Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and Physicochemical Study of an Anhydrous Organic Acidic Cyclohexaphosphate

Journal Article · Mon Jan 15 04:00:00 EST 2018 · Journal of Fluorescence (Online)

DOI:https://doi.org/10.1007/S10895-017-2181-4· OSTI ID:22795684

Fezai, Ramzi; Rzaigui, Mohamed ^[1]

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1. Université de Carthage, Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte (Tunisia)

The new organic–inorganic hybrid [5-Cl-2-(CH{sub 3})C{sub 6}H{sub 3}NH{sub 3}]{sub 4}H{sub 2}P{sub 6}O{sub 18} has been synthesized by the slow evaporation method. X-ray diffraction on a single crystal shows that this acidic cyclohexaphosphate crystallized in the monoclinic space group C{sub 2/c} with a = 33.89(11) Å, b = 9.16(16) Å, c = 13.68(3) Å, β = 91.35(2)°, V = 4244.9(19) Å{sup 3} and Z = 4. {sup 31}P MAS-NMR and {sup 13}C CP/MAS-NMR results are in accordance with X-ray findings. Fluorescent study shows the blue photoluminescence. Furthermore, FT-IR analysis was studied and the complete vibrational assignments were done. Intermolecular interactions were analyzed using Hirshfeld surface analysis and the associated 2D fingerprint plots.

• OSTI ID: 22795684
• Journal Information: Journal of Fluorescence (Online), Journal Name: Journal of Fluorescence (Online) Journal Issue: 1 Vol. 28; ISSN 1573-4994
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
CARBON 13
FLUORESCENCE
FOURIER TRANSFORMATION
INFRARED SPECTRA
MONOCLINIC LATTICES
MONOCRYSTALS
NUCLEAR MAGNETIC RESONANCE
PHOSPHORUS 31
PHOTOLUMINESCENCE
SPACE GROUPS
X RADIATION
X-RAY DIFFRACTION