Synthesis and structure of ruthenium complexes [Ph{sub 3}PCH{sub 2}C{sub 6}H{sub 4}F-4]{sub 2}[RuCl{sub 6}] and [Ph{sub 3}PCH{sub 2}C{sub 6}H{sub 4}F-4][trans-RuCl{sub 4}(dmso-S){sub 2}]
Journal Article
·
· Russian Chemical Bulletin
- South Ural State University (Russian Federation)
The reaction of (4-fluorobenzyl)triphenylphosphonium chloride with ruthenium(III) chloride hydrate in the presence of hydrochloric acid in dimethyl sulfoxide affords the complex [Ph{sub 3}PCH{sub 2}C{sub 6}H{sub 4}F-4]{sub 2}[RuCl{sub 6}]. In the absence of hydrochloric acid, the reaction gives the complex [Ph{sub 3}PCH{sub 2}C{sub 6}H{sub 4}F-4][trans-RuCl{sub 4}(dmso-S){sub 2}]. The structures of the complexes were studied by {sup 1}H, {sup 19}F, and {sup 31}P NMR spectroscopy and X-ray diffraction.
- OSTI ID:
- 22863570
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 6 Vol. 66; ISSN RCBUEY; ISSN 1066-5285
- Country of Publication:
- United States
- Language:
- English
Similar Records
Carbonyl derivatives of chloride-dimethyl sulfoxide-ruthenium(III) complexes: Synthesis, crystal structure, and reactivity of [(DMSO){sub 2}H][trans-RuCl{sub 4}(DMSO)(CO)] and mer,cis-RuCl{sub 3}(DMSO){sub 2}(CO)
Preparation of tetraalkyl phosphine complexes of the f-block metals. Crystal structure of Th(CH/sub 2/Ph)/sub 4/(Me/sub 2/PCH/sub 2/CH/sub 2/PMe/sub 2/) and U(CH/sub 2/Ph)/sub 3/Me(Me/sub 2/PCH/sub 2/CH/sub 2/PMe/sub 2/)
The fate of a bimetallic ethylene dimerization catalyst: Synthesis and structure of (dfepe){sub 2}Ir{sub 2}({mu}-{eta}{sup 1}:{eta}{sup 3}-C{sub 4}H{sub 6})({mu}-H)(H) (dfepe = (C{sub 2}F{sub 5}){sub 2}PCH{sub 2}CH{sub 2}P(C{sub 2}F{sub 5}){sub 2})
Journal Article
·
Wed Sep 13 00:00:00 EDT 1995
· Inorganic Chemistry
·
OSTI ID:210095
Preparation of tetraalkyl phosphine complexes of the f-block metals. Crystal structure of Th(CH/sub 2/Ph)/sub 4/(Me/sub 2/PCH/sub 2/CH/sub 2/PMe/sub 2/) and U(CH/sub 2/Ph)/sub 3/Me(Me/sub 2/PCH/sub 2/CH/sub 2/PMe/sub 2/)
Journal Article
·
Sat Dec 31 23:00:00 EST 1983
· Organometallics; (United States)
·
OSTI ID:5814605
The fate of a bimetallic ethylene dimerization catalyst: Synthesis and structure of (dfepe){sub 2}Ir{sub 2}({mu}-{eta}{sup 1}:{eta}{sup 3}-C{sub 4}H{sub 6})({mu}-H)(H) (dfepe = (C{sub 2}F{sub 5}){sub 2}PCH{sub 2}CH{sub 2}P(C{sub 2}F{sub 5}){sub 2})
Journal Article
·
Sun Dec 19 23:00:00 EST 1999
· Organometallics
·
OSTI ID:20013626