Multiblock Copolymer Anion-Exchange Membranes Derived from Vinyl Addition Polynorbornenes

Selhorst, Ryan; Gaitor, Jamie; Lee, Minjung; Markovich, Danielle; Yu, Yue; Treichel, Megan; Olavarria Gallegos, Che; Kowalewski, Tomasz; Kourkoutis, Lena F.; Hayward, Ryan C.; Noonan, Kevin J.  T.

doi:10.1021/acsaem.1c02094

Multiblock Copolymer Anion-Exchange Membranes Derived from Vinyl Addition Polynorbornenes

Journal Article · Fri Sep 03 04:00:00 EDT 2021 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.1c02094· OSTI ID:1852124

Selhorst, Ryan ^[1]; Gaitor, Jamie ^[2]; Lee, Minjung ^[3]; Markovich, Danielle ^[4]; Yu, Yue ^[4]; Treichel, Megan ^[2]; Olavarria Gallegos, Che ^[2]; ^[2]; ^[5]; ^[6]; ^[2]

Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States; OSTI
Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States
Department of Polymer Science & Engineering, University of Massachusetts Amherst, Amherst Massachusetts 01003, United States
School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, United States
School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, United States; Kavli Institute at Cornell for Nanoscale Science, Cornell University, Ithaca, New York 14853, United States
Department of Polymer Science & Engineering, University of Massachusetts Amherst, Amherst Massachusetts 01003, United States; Department of Chemical and Biological Engineering, University of Colorado Boulder, 3415 Colorado Ave., Boulder, Colorado 80303, United States

Not provided.

Research Organization:: Univ. of Massachusetts, Amherst, MA (United States); Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0016208; SC0019445

OSTI ID:: 1852124

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 9 Vol. 4; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (41)

