An approach to sulfate geoengineering with surface emissions of carbonyl sulfide

Journal Article · Tue May 03 00:00:00 EDT 2022 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-22-5757-2022· OSTI ID:2282470

Quaglia, Ilaria ^[1]; Visioni, Daniele ^[2]; Pitari, Giovanni ^[1]; Kravitz, Ben ^[3]

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1. University of L'Aquila (Italy)
2. Cornell Univ., Ithaca, NY (United States)
3. Indiana Univ., Bloomington, IN (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sulfate geoengineering (SG) methods based on lower stratospheric tropical injection of sulfur dioxide (SO₂) have been widely discussed in recent years, focusing on the direct and indirect effects they would have on the climate system. Here a potential alternative method is discussed, where sulfur emissions are located at the surface or in the troposphere in the form of carbonyl sulfide (COS) gas. There are two time-dependent chemistry–climate model experiments designed from the years 2021 to 2055, assuming a 40 Tg-Syr^-1 artificial global flux of COS, which is geographically distributed following the present-day anthropogenic COS surface emissions (SG-COS-SRF) or a 6 Tg-Syr^-1 injection of COS in the tropical upper troposphere (SG-COS-TTL). The budget of COS and sulfur species is discussed, as are the effects of both SG-COS strategies on the stratospheric sulfate aerosol optical depth (~Δτ=0.080 in the years 2046–2055), aerosol effective radius (0.46 µm), surface SO_x deposition (+8.9 % for SG-COS-SRF; +3.3 % for SG-COS-TTL), and tropopause radiative forcing (RF; ~-1.5 W m^–2 in all-sky conditions in both SG-COS experiments). Indirect effects on ozone, methane and stratospheric water vapour are also considered, along with the COS direct contribution. According to our model results, the resulting net RF is –1.3 W m^–2, for SG-COS-SRF, and –1.5 W m^–2, for SG-COS-TTL, and it is comparable to the corresponding RF of –1.7 W m^–2 obtained with a sustained injection of 4 Tg-Syr^-1 in the tropical lower stratosphere in the form of SO₂ (SG-SO2, which is able to produce a comparable increase of the sulfate aerosol optical depth). Significant changes in the stratospheric ozone response are found in both SG-COS experiments with respect to SG-SO2 (~5 DU versus +1.4 DU globally). According to the model results, the resulting ultraviolet B (UVB) perturbation at the surface accounts for –4.3 % as a global and annual average (versus –2.4 % in the SG-SO2 case), with a springtime Antarctic decrease of –2.7 % (versus a +5.8 % increase in the SG-SO2 experiment). Overall, we find that an increase in COS emissions may be feasible and produce a more latitudinally uniform forcing without the need for the deployment of stratospheric aircraft. However, our assumption that the rate of COS uptake by soils and plants does not vary with increasing COS concentrations will need to be investigated in future work, and more studies are needed on the prolonged exposure effects to higher COS values in humans and ecosystems.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE
• Grant/Contract Number: AC05-76RL01830
• OSTI ID: 2282470
• Report Number(s): PNNL-SA--179463
• Journal Information: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Journal Issue: 9 Vol. 22; ISSN 1680-7324
• Publisher: Copernicus Publications, EGU
• Country of Publication: United States
• Language: English

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54 ENVIRONMENTAL SCIENCES