Microstructure and mechanical properties of intragranular W-Cu/TiC-ZrC composite prepared by reactive melt infiltration at 1300 °C

Journal Article · Sun Apr 15 04:00:00 EDT 2018 · Materials Characterization

DOI:https://doi.org/10.1016/J.MATCHAR.2018.01.046· OSTI ID:22805743

Wang, Dong; Wei, Boxin; Wang, Yujin; Song, Guiming; Zhou, Yu ^[1]

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1. Key Laboratory of Advanced Structural-Functional Integration Materials & Green Manufacturing Technology, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China)

Highlights: • W-Cu/TiC-ZrC composites with nano W dispersoids were prepared by reactive melt infiltration. • The nano-sized dispersoids were analyzed by TEM in detail. • The intragranular nano W dispersoids and ribbon like precipitates have toughening effects. - Abstract: Newly intragranular W-Cu/TiC-ZrC composites with nano W dispersoids in TiC matrix have been prepared by reactive melt infiltration at 1300 °C for 1 h in vacuum using molten Zr-Cu binary alloys and a (Ti{sub 0.75},W{sub 0.25})C solid solution powder as raw materials. The as-synthesized composites consist of major phases of W, Cu, TiC and ZrC. With the decrease of Zr content from 66 to 21 at.% in the Zr-Cu infiltrator, the reaction formed W phase in the composite has changed from micron-sized intergranular grains to nano-sized rounded inclusions in TiC{sub y} grains. The crystallographic orientation relationship at W and TiC interfaces are detected as:(0 1 1-bar ){sub W}//(1 1 1-bar ){sub TiC}&[0 1 1]{sub W}//[0 1 1]{sub TiC} and (4 1 1){sub W}//(4 2 4){sub TiC}&[0 1 1-bar ]{sub W}//[4 2-bar 3-bar ]{sub TiC}. Nano-sized lamellar structure with both W and Cu rich is detected to have super-lattice structure based on the TiC lattice. The elastic modulus, flexural strength, fracture toughness of the intragranular W-Cu/TiC-ZrC composite infiltrated with Zr{sub 14}Cu{sub 51} melt are 207.5 GPa, 457 MPa and 10.21 MPa∙m{sup 1/2}, respectively. The intragranular nano W dispersoids and ribbon like precipitates hinder crack propagation via crack deflection and bridging.

• OSTI ID: 22805743
• Journal Information: Materials Characterization, Journal Name: Materials Characterization Vol. 138; ISSN 1044-5803; ISSN MACHEX
• Country of Publication: United States
• Language: English

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
BINARY ALLOY SYSTEMS
COMPOSITE MATERIALS
COPPER
CRACK PROPAGATION
CRYSTALLOGRAPHY
FLEXURAL STRENGTH
MICROSTRUCTURE
NANOSTRUCTURES
PRECIPITATION
PRESSURE RANGE GIGA PA
PRESSURE RANGE MEGA PA 100-1000
SOLID SOLUTIONS
TEMPERATURE RANGE 1000-4000 K
TITANIUM CARBIDES
TRANSMISSION ELECTRON MICROSCOPY
TUNGSTEN
ZIRCONIUM CARBIDES