Anion conducting multiblock poly(arylene ether sulfone)s containing hydrophilic segments densely functionalized with quaternary ammonium groups Weiber, Eva Annika; Meis, David; Jannasch, Patric Polymer Chemistry, Vol. 6, Issue 11 https://doi.org/10.1039/C4PY01588F	journal	January 2015
Syntheses and Structures of Bulky Monophosphine-Ligated Methylpalladium Complexes: Application to Homo- and Copolymerization of Norbornene and/or Methoxycarbonylnorbornene Yamashita, Makoto; Takamiya, Ikuko; Jin, Koichiro Organometallics, Vol. 25, Issue 19 https://doi.org/10.1021/om060347w	journal	September 2006
Polyethylene-Based Block Copolymers for Anion Exchange Membranes Li, Yifan; Liu, Ye; Savage, Alice M. Macromolecules, Vol. 48, Issue 18 https://doi.org/10.1021/acs.macromol.5b01457	journal	September 2015
Ion Transport by Nanochannels in Ion-Containing Aromatic Copolymers Li, Nanwen; Guiver, Michael D. Macromolecules, Vol. 47, Issue 7 https://doi.org/10.1021/ma402254h	journal	February 2014
Exploring the Effects of Bulky Cations Tethered to Semicrystalline Polymers: The Case of Tetraaminophosphoniums with Ring-Opened Polynorbornenes Treichel, Megan; Tyler Womble, C.; Selhorst, Ryan Macromolecules, Vol. 53, Issue 19 https://doi.org/10.1021/acs.macromol.0c00422	journal	September 2020
Synthesis and Rheological Properties of Poly(5-n-hexylnorbornene) Müller, Kerstin; Kreiling, Stefan; Dehnicke, Kurt Macromolecular Chemistry and Physics, Vol. 207, Issue 2 https://doi.org/10.1002/macp.200500228	journal	January 2006
Degradation of Organic Cations under Alkaline Conditions You, Wei; Hugar, Kristina M.; Selhorst, Ryan C. The Journal of Organic Chemistry, Vol. 86, Issue 1 https://doi.org/10.1021/acs.joc.0c02051	journal	November 2020
Role of Defects in Ion Transport in Block Copolymer Electrolytes Kambe, Yu; Arges, Christopher G.; Czaplewski, David A. Nano Letters, Vol. 19, Issue 7 https://doi.org/10.1021/acs.nanolett.9b01758	journal	June 2019
Designing Advanced Alkaline Polymer Electrolytes for Fuel Cell Applications Pan, Jing; Chen, Chen; Zhuang, Lin Accounts of Chemical Research, Vol. 45, Issue 3 https://doi.org/10.1021/ar200201x	journal	October 2011
Protons and Hydroxide Ions in Aqueous Systems Agmon, Noam; Bakker, Huib J.; Campen, R. Kramer Chemical Reviews, Vol. 116, Issue 13 https://doi.org/10.1021/acs.chemrev.5b00736	journal	April 2016
Anionic multiblock copolymer membrane based on vinyl addition polymerization of norbornenes: Applications in anion-exchange membrane fuel cells Mandal, Mrinmay; Huang, Garrett; Kohl, Paul A. Journal of Membrane Science, Vol. 570-571 https://doi.org/10.1016/j.memsci.2018.10.041	journal	January 2019
Block Copolymers for Fuel Cells Elabd, Yossef A.; Hickner, Michael A. Macromolecules, Vol. 44, Issue 1 https://doi.org/10.1021/ma101247c	journal	January 2011
Anion Exchange Membranes’ Evolution toward High Hydroxide Ion Conductivity and Alkaline Resiliency Arges, Christopher G.; Zhang, Le ACS Applied Energy Materials, Vol. 1, Issue 7 https://doi.org/10.1021/acsaem.8b00387	journal	June 2018
Hydroxide diffuses slower than hydronium in water because its solvated structure inhibits correlated proton transfer Chen, Mohan; Zheng, Lixin; Santra, Biswajit Nature Chemistry, Vol. 10, Issue 4 https://doi.org/10.1038/s41557-018-0010-2	journal	March 2018
Interconnected ionic domains enhance conductivity in microphase separated block copolymer electrolytes Arges, Christopher G.; Kambe, Yu; Dolejsi, Moshe Journal of Materials Chemistry A, Vol. 5, Issue 11 https://doi.org/10.1039/C6TA10838E	journal	January 2017
Functionalized polynorbornene dielectric polymers: Adhesion and mechanical properties Grove, Nicole R.; Kohl, Paul A.; Bidstrup Allen, Sue Ann Journal of Polymer Science Part B: Polymer Physics, Vol. 37, Issue 21 https://doi.org/10.1002/(SICI)1099-0488(19991101)37:21<3003::AID-POLB10>3.0.CO;2-T	journal	November 1999
Efficient Preparation of Styrene Block Copolymer Anion Exchange Membranes via One-Step Friedel–Crafts Bromoalkylation with Alkenes Jeon, Jong Yeob; Tian, Ding; Pagels, Michael K. Organic Process Research & Development, Vol. 23, Issue 8 https://doi.org/10.1021/acs.oprd.9b00218	journal	July 2019
Addition polymerization of functionalized norbornenes as a powerful tool for assembling molecular moieties of new polymers with versatile properties Bermeshev, M. V.; Chapala, P. P. Progress in Polymer Science, Vol. 84 https://doi.org/10.1016/j.progpolymsci.2018.06.003	journal	September 2018
Anion-exchange membranes in electrochemical energy systems Varcoe, John R.; Atanassov, Plamen; Dekel, Dario R. Energy & Environmental Science, Vol. 7, Issue 10, p. 3135-3191 https://doi.org/10.1039/C4EE01303D	journal	January 2014
Achieving Continuous Anion Transport Domains Using Block Copolymers Containing Phosphonium Cations Zhang, Wenxu; Liu, Ye; Jackson, Aaron C. Macromolecules, Vol. 49, Issue 13 https://doi.org/10.1021/acs.macromol.6b00653	journal	June 2016
Ion transport properties of mechanically stable symmetric ABCBA pentablock copolymers with quaternary ammonium functionalized midblock Ertem, S. Piril; Caire, Benjamin R.; Tsai, Tsung-Han Journal of Polymer Science Part B: Polymer Physics, Vol. 55, Issue 7 https://doi.org/10.1002/polb.24310	journal	February 2017
Synthesis of Aromatic Anion Exchange Membranes by Friedel–Crafts Bromoalkylation and Cross-Linking of Polystyrene Block Copolymers Jeon, Jong Yeob; Park, Sungmin; Han, Junyoung Macromolecules, Vol. 52, Issue 5 https://doi.org/10.1021/acs.macromol.8b02355	journal	February 2019
Anion Conductive Block Poly(arylene ether)s: Synthesis, Properties, and Application in Alkaline Fuel Cells Tanaka, Manabu; Fukasawa, Keita; Nishino, Eriko Journal of the American Chemical Society, Vol. 133, Issue 27, p. 10646-10654 https://doi.org/10.1021/ja204166e	journal	July 2011
Alkaline-stable anion exchange membranes: A review of synthetic approaches You, Wei; Noonan, Kevin J. T.; Coates, Geoffrey W. Progress in Polymer Science, Vol. 100 https://doi.org/10.1016/j.progpolymsci.2019.101177	journal	January 2020
Addition Polymerization of Norbornene-Type Monomers. High Activity Cationic Allyl Palladium Catalysts Lipian, John; Mimna, Richard A.; Fondran, John C. Macromolecules, Vol. 35, Issue 24 https://doi.org/10.1021/ma0209287	journal	November 2002
Structure and Dynamics of OH ^- (aq) Tuckerman, Mark E.; Chandra, Amalendu; Marx, Dominik Accounts of Chemical Research, Vol. 39, Issue 2 https://doi.org/10.1021/ar040207n	journal	February 2006
Highly conductive and chemically stable alkaline anion exchange membranes via ROMP of trans -cyclooctene derivatives You, Wei; Padgett, Elliot; MacMillan, Samantha N. Proceedings of the National Academy of Sciences, Vol. 116, Issue 20 https://doi.org/10.1073/pnas.1900988116	journal	April 2019
Anion conducting multiblock copolymer membranes with partial fluorination and long head-group tethers Liu, Lisha; Ahlfield, John; Tricker, Andrew Journal of Materials Chemistry A, Vol. 4, Issue 41 https://doi.org/10.1039/C6TA06653D	journal	January 2016
Rapid Analysis of Tetrakis(dialkylamino)phosphonium Stability in Alkaline Media Womble, C. Tyler; Kang, Jamie; Hugar, Kristina M. Organometallics, Vol. 36, Issue 20 https://doi.org/10.1021/acs.organomet.7b00663	journal	October 2017
A Polyethylene-Based Triblock Copolymer Anion Exchange Membrane with High Conductivity and Practical Mechanical Properties Buggy, Nora C.; Du, Yifeng; Kuo, Mei-Chen ACS Applied Polymer Materials, Vol. 2, Issue 3 https://doi.org/10.1021/acsapm.9b01182	journal	February 2020
Anion Conductive Triblock Copolymer Membranes with Flexible Multication Side Chain Lin, Chen Xiao; Wu, Hong Yue; Li, Ling ACS Applied Materials & Interfaces, Vol. 10, Issue 21 https://doi.org/10.1021/acsami.8b03757	journal	May 2018
Stable Elastomeric Anion Exchange Membranes Based on Quaternary Ammonium-Tethered Polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene Triblock Copolymers Mohanty, Angela D.; Ryu, Chang Y.; Kim, Yu Seung Macromolecules, Vol. 48, Issue 19, p. 7085-7095 https://doi.org/10.1021/acs.macromol.5b01382	journal	September 2015
The nature and transport mechanism of hydrated hydroxide ions in aqueous solution Tuckerman, Mark E.; Marx, Dominik; Parrinello, Michele Nature, Vol. 417, Issue 6892 https://doi.org/10.1038/nature00797	journal	June 2002
Highly Conductive Anion-Exchange Membranes Based on Cross-Linked Poly(norbornene): Vinyl Addition Polymerization Mandal, Mrinmay; Huang, Garrett; Kohl, Paul A. ACS Applied Energy Materials, Vol. 2, Issue 4 https://doi.org/10.1021/acsaem.8b02051	journal	March 2019
Living Vinyl Addition Polymerization of Substituted Norbornenes by a t -Bu ₃ P-Ligated Methylpalladium Complex Kim, Dong-Gyun; Bell, Andrew; Register, Richard A. ACS Macro Letters, Vol. 4, Issue 3 https://doi.org/10.1021/acsmacrolett.5b00079	journal	February 2015
Alkaline polymer electrolyte membranes for fuel cell applications Wang, Yan-Jie; Qiao, Jinli; Baker, Ryan Chemical Society Reviews, Vol. 42, Issue 13 https://doi.org/10.1039/c3cs60053j	journal	January 2013
Strategies for Developing New Anion Exchange Membranes and Electrode Ionomers Hickner, Michael A. The Electrochemical Society Interface, Vol. 26, Issue 1 https://doi.org/10.1149/2.F08171if	journal	January 2017
Poly(norbornene) anion conductive membranes: homopolymer, block copolymer and random copolymer properties and performance Mandal, Mrinmay; Huang, Garrett; Hassan, Noor Ul Journal of Materials Chemistry A, Vol. 8, Issue 34 https://doi.org/10.1039/D0TA04756B	journal	January 2020
Synthesis of multi-block poly(arylene ether sulfone) copolymer membrane with pendant quaternary ammonium groups for alkaline fuel cell Zhao, Zhuo; Wang, Junhua; Li, Shenghai Journal of Power Sources, Vol. 196, Issue 10, p. 4445-4450 https://doi.org/10.1016/j.jpowsour.2011.01.081	journal	May 2011
Anion-Conductive Multiblock Aromatic Copolymer Membranes: Structure–Property Relationships Park, Doh-Yeon; Kohl, Paul A.; Beckham, Haskell W. The Journal of Physical Chemistry C, Vol. 117, Issue 30 https://doi.org/10.1021/jp311987v	journal	July 2013
Phosphonium-Functionalized Polyethylene: A New Class of Base-Stable Alkaline Anion Exchange Membranes Noonan, Kevin J. T.; Hugar, Kristina M.; Kostalik, Henry A. Journal of the American Chemical Society, Vol. 134, Issue 44 https://doi.org/10.1021/ja307466s	journal	October 2012

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