Imprinting Chirality onto the Electronic States of Colloidal Perovskite Nanoplatelets

Georgieva, Zheni N.; Bloom, Brian P.; Ghosh, Supriya; Waldeck, David H.

doi:10.1002/adma.201800097

Imprinting Chirality onto the Electronic States of Colloidal Perovskite Nanoplatelets

Journal Article · Thu Apr 26 00:00:00 EDT 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201800097· OSTI ID:1604940

Georgieva, Zheni N. ^[1]; Bloom, Brian P. ^[2]; Ghosh, Supriya ^[2]; ^[2]

Univ. of Pittsburgh, PA (United States); University of Pittsburgh
Univ. of Pittsburgh, PA (United States)

The direct synthesis of chiroptical organic–inorganic methylammonium lead bromide perovskite nanoplatelets that are passivated by R- or S-phenylethylammonium ligands is discussed. The circular dichroism spectra can be divided into two components: (1) a region associated with a charge transfer transition between the ligand and the nanoplatelet, 300–350 nm, and (2) a region corresponding to the excitonic absorption maximum of the perovskite, 400–450 nm. The temperature- and concentration-dependent circular dichroism spectra suggest that the chiro-optical response arises from chiral imprinting by the ligand on the electronic states of the quantum-confined perovskite rather than chiral ligand-induced stereoselective aggregation.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FG02-07ER46430

OSTI ID:: 1604940

Alternate ID(s):: OSTI ID: 1537226
OSTI ID: 1434966

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 23 Vol. 30; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Imprinting Chirality onto the Electronic States of Colloidal Perovskite Nanoplatelets

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