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Effect of Tuning the Structure on the Optical and Magnetic Properties by Various Transition Metal Doping in ZnO/TM (TM = Fe, FeCo, Cr, and Mn) Thin Films

Journal Article · · Journal of Superconductivity and Novel Magnetism
 [1];  [2];  [3]
  1. Ibn Tofail University, Laboratory of Optoelectronics, Physical Chemistry Materials and Environmental, Department of Physics, Faculty of Sciences (Morocco)
  2. University Abdelmalek Essaadi-FST Tangier, Laboratory of Materials and Valorization of Natural Resources (Morocco)
  3. Mohammed V University-Agdal, Laboratory of Magnetism and High Energies Physics, URAC 12, Department of Physics, Faculty of Science (Morocco)

We have investigated in this work the physical, optical, electronic, and the magnetic behavior (Curie temperature, magnetic moment) of Zn.1-x.MxO (M = Fe 5%, Co 1%, Cr 5%, and Mn 5%), diluted magnetic semiconductors (DMSs). The samples were deposited on glass substrate by the spray pyrolysis technique, and the results of the x-ray diffraction (XRD) of the prepared substrates was used to prove the incorporation of the dopants into the ZnO lattice host; the ferromagnetic and the antiferromagnetic state competitions and their effects on the physical, magnetic, and optical properties, were investigated. The electronic structure and magnetic properties of transition metal (TM) defects, were investigated in detail, by using the Korringa–Kohn–Rostoker (KKR) method combined with the coherent potential approximation (CPA). As a result, doping by TM impurities induce the ferromagnetism with different competitions between the ferromagnetic and antiferromagnetic states, which affects the physical properties of the TM (Fe, Fe/Co, Cr, and Mn)-doped ZnO, with a Curie temperature closer to room-temperature ferromagnetic.

OSTI ID:
22774107
Journal Information:
Journal of Superconductivity and Novel Magnetism, Journal Name: Journal of Superconductivity and Novel Magnetism Journal Issue: 2 Vol. 31; ISSN 1557-1939
Country of Publication:
United States
Language:
English

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