Two directions of heterocyclization in the reactions of dimethyl bicyclo[2.2.2]oct-5-ene-endo-2,endo-3-dicarboxylate with hetarenesulfenyl chlorides
Journal Article
·
· Russian Chemical Bulletin
- R. E. Alekseev Nizhny Novgorod State Technical University (Russian Federation)
A reaction of dimethyl bicyclo[2.2.2]oct-5-ene-endo-2,endo-3-dicarboxylate with 1,3-benzо- thiazole-2- and 3-methoxycarbonylpyridine-2-sulfenyl chlorides leads to two types of heterocyclization products, which are formed through the ring closure by the oxygen atom of the carbоmethoxy group and/or by the nitrogen atom of the hetaryl fragment of the sulfenylating agent. The product ratio is affected by the medium nature and structural features of sulfenyl chlorides.
- OSTI ID:
- 22863356
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 3 Vol. 67; ISSN RCBUEY; ISSN 1066-5285
- Country of Publication:
- United States
- Language:
- English
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