Nuclear Magnetic Resonance Spectra of Polyhydroxylated Fullerene C{sub 60}(OH){sub n}

Journal Article · Sun Jul 15 00:00:00 EDT 2018 · Physics of the Solid State

DOI:https://doi.org/10.1134/S106378341807017X· OSTI ID:22771065

Mazur, A. S. ^[1]; Karpunin, A. E. ^[2]; Proskurina, O. V. ^[3]; Gerasimov, V. I.; Matveev, V. V. ^[1]; Kuz’min, Yu. I. ^[2]

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1. St. Petersburg State University (Russian Federation)
2. St. Petersburg Polytechnic University (Russian Federation)
3. St. Petersburg State Technological Institute (Technical University) (Russian Federation)

Polyhydroxylated fullerene C{sub 60}(OH){sub n} (with an estimated number of hydroxyl groups n = 38–44) synthesized from pure fullerene by mixing a benzene solution of C{sub 60} with a NaOH aqueous solution in the presence of a catalyst was studied with {sup 1}H and {sup 13}C solid-state nuclear magnetic resonance. Possible features of the structure of a molecule shell were revealed from {sup 1}H NMR data. The {sup 13}C spectrum showed a peak splitting with an increase in temperature, which is probably due to fullerenol isomers.

• OSTI ID: 22771065
• Journal Information: Physics of the Solid State, Journal Name: Physics of the Solid State Journal Issue: 7 Vol. 60; ISSN 1063-7834
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
BENZENE
CARBON 13
CATALYSTS
FULLERENES
HYDROGEN 1
ISOMERS
MIXING
MOLECULES
NUCLEAR MAGNETIC RESONANCE
SODIUM HYDROXIDES
SOLIDS
SPECTRA