S. Polymers, Vol. 15, Issue 22 https://doi.org/10.3390/polym15224444	journal	November 2023

Similar Records

Multiblock Copolymer Anion-Exchange Membranes Derived from Vinyl Addition Polynorbornenes

Journal Article · Thu Sep 02 20:00:00 EDT 2021 · ACS Applied Energy Materials · OSTI ID:1857348

Multiblock Copolymer Anion-Exchange Membranes Derived from Vinyl Addition Polynorbornenes

Journal Article · Fri Sep 03 00:00:00 EDT 2021 · ACS Applied Energy Materials · OSTI ID:1852124

Related Subjects

30 DIRECT ENERGY CONVERSION
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ammonium polymers
anion exchange membranes
fuel cell
statistical copolymers
tetraaminophosphonium polymers
vinyl addition polynorbornenes

Comparing Ammonium and Tetraaminophosphonium Anion-Exchange Membranes Derived from Vinyl-Addition Polynorbornene Copolymers

Citation Formats

References (48)

Similar Records

Related Subjects