Electron-donating functional groups strengthen ligand-induced chiral imprinting on CsPbBr3 quantum dots

Dunlap-Shohl, Wiley A.; Tabassum, Nazifa; Zhang, Peng; Shiby, Elizabeth; Beratan, David N.; Waldeck, David H.

doi:10.1038/s41598-023-50595-2

Electron-donating functional groups strengthen ligand-induced chiral imprinting on CsPbBr3 quantum dots

Journal Article · Tue Jan 02 23:00:00 EST 2024 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-023-50595-2· OSTI ID:2275006

Dunlap-Shohl, Wiley A.; Tabassum, Nazifa; Zhang, Peng; Shiby, Elizabeth; ;

Abstract

Chiral perovskite nanoparticles and films are promising for integration in emerging spintronic and optoelectronic technologies, yet few design rules exist to guide the development of chiral material properties. The chemical space of potential building blocks for these nanostructures is vast, and the mechanisms through which organic ligands can impart chirality to the inorganic perovskite lattice are not well understood. In this work, we investigate how the properties of chiral ammonium ligands, the most common organic ligand type used with perovskites, affect the circular dichroism of strongly quantum confined CsPbBr ₃ nanocrystals. We show that aromatic ammonium ligands with stronger electron-donating groups lead to higher-intensity circular dichroism associated with the lowest-energy excitonic transition of the perovskite nanocrystal. We argue that this behavior is best explained by a modulation of the exciton wavefunction overlap between the nanocrystal and the organic ligand, as the functional groups on the ligand can shift electron density toward the organic species-perovskite lattice interface to increase the imprinting.

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Sponsoring Organization:: USDOE

OSTI ID:: 2275006

Alternate ID(s):: OSTI ID: 2340087

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 14; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